• Title/Summary/Keyword: Interfacial Tension

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A Study on the Resistance Spot Weldability of 590 MPa Grade DP Steel with Modified Electrode Tip (가공 전극을 적용한 590 MPa급 DP강의 저항 점용접에 관한 연구)

  • Lee, Sang-Min;Park, Yeong-Do
    • Korean Journal of Metals and Materials
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    • v.48 no.1
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    • pp.71-76
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    • 2010
  • The use of advanced high-strength steels (AHSS) in automotive applications has steadily increased over the past few years. Two different failure modes are generally observed in shear-tension tests for resistance spot welds of AHSS. interfacial fractures and full button pullout. Despite high load-carrying capacity. the resistance spot welds in AHSS cue prone to interfacial fractures. To improve the load carrying ability of welds during shear-lap and cross tension tests. the tip surface of the electrode was grooved in a round shape. The electrode tip surface was modified so as to concentrate the current now in the central and circumferential portion of the electrode force. The results showed that the interfacial fracture was suppressed in welds using the modified electrode. In a comparison of failure mode during mechanical tests. the welds made with the modified electrode showed a higher tendency to fail via full button pullout fracture.

Experiments on Interfacial Properties Between Ground and Shotcrete Lining (지반과 숏크리트 라이닝의 인터페이스 특성에 관한 실험적 연구)

  • Chang, Soo-Ho;Lee, Seok-Won;Bae, Gyu-Jin;Choi, Soon-Wook;Park, Hae-Geun;Kim, Jae-Kwon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.407-414
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    • 2004
  • Interfacial properties between rock mass and shotcrete play a significant role in the transmission of loads from the ground to shotcrete. These properties have a major effect on the behaviours of rock mass and shotcrete. They, however, have merely been assumed in most of numerical analyses, and little care has been taken in identifying them. This paper aimed to identify interfacial properties including cohesion, tension, friction angle, shear stiffness, and normal stiffness, through direct shear tests as well as interface normal compression tests for shotcrete/rock cores obtained from a tunnel sidewall. Mechanical properties such as compression strength and elastic modulus were also measured to compare them with the time-dependent variation of interfacial properties. Based on experiments, interfacial properties between rock and shotcrete showed a significant time-dependent variation similar to those of its mechanical properties. In addition, the time-dependent behaviours of interfacial properties can be well regressed through exponential and logarithmic functions of time.

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Characterization of Thin Liquid Films Using Molecular Dynamics Simulation

  • Lee, Jaeil;Park, Seungho;Ohmyoung Kwon;Park, Young-Ki;Lee, Joon-Sik
    • Journal of Mechanical Science and Technology
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    • v.16 no.11
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    • pp.1477-1484
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    • 2002
  • Various characteristics of a thin liquid film in its vapor-phase are investigated using the molecular dynamics technique. Local distributions of the temperature, density, normal and tangential pressure components, and stress are calculated for various film thicknesses and temperature levels. Distributions of local stresses change considerably with respect to film thicknesses, and interracial regions on both sides of the film start to overlap with each other as the film becomes thinner. Integration of the local stresses, i.e., the surface tension, however, does not vary much regardless of the interfacial overlap. The minimum thickness of a liquid film before rupturing is estimated with respect to the calculation domain sizes and is compared with a simple theoretical relation.

Manufacturing Process of Translucent Microemulsion and Its Stability (Translucent Microemulsion의 제조 공정과 안정성)

  • Bae, Duck-Hwan;Shin, Jae-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.3
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    • pp.167-173
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    • 2000
  • The process variables for the manufacture of translucent microemulsion prepared with 2-octyl dodecanol, 12-hydroxy stearic acid cholesteryl , POE(40)HCO and 1,3-butandiol were examined initially (primary emulsion) and following aging for three months. The techniques empolyed in this study were particle size, turbidity, interfacial tension and microfluidizer. Particle size analysis and turbidity measurement to evaluate the emulsion stability were used. It was concluded that the process of the emulsification was an important indicator of the stability of the translucent microemulsion. From the particle size and and turbidity measurement of translucent microemulsion, adding the surfactant to the oil phase before the emulsification was found to be the most important factor for the stability of emulsions. We found that interfacial tension of the adding the surfactant to the oil phase is lower than that of the adding the surfactant to aqueous phase. In spite of hydrophilic surfactant, adding the surfactant to aqueous phase produced inferior emulsion to that to oil phase.

Flow Characteristics in the Converging Mini-Channels (좁아지는 유로에서의 유동 특성)

  • Karng, Sarng-Woo;Kim, Jin-Ho;Lee, Yoon-Pyo
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1623-1628
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    • 2004
  • Recently mini-channels or micro-channels are widely used for cooling the high density power electronic devices. Especially, the channels are used in small and high efficient equipments such as heat pipes and heat exchangers. Interfacial velocities between liquid and gas phases are very important in mini or micro-channels. In this paper, an experiment and a numerical analysis on the interfacial velocities were performed. In the experiment, the interfacial velocities which were measured by the high-speed CCD camera were about $26{\sim}33$ cm/s and the velocities increased as the inclination angle did. In the numerical experiment, CFD-ACE+, a commercial program, was used, the velocities had similar values with experimental results. As the inclination angle and the contact angle increased, the interfacial velocities did because of the surface tension which causes to move the interface. The effect of inclination angle was larger in the converging channels than in straight channels.

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A study on the Interfacial Properties of Electrodeposited Single Carbon Fiber/Epoxy Composites Using Tensile and Compressive Fragmentation Tests

  • Park, Joung-Man;Kim, Jin-Won
    • Macromolecular Research
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    • v.10 no.1
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    • pp.24-33
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    • 2002
  • Interfacial and microfailure properties of carbon fiber/epoxy composites were evaluated using both tensile fragmentation and compressive Broutman tests. A monomeric and two polymeric coupling agents were applied via the electrodeposition (ED) and the dipping applications. A monomeric and a polymeric coupling agent showed significant and comparable improvements in interfacial shear strength (IFSS) compared to the untreated case under both tensile and compressive tests. Typical microfailure modes including cone-shaped fiber break, matrix cracking, and partial interlayer failure were observed under tension, whereas the diagonal slipped failure at both ends of the fractured fiber appeared under compression. Adsorption and shear displacement mechanisms at the interface were described in terms of electrical attraction and primary and secondary bonding forces.

Katayama Equation Modified on the Basis of Critical-Scaling Theory (임계 축척 이론을 이용한 카타야마 식의 수정)

  • Lim, Kyung-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.3
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    • pp.185-191
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    • 2006
  • It is desirable to have an accurate expression on the temperature dependence of surface(or interfacial) tension ${\sigma}$, because most of the interfacial thermodynamic functions can be derived from it. There have been proposed several equations on the temperature dependence of the surface tension, ${\sigma}(T)$. Among them $E{\ddot{o}}tv{\ddot{o}}s$ equation and the one modified by Katayama, which is called Katayama equation, for improving accuracies of $E{\ddot{o}}tv{\ddot{o}}s$ equation close to critical points, have been most well-known. In this article Katayama equation is interpreted on the basis of the cell model to understand the nature of the equation. The cell model results in an expression very similar to Katayama equation. This implies that, although $E{\ddot{o}}tv{\ddot{o}}s$ and Katayama equations were obtained on the basis of experimental results, they have a sound theoretical background. The Katayama equation is also modified with the phase volume replaced with a critical scaling expression. The modified Katayama equation becomes a power-law equation with the exponent slightly different from the value obtained by critical-scaling theory. This implies that Katayama equation can be replaced by a critical-scaling equation which is proven to be accurate.

Molecular Area and Interfacial Tension Behavior of High Efficiency Cosurfactants (보조계면활성제의 계면에서의 분자면적과 계면장력 거동)

  • Kim, Chunhee
    • Journal of the Korean Chemical Society
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    • v.40 no.1
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    • pp.1-10
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    • 1996
  • Gibbs' adsorption isotherms are studied to assay the structural effects of ethylene oxide (EO) and propylene oxide (PO) moieties on the molecular area and the interfacial tension behavior of molecules at the interface. Several industrial alcohols and isomerically pure alcohols, which have a general stucture of C4H9O(EO)m(PO)nH, are examined for their cosurfactant properties. They are high molecular weight alcohols and more surface active than the cosurfactants usually used. Results show that the number and the sequence of EO and PO units significantly affect the molecular areas and the interfacial tension (IFT) behavior of these molecules at the water/oil interface. The following conclusions are drawn from the result: 1) PO is more efficient in lowering the IFT and less effective in adsorption than EO. 2) For molecules having the same molecular weight but different structures, smaller molecules are more efficient in lowering the IFT. 3) When more EO, PO, or both units are added to the same hydrophobe, the molecule become bigger and more efficient in lowering the IFT.

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The Stabilization of Liquid Crystal Emulsions by Acrylamide Copolymers (Acrylamide Copolymers에 의한 Liquid Crystal Emulsions의 안정성에 관한 연구)

  • Ryu, Hai-Il;Jang, Nak-Han;Jeon, Youn-Seok;Lee, Myeong-Shin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.8
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    • pp.2005-2014
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    • 2009
  • There are several methods to fabricate Polymer Dispersed Liquid Crystal(PDLC) films. One of them, so-called Nematic Curvilinear Aligned Phase(NCAP) film, is based on emulsion technology. To produce NCAP systems various water soluble polymers, such as partially hydrolyzed polyvinylalcohol(PVA) and polyvinyl pyrrolidone(PVP), which can form stable emulsion of liquid crystal(LC) without any stabilizers were used. In this work, we studied the dependence of emulsion stability on nature and composition of copolymers composed of water-soluble and water-insoluble moiety. We found that interfacial surface tension depends on the composition of comonomer, the copolymer concentration in the water, and the nature of hydrophobic chain. The Acrylamide -styrene(AA-ST) copolymer showed the lowest interfacial surface tension among the tested copolymers at the same concentration. Since the interfacial surface tension decreases with increasing the compatibility of copolymer with LC phase the AA-ST copolymer has the best compatibility with LC molecules. It is believed that molecules adsorbing easily on the surface of LC droplets allows the LC emulsion system to be more stable.

Bioremedation of petrolium pollution (유류오염의 미생물학적 제어)

  • 이상준;차미선;이근희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.02a
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    • pp.14-28
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    • 2001
  • As basic study for purpose bioremedation in oil-contaminated environment, Primarily, we isolated biosurfactant producer- strains utilized of oil-agar plate, and measured surface tension and emulsifying activity. We investigated in oil-contaminated soil and sea water. In this laboratory, Pseudomonas sp. EL-012S strain isolated from oil-contaminated soil was able to product novel biosurfactant under the optimal culture condition. Its condition was n-hexadecane 2.0%, NH$_4$NO$_3$0.4%, Na$_2$HPO$_4$0.6%, KH$_2$PO$_4$0.4%, MgSO$_4$.7$H_2O$ 0.02%, CaCl$_2$.2$H_2O$ 0.001%, FeSO.7$H_2O$ 0.001%, initial pH 7.0 and aeration at 3$0^{\circ}C$, respectively. This biosurfactant was produced in both late-exponential and early-stationary phase. The biosurfactant from Pseudomonas sp. EL-012S was composed of carbohydrate, lipid and protein. The purified-biosurfactant was examined two (biosurfactant type I, II) with the silica gel G60 column chromatography and the purified biosurfactant confirmed thin layer chromatography, high performed liquid chromatography and gas chromatography. The biosurfactant type I involved in carbohydrate-lipid-protein characteristics lowered surface tension of water to 27dyne/cm and interfacial tension 4.5dyne/cm aginst to n-hexadecane and the biosurfactant type B involved in carbohydrate lipid characteristics lowered surface tension of water to 30dyne/cm and interfacial tension 8dyne/cm against to n-hexadecane. Specially type I had the properties such as strong emulsifying activity, emulsion stability, pH-stability, thermo-stability, high cleaning activity and forming ability.

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