• Title/Summary/Keyword: Interface reaction

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Fracture Behavior of Fe Crucible in Molten Aluminum Coated with Al and Anodized Al (수명을 향상시키기 위해 Al 메탈 코팅과 양극산화처리된 Steel 도가니의 파괴 거동)

  • Cha, Taemin;Shin, Byung-Hyun;Hwang, Myungwon;Kim, Do-Hyung;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.51 no.1
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    • pp.34-39
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    • 2018
  • Steel crucible used for molten Al has a problem of very limited lifetime because of the interaction between Fe and molten Al. This study was performed to improve the lifetime of steel crucible for molten Al by coating metallic Al and by further anodizing treatment to form thick and uniform anodic oxide films. The lifetime of the steel crucible was improved slightly by Al coating from 30 to 40 hours by metallic Al coating and largely to 120 hours by coating the surface with anodic oxide film. The improved lifetime was attributed to blocking of the reaction between Fe and molten Al with the help of anodic oxide layer with more than 20 um thickness on the crucible surface. The failure of the steel crucible arises from the formation of intermetallic compounds and pores at the steel/Al interface.

Surface Modification of Polyester by UV-irradiation with Oxidizing Agent, and Its Adhesion Property (자외선/산화제 처리에 의한 폴리에스테르의 표면개질 및 접착성)

  • 최창남;김종배;김상률
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.50-56
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    • 1999
  • The adhesive properties of polyester cord in rubber matrix were investigated according to the surface modification. The polyester cord was oxidized in sodium hypochlorite solution, and graft-polymerized with acrylic acid under the irradiation with ultraviolet light, and then coated with resorcinol-formaldehyde latex (RFL). The modified surface was checked with scanning electron microscope. The adhesive properties were measured by the full-Out method, and evaluated with regard to the energy of adhesion and the maximum load. The polyester was not oxidized in sodium hypochlorite solution, so the surface was not able to etch to produce the coarse topology. As the concentration of acrylic acid and the reaction time were increased, the graft yields were also increased. It was considered that the acrylic acid would swell the polyester and diffuse easily to the inner side of substrate. The adhesive properties of polyeser to rubber matrix were affected by the surface condition. Namely, the maximum load was almost same, but the energy of adhesion was rather higher In the polyester grafted with acrylic acid than in control one. We concluded that the flexible aliphatic chains of polyacrylic acid situated in the interface of cord and rubber matrix were distributed well the stress and strain all over the filler resulting the high energy of adhesion.

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Liquid Crystal Based Optical Sensor for Imaging Trypsin Activity at Interfaces Between Aqueous Phases and Thermotropic Liquid Crystals

  • Zhang, Minmin;Jang, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2973-2977
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    • 2013
  • In this study, we developed a liquid crystal (LC)-based optical sensor for monitoring enzymatic activity through orientational changes in liquid crystals (LCs) coupled to the properties of a poly-${\small{L}}$-lysine (PLL)-based polymeric membrane. We prepared a PLL-based polymeric membrane at the planar interface between the thermotropic liquid crystal and aqueous phases. The PLL-based polymeric membrane was obtained by contacting the PLL solution with water immiscible LCs, 4-cyano-4'-pentyl-biphenyl (5CB) doped with adipoyl chloride. We then investigated the membrane properties by examining the permeability of the membrane to phospholipids, 1,2-didodecanoyl-rac-glycero-3-phosphocholine (DLPC). The permeability of the membrane to transport phospholipids was monitored through the orientational transition of 5CB in contact with the dispersions of DLPC. Since trypsin can enzymatically catalyze the hydrolysis of PLL, we incubated an aqueous trypsin solution with the membrane for 2 h at room temperature to cause an increase in the permeability of the polymeric membrane to DLPC. As a result, a bright to dark optical shift of LCs was observed, which implied that an enzymatic reaction between trypsin and PLL-based membrane occurred. Two control experiments using chymotrypsin and bovine serum albumin (BSA) revealed no sign of improved permeability based on the orientational transition of LCs.

Use of High Zinc Bath Entry Strip Temperature to Solve Coating Problems

  • Sippola, Pertti;Smith, David
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.175-186
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    • 2010
  • The auto industry is demanding more ductile high-strength steel grades to build lighter and stronger car bodies. The hot-dip galvanizing problems of these new steel grades are creating a demand for an improved method to control zinc wettability. The simplest way to improve zinc wettability on industrial hot-dip galvanizing lines is to increase the strip immersion temperature at zinc bath entry for enhancing the aluminothermic reaction. However, this practice increases the reactivity due to overheating the zinc in the snout which induces the formation of brittle Fe-Zn compounds at the strip/coating interface with the formation of higher amounts of dross in the zinc bath and snout contamination. Thus, this simple practice can only be utilized for short production periods of one to two hours without deteriorating coating quality. This problem has been solved by employing a technique that allows the use of a higher and attuned strip immersion temperature at zinc bath entry while still maintaining a constantly low zinc bath temperature. This has been proven to provide the solution for both the improved wettability and a significant reduction in the amounts of dross in the zinc bath.

A Study on Cu(B)/Ti/SiO2/Si Structure for Application to Advanced Manufacturing Process (차세대 공정에 적용 가능한 Cu(B)/Ti/SiO2/Si 구조 연구)

  • Lee Seob;Lee Jaegab
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.246-250
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    • 2004
  • We have investigated the effects of boron added to Cu film on the Cu-Ti reaction and microstructural evolution of Cu(B) alloy film during annealing of Cu(B)/Ti/$SiO_2$/Si structure. The result were compared with those of Cu(B)/$SiO_2$ structure to identify the effects of Ti glue layers on the Boron behavior and the result grain growth of Cu(B) alloy. The vacuum annealing of Cu(B)/Ti/$SiO_2$ multilayer structure allowed the diffusion of B to the Ti surface and forming $TiB_2$ compounds at the interface. The formed $TiB_2$ can act as a excellent diffusion barrier against Cu-Ti interdiffusion up to $800^{\circ}C$. Also, the resistivity was decreased to $2.3\mu$$\Omega$-cm after annealing at $800^{\circ}C$. In addition, the presence of Ti underlayer promoted the growth Cu(l11)-oriented grains and allowed for normal growth of Cu(B) film. This is in contrast with abnormal growth of randomly oriented Cu grains occurring in Cu(B)/$SiO_2$ upon annealing. The Cu(B)/Ti/$SiO_2$ structure can be implemented as an advanced metallization because it exhibits the low resistivity, high thermal stability and excellent diffusion barrier property.

A Study on the Fabrication of Al/TiCp Composites by Liquid Mixing method(I) (액상교반법에 의한 AI/TiCp 복합재료의 제조에 관한 연구(I))

  • Im, Jong-Guk;Kim, Myeong-Han;Choe, Jae-Ha
    • Korean Journal of Materials Research
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    • v.3 no.5
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    • pp.529-537
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    • 1993
  • The mecllanical properties of AI/TiCp composite fabrication by liquid mixing was investigat ed. The composites, containing 10 wt% Tic. were producwi using induction furnace with mechanical stirring. The amounts of' 1.5wt% Mg were, added to wetting agents. Thr presence of aluminum in TiC composites showed rnhanced strengrh without loss of ductility at room and clrvated temperatures. Espe cially, wear resistance was found to dramatically irnprovc. I3ul excess stirring d~terrninrd the mect~ani~ cal properties. Approximate values at present work were 500 rpm. There was no inrerfacial reaction of any kind and the interface remains clearly deineated.

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Current Conservation Factors for Consistent One-Dimensional Neutronics Modeling

  • Lee, Kibog;Joo, Han-Gyu;Cho, Byung-Oh;Zee, Sung-Quun
    • Nuclear Engineering and Technology
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    • v.32 no.3
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    • pp.235-243
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    • 2000
  • A one-dimensional neutronics formulation is established within the framework of the nonlinear analytic nodal method such that it can result in consistent one-dimensional models that produce the same axial information as their corresponding reference three-dimension81 models. Consistency is achieved by conserving axial interface currents as well as the planar reaction rates of the three-dimensional case. For current conservation, flux discontinuity is introduced in the solution of the two-node problem. The degree of discontinuity, named the current conservation factor, is determined such that the surface averaged axial current of the reference three-dimensional case can be retrieved from the two-node calculation involving the radially collapsed group constants and the discontinuity factor. The current conservation factors are derived from the analytic nodal method and various core configurations are analyzed to show that the errors in K-eff and power distributions can be reduced by a order of magnitude by the use of the current conservation factor with no significant computational overhead.

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Improvement of Bonding Process and Bond Strength of HTPB Propellant/Liner using a Polymeric Curative (고분자 경화제를 사용한 라이너와 HTPB 추진제의 접착력 및 접착공정 개선)

  • Jeong Byung-Hun;Seo Tae-Seok;Hong Myung-Pyo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.10 no.2
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    • pp.110-114
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    • 2006
  • The study has been performed on the improvement of bonding process and bond strength of HTPB propellant and liner using a polymeric curative. In case of liner using polymeric curative prepared from reaction of HTPB and TDI, migration of curative was decreased at bond interface. So EPDM insulation sanding and Desmodur RE coating process could be omitted in motor case preparation and bond strengths between the HTPB propellant and liner were increased. Also deterioration phenomena of bond strength could not be observed in accelerated aging test.

CFD simulation of a prefilming air blast fuel nozzle (Prefilming air blast 연료 노즐의 다상유동 및 반응 유동장 수치해석)

  • Jung, Seungchai;Kim, Shaun;Park, Heeho;Ryu, Shiyang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.251-253
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    • 2017
  • Numerical study of air-blast type injector for low emission aircraft engines was conducted. Volume-of-fluids approach was used to track interface of fuel and air. Primary atomization of fuel stream was visualized, and thickness and mean velocity at the injector exit was calculated. Liquid fuel injected from fuel slots joined together as a thin film on preflimer surface, and interacted with swirling air. As instability on the fuel surface increased, separation of fuel as ligaments and droplets occured. The film thickness and velocity were used to as fuel injection boundary condition for reactive flow simulation. Primary reaction zone was formed in vicinity of the fuel nozzle, creating a stable flame inside the combustor.

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Development of Eye-Tracking System Using Dual Machine Learning Structure (이중 기계학습 구조를 이용한 안구이동추적 기술개발)

  • Gang, Gyeong Woo;Min, Chul Hong;Kim, Tae Seon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.7
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    • pp.1111-1116
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    • 2017
  • In this paper, we developed bio-signal based eye tracking system using electrooculogram (EOG) and electromyogram (EMG) which measured simultaneously from same electrodes. In this system, eye gazing position can be estimated using EOG signal and we can use EMG signal at the same time for additional command control interface. For EOG signal processing, PLA algorithms are applied to reduce processing complexity but still it can guarantee less than 0.2 seconds of reaction delay time. Also, we developed dual machine learning structure and it showed robust and enhanced tracking performances. Compare to conventional EOG based eye tracking system, developed system requires relatively light hardware system specification with only two skin contact electrodes on both sides of temples and it has advantages on application to mobile equipments or wearable devices. Developed system can provide a different UX for consumers and especially it would be helpful to disabled persons with application to orthotics for those of quadriplegia or communication tools for those of intellectual disabilities.