• Title/Summary/Keyword: Interfacial Force

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XPS Analysis of PVDF Film Treated by Corona Discharge in Ethyl Methacrylate Vapor Atmosphere (에틸메타크릴레이트 증기 분위기에서 코로나 방전 처리한 PVDF 필름의 XPS 분석)

  • Moon, HuiKwon;Seomoon, Kyu
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.627-632
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    • 2016
  • Ethyl methacrylate (EMA) monomer coupling onto the polyvinylidene fluoride (PVDF) film surface was attempted to enhance the interfacial adhesive force between PVDF-polyvinyl chloride (PVC) bilayer films via dielectric barrier corona discharge. The interfacial forces were quite enhanced when PVDF films were treated by corona discharge in an EMA 1% atmosphere. The contact angle of PVDF films decreased due to corona treatment. X-ray photoelectron spectroscopy (XPS) analysis showed that the carbon and oxygen content of the PVDF film surface increased with corona discharge while the fluoride content decreased. The curve fitting of XPS $C_{1s}$ peaks revealed that the non-polar C-C bonded carbon and oxygen-bonded carbon increased gradually with corona treatment, while the fluorine-bonded carbon decreased.

Interfacial Adhesion Properties of Surface Treated Polyarylate Fiber with Polyethylene Naphthalate (폴리아릴레이트 섬유의 표면처리에 의한 폴리에틸렌 나프탈레이트 수지와의 계면접착특성)

  • Yong, Da Kyung;Choi, Han Na;Yang, Ji Woo;Lee, Seung Goo
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.24-30
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    • 2012
  • Morphological changes of polyarylate (PAR) fiber treated with formic acid and ultraviolet (UV) were observed by using a scanning electron microscope (SEM) and an atomic force microscope (AFM). The results were analysed by using root mean square (RMS) roughness. In addition, the chemical changes of surface was investigated using contact angle and the interfacial adhesive strength between PAR fiber and PEN (Polyethylene naphthalate) matrix was calculated using the Pull-out test results. As the acid treatment concentration and UV irradiation time increased, cracks and pores were produced on the PAR fiber surface. Due to the roughness increased, the contact angle was decreased. For this reason, RMS roughness of PAR fiber was increased and the interfacial adhesive strength between the PAR fiber and PEN matrix was improved. The increase of interfacial adhesive strength was responsible for the increase of surface area which have cracks and pores.

Effect of Desmear Treatment on the Interfacial Bonding Mechanism of Electroless-Plated Cu film on FR-4 Substrate (Desmear 습식 표면 전처리가 무전해 도금된 Cu 박막과 FR-4 기판 사이의 계면 접착 기구에 미치는 영향)

  • Min, Kyoung-Jin;Park, Young-Bae
    • Korean Journal of Materials Research
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    • v.19 no.11
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    • pp.625-630
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    • 2009
  • Embedding of active devices in a printed circuit board has increasingly been adopted as a future electronic technology due to its promotion of high density, high speed and high performance. One responsible technology is to embedded active device into a dielectric substrate with a build-up process, for example a chipin-substrate (CiS) structure. In this study, desmear treatment was performed before Cu metallization on an FR-4 surface in order to improve interfacial adhesion between electroless-plated Cu and FR-4 substrate in Cu via structures in CiS systems. Surface analyses using atomic force microscopy and x-ray photoemission spectroscopy were systematically performed to understand the fundamental adhesion mechanism; results were correlated with peel strength measured by a 90o peel test. Interfacial bonding mechanism between electrolessplated Cu and FR-4 substrate seems to be dominated by a chemical bonding effect resulting from the selective activation of chemical bonding between carbon and oxygen through a rearrangement of C-C bonding rather than from a mechanical interlocking effect. In fact, desmear wet treatment could result in extensive degradation of FR-4 cohesive strength when compared to dry surface-treated Cu/FR-4 structures.

On the Relationship between Material Removal and Interfacial Properties at Particulate Abrasive Machining Process (연마가공에서의 접촉계면 특성과 재료제거율간의 관계에 대한 연구)

  • Sung, In-Ha
    • Tribology and Lubricants
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    • v.25 no.6
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    • pp.404-408
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    • 2009
  • In this paper, the relationship between the material removal rate and the interfacial mechanical properties at particle-surface contact situation, which can be seen in an abrasive machining process using micro/nano-sized particles, was discussed. Friction and stiffnesses were measured experimentally on an atomic force microscope (AFM) by using colloidal probes which have a silica colloid particle in place of tip to simulate a particle-flat surface contact in an abrasive machining process. From the experimental investigation and theoretical contact analysis, the interfacial contact properties such as lateral stiffness of contact, friction, the material removal rate were presented with respect to some of material surfaces and the relationship between the properties as well.

A Study on the Resistance Spot Weldability of 590 MPa Grade DP Steel with Modified Electrode Tip (가공 전극을 적용한 590 MPa급 DP강의 저항 점용접에 관한 연구)

  • Lee, Sang-Min;Park, Yeong-Do
    • Korean Journal of Metals and Materials
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    • v.48 no.1
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    • pp.71-76
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    • 2010
  • The use of advanced high-strength steels (AHSS) in automotive applications has steadily increased over the past few years. Two different failure modes are generally observed in shear-tension tests for resistance spot welds of AHSS. interfacial fractures and full button pullout. Despite high load-carrying capacity. the resistance spot welds in AHSS cue prone to interfacial fractures. To improve the load carrying ability of welds during shear-lap and cross tension tests. the tip surface of the electrode was grooved in a round shape. The electrode tip surface was modified so as to concentrate the current now in the central and circumferential portion of the electrode force. The results showed that the interfacial fracture was suppressed in welds using the modified electrode. In a comparison of failure mode during mechanical tests. the welds made with the modified electrode showed a higher tendency to fail via full button pullout fracture.

Improved performance of polyamide nanofiltration membranes by incorporating reduced glutathione during interfacial polymerization

  • Jiao, Zhiwei;Zhou, Linjie;Wu, Mengyuan;Gao, Kang;Su, Yanlei;Jiang, Zhongyi
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2487-2495
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    • 2018
  • Inspired by the specific amino acid sequence Asn-Pro-Ala (NPA) of water channel aquaporins (AQPs), we fabricated polyamide (PA) nanofiltration (NF) membranes by introducing reduced glutathione (GSH) in interfacial polymerization (IP) method. Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectrometry (XPS), scanning electron microscope (SEM), atomic force microscopy (AFM), zeta potential and static water contact angle measurement were employed to characterize the chemical composition, morphology, electronegativity and hydrophilicity of the NF membranes. The water flux of GSH/PIP-TMC NF membrane reached $32.00L\;m^{-2}h^{-1}$ at 0.2 MPa, which was approximately twice than that of pristine PIP-TMC NF membrane when the ratio of GHS to piperazidine (PIP) was 40% during IP process. More water channels were built as GSH was embedded into PA layer. The fabricated NF membranes also took on potent rejection for dyes and $Na_2SO_4$. This study presents a simple and facile method to simulate water channels-based biological materials which may find potential application in water treatment.

Deformation analysis of a geocell mattress using a decoupled iterative method

  • Zhang, Ling;Zhao, Minghua;Zhao, Heng
    • Structural Engineering and Mechanics
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    • v.46 no.6
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    • pp.775-790
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    • 2013
  • Deformation analysis is a major concern in many geotechnical applications. In this paper, the deformation behavior of a geocell mattress subjected to symmetric loads was studied. The mattress was idealized as an elastic foundation beam. The horizontal beam-soil interfacial shear resistances at the beam top and bottom sides were taken into account by assuming the resistances to be linear with the relative horizontal displacements. A decoupled iterative method was employed to solve the differential displacement equations derived from the force analysis of a beam element and to obtain the solutions for the deformations and internal forces of the geocell reinforcement. The validity of the present solutions was verified by the existing finite element method and power-series solutions.

An Experimental Study on Flexural Repair of Reinforced Concrete Beams with the CFRP Sheet (탄소섬유시트를 사용한 철근콘크리트 구조물의 휨 보강에 관한 실험적 연구)

  • 박정원;박상렬;민창식
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.781-786
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    • 2000
  • This paper presents the behavior and strenghening effect of reinforced concrete rectangular beams strengthened sing CFRP sheets with different strengthening level. In general, normally strengthened beams are failed by interfacial shear failure (delamination) within concrete, instead of by tensile failure of the CFRP sheets. The delamination occurred suddenly and the concrete cover cracked vertically by flexure was spalled off due to the release energy. The ultimate load considerably increased with an increase of strengthening level, while the ultimate deflection significantly decreased. The tensile force of CFRP sheets and average shear stress of concrete at delamination failure were curvilinearly proportional to the strengthening level. Therefore, the increment of ultimate load obtained by strengthening was curvilinearly proportional to th strengthening level.

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Effect of Surface Modification of Donor Plate on the Fabrication of OLED Devices by LITI Process

  • Bae, Heung-Kwon;Kim, Jin-Hoo;Kwon, Hyeok-Yong;Lee, Yoon-Soo;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.784-786
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    • 2009
  • Thermal transfer of emitting layer from the donor film to the substrates depends on the physical interaction between the donor film, the emitting layer, and the hole-transport layer (HTL). The interfacial adhesion between the donor film and the EML, the cohesive force of the EML, and the interfacial adhesion between the EML and the HIL have to be optimized to achieve good LITI pattern quality. It was found that surface pretreatment of the donor plate was important on the laser induced thermal transfer of the emitting layer onto the HIL layer of the OLED devices.

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Strengthening Effect of R/C Beams with different Strengthening Level

  • Park, Sang-Yeol;Park, Jeong-Won;Min, Chang-Shik
    • KCI Concrete Journal
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    • v.12 no.1
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    • pp.113-120
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    • 2000
  • This paper presents the behavior and strengthening effect of reinforced concrete rectangular beams strengthened using CFRP sheets with different strengthening level. In general, normally strengthened beams are failed by interfacial shear failure (delamination) within concrete, instead of by tensile failure of the CFRP sheets. The delamination occurred suddenly and the concrete cover cracked vertically by flexure was spalled off due to the release energy. The strengthened beams were stiffer than the control beam before and after reinforcement yielding. The ultimate load considerably increased with an increase of strengthening level, while the ultimate deflection significantly decreased. The tensile force of CFRP sheets and average shear stress of concrete at delamination failure were curvilinearly proportional to the strengthening level. Therefore, the increment of ultimate load obtained by strengthening was curvilinearly proportional to the strengthening level. The averaged horizontal shear stress of concrete at the interface ranges between (equation omitted) and (equation omitted) (in kg/$\textrm{cm}^2$) depending on strengthening level.

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