• Title/Summary/Keyword: Interfacial Properties

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A Study of Mechanical Interfacial Properties of Carbon Nanotube on Carbon Fiber/Epoxy Resin Composites (탄소나노튜브로 표면처리 된 탄소섬유/에폭시 수지 복합재료의 기계적 특성 연구)

  • Hong, Eunmi;Lee, Kyuhwan;Kim, Yangdo;Lim, Dongchan
    • Journal of the Korean institute of surface engineering
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    • v.46 no.5
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    • pp.223-228
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    • 2013
  • In this work, the grow of carbon nanotube (CNT) on carbon fiber was introduced on PAN-based carbon fibers for the enhancement of mechanical interfacial strength of carbon fibers-reinforced composites. The surface properties of carbon fibers were determined by scanning electron microscopy (SEM) and mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS). From the results, it was found that the mechanical interfacial properties of CNT-carbon fibers-reinforced composites (CNT-CFRPs) enhanced with decreasing the CNT content. The excessive CNT content can lead the failure due to the interfacial separation between fibers and matrices in this system. In conclusion, the optimum CNT content on carbon fiber surfaces can be a key factor to determine the mechanical interfacial properties of the CNT-CFRPs.

Fabrication and Fracture Properties of Nb/MoSi2Laminate Composites (Nb/MoSi2적층복합재료의 제조 및 파괴특성)

  • Lee, Sang-Pill;Yoon, Han-Ki
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.6
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    • pp.1047-1052
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    • 2002
  • The impact value, the interfacial shear strength, the tensile strength and the fracture strain of Nb/MoSi$_2$laminate composites, which were associated with the interfacial reaction layer, have been investigated. Three types of Nb/MoSi$_2$ laminate composites alternating sintered MoSi$_2$ layers and Nb foils were fabricated as the parameter of hot press temperature. The thickness of interfacial reaction layer of Nb/MoSi$_2$ laminate composites increased with increasing the fabrication temperature. The growth of interfacial reaction layer increased the interfacial shear strength and led to the decrease of impact value in Nb/MoSi$_2$ laminate composites. It was also found that in order to maximize the fracture energy of Nb/MoSi$_2$ laminate composites, interfacial shear strength and the thickness of interfacial reaction layer must be secured appropriately.

Corelationship between Interfacial Fracture Toughness and Mechanical Properties of Concrete (계면파괴인성과 콘크리트 역학적 성질의 상관관계)

  • 이광명;안기석;이회근;김태근
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.359-364
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    • 1998
  • The interfacial zone in concrete materials is extensive, geometrically complex, and constitutes inherently weak zones that limit the concrete performance. Motar-aggregate interfaces play a major role in the fracture processing in concrete composites. Also, the interfacial bond considerably influence mechanical properties of concrete such as modulus of elasticity, strength, and fracture energy, Characterization of the interfacial properties is, therefore, essential to overcome the limitations associated with the interfaces. an objective of this paper is to investigate the corelationship between the fracture toughness of mortar-aggregate interface and the concrete properties such as strengths and elastic moduli. It is observed from the test results that interface fracture toughness is closely related with the compressive strength rather than other properties. At early ages, the development of both tensile strength and elastic modulus are much greater thatn that of both interface fracture toughness and compressive strength.

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Improvement of Impact Properties for $Nb/MoSi_2$ Laminate Composites by the Interfacial Modification (II)

  • Lee, Sang-Pill;Yoon, Han-Ki
    • Journal of Mechanical Science and Technology
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    • v.14 no.8
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    • pp.830-835
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    • 2000
  • The thermodynamical estimation of the interfacial reaction and the impact properties of $Nb/MoSi_2$ laminate composites containing SiC, $NbSi_2$ or $ZrO_2$ particles are investigated. Laminate composites, which comprise alternating layers of $MoSi_2$ with the particle and Nb foil, were fabricated by the hot press process. It is clearly found out that the interfacial reaction of $Nb/MoSi_2$ can be controlled by the addition of $ZrO_2$ particle to the $MoSi_2$ phase. The addition of $ZrO_2$ particle increases both the impact value and the sintered density of Nb/McSij, The suppression of the interfacial reaction is caused by the formation of $ZrSiO_2$ in $MoSi_2-ZrO_2$ matrix mixture.

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A Theory of Interface between Polymer and Polymer Mixture

  • Yoon Kyung-Sup;Park Hyungsuk
    • Bulletin of the Korean Chemical Society
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    • v.15 no.1
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    • pp.45-52
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    • 1994
  • We present a theoretical study of the non-symmetrical A/BC polymeric system. The polymer blends consist of two phases, a pure polymeric phase A on one side and a mixture of polymers B as a compatibilizer and C on the other. The adsorption of homopolymer B to the interface improves the interfacial adhesion between two phases. By employing the functional integral techniques, we derive the mean-field equations and solve them numerically to obtain the interfacial properties including the concentration profiles in the limit of infinite molecular weight for the polymers. Thecalculations of the interfacial properties are performed for typical values of the Flory X parameters and the volume fraction of polymer B in the asymptotic mixture phase. The interfacial adsorption of polymer B and the degrees of the specific interaction between the polymers play an important role in modification of the interfacial properties.

Studies on Mechanical Interfacial Properties of Kevlar-29 Fibers Reinforced Composites (Kevlar-29 섬유강화 복합재료의 기계적 계면 특성 연구)

  • Park, Soo-Jin;Seo, Min-Kang;Ma, Tae-Jun;Lee, Jae-Rock
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.158-162
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    • 2001
  • The effects of chemical treatment on Kevlar-29 fibers have been studied in a composite system. The surface characteristics of the Kevlar-29 fibers were characterized by pH, acid-base value and X-ray photoelectron spectroscopy (XPS). The mechanical interfacial properties of final composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). Also, the impact properties of the composites were investigated in the differentiating studies between initiation and propagation energies, and ductile index (DI) along with maximum farce and total energy. It was found that the chemical treatment with phosphoric acid ($H_3PO_4$) solution significantly affected the degree of adhesion at interfaces between fibers and resin matrix, resulting in improving the mechanical interfacial strength of the composites. This was probably due to the presence of chemical polar groups on Kevlar surfaces, leading to an increment of interfacial binding force in a composite system.

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Interfacial Shear Strength and Thermal Properties of Electron Beam-Treated Henequen Fibers Reinforced Unsaturated Polyester Composites

  • Pang Yansong;Cho Donghwan;Han Seong Ok;Park Won Ho
    • Macromolecular Research
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    • v.13 no.5
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    • pp.453-459
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    • 2005
  • Natural fiber henequen/unsaturated polyester (UPE) composites were fabricated by means of a compression molding technique using chopped henequen fibers treated at various electron beam (EB) dosages. The interfacial shear strength (IFSS), dynamic mechanical properties, and thermal expansion behavior were investigated through a single fiber microbonding test, fractographic observation, dynamic mechanical analysis, and thermomechanical analysis, respectively. The results indicated that the interfacial and dynamic mechanical properties significantly depended on the level of the EB treatment irradiated onto the henequen fiber surfaces. The effect of EB treatment on the IFSS, storage modulus and fracture surface of the henequen/UPE composites agreed with each other. The results of this study also suggested that the modification of henequen fiber surfaces at 10 kGy EB is the most effective for improving the interfacial properties of the henequen/UPE composites.

Interfacial Properties of Polypropylene Fiber in High Performance Fiber Reinforced Cement Composites (고인성 섬유보강 복합체 내에서 폴리프로필렌 섬유의 계면 부착성능)

  • Han Byung-Chan;Jeon Esther;Park Wan-Shin;Lee Young-Seak;Hiroshi Fukuyama;Yun Hyun-Do
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.108-111
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    • 2004
  • The polypropylene(PP) fiber is poised as a low cost alternative for reinforcement in structural applications in comparison with other high performance fibers, such as the polyvinyl-alcohol(PVA), polyethylene, carbon and aramid fiber. The mechanical properties of the composite are strongly determined by the interfacial behavior of fiber and cementitious matrix. The crack bridging mechanism contribute to composite toughness from activation of the fiber-matrix interface where energy is dissipated through debonding of the interface and fiber pullout. In this study, therefore, the pullout behavior of PP fibers is investigated. Experimental work includes the investigation of the interfacial properties, and the composite property. The quantification of interfacial properties, the frictional bond is achieved through single fiber pullout test. A study on the effect of inclination angle on fiber pullout behavior is also conducted.

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Interfacial Properties in Cu-phthalocyanine-based Hybrid Inorganic/Organic Multilayers

  • Lee, Nyun Jong;Ito, Eisuke;Bae, Yu Jeong;Kim, Tae Hee
    • Journal of Magnetics
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    • v.17 no.4
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    • pp.261-264
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    • 2012
  • Interfacial properties of 5 nm MgO(001)/7 nm Fe(001)/1.8 nm MgO(001)/t nm Cu-phthalocyanine (CuPc) hybrid multilayers with t = 0, 1, 7, and 10 were investigated by using x-ray photoemission spectroscopy (XPS). Rather sharp interfacial properties were observed in the CuPc films grown on an epitaxial MgO/Fe/MgO(001) trilayer than a MgO/Fe(001) bilayer. This work suggests a new way to improve device performance of organic spintronic devices by utilizing an artificially grown MgO(001) thin layer.

Surface Modification of Glass Fiber for Polymer Insulator by Plasma Surface Treatment (플라즈마 표면처리에 따른 고분자절연재료용 유리섬유의 표면개질)

  • 임경범;이덕출
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.52 no.5
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    • pp.206-206
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    • 2003
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, glass surface was treated by plasma to examine the effect of dry interface treatment without coupling agent. It was identified that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.