• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.825-827
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• 2002

The polymer encapsulation of white inorganic $TiO_2$ pigment particles was prepared by a two stage dispersion polymerization technique for applications in electrophoretic displays (EPDs). In order to give functionality for inorganic pigment particles in the EPD, we have investigated the density of the polymer encapsulated $TiO_2$ particles. The average density of the polymer encapsulated $TiO_2$ particles was 2.2 at 25$^{\circ}C$. The average density of the polymer encapsulated $TiO_2$ particles is suitable to 1.7, due to density matching with suspending media. Therefore, we will attempt density compatibility of dispersion polymerization technique for encapsulation of $TiO_2$ particles in suspending media.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.6
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• pp.3102-3107
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• 2013

Inorganic pigments were prepared from $Al_2O_3$, CoO, $Cr_2O_3$, ZnO, $SrO_2$ and Kaolin. The pigment was prepared through the processes of mixing and crushing of the raw materials, sintering, milling and drying. The color of the pigments was changed from blue to green as $Cr_2O_3$ contents in the pigment increased. The color became brighter irrespective of the pigment composition as pigment particle size became smaller. Maximum sintering temperature was the most suitable at around $1,250^{\circ}C$. In the test of compatability between the pigment and glaze, the color became close to green as $Cr_2O_3$ contents in the pigment increased, and became close to blue as CoO contents increased.

• Korean Journal of Materials Research
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• v.16 no.7
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• pp.422-429
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• 2006

Studies were performed on preparation of organic-inorganic hybrid silica dye in a dispersing ink system. The silica was subjected to surface modification using 3-aminopropyltrimethoxysilane (APTMS) in order to promote the chemical reactivity of the raw silica. On the surfaces of the aminosilane-functionalised silica, red vinylsulfone-containing azo dye was adsorbed. The dye was found to have chemically reacted with the aminosilane-grafted silica surface, which was proven by FT-IR spectra. Studies on morphology and microstructure were performed employing scanning electron microscopy. The SEM micrographs and particle size distributions showed that a homogeneous pigment can be obtained employing silica as a core. Particle size distribution was also examined using the technique of dynamic light scattering. The ensuing pigment was subjected to various physicochemical evaluation such as inkjet property, storage stability, color change as inkjet ink using printer, spectrophotometric, microscopic techniques. Studies on hybrid dyes from the silica surface demonstrated that, in general, stable pigments for inkjet dispersion ink were obtained.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.30 no.2
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• pp.189-195
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• 2004

Carbon black have not been used as pigment material in cosmetic because of very low density and dispersity, but carbon black have applicable character as black pigment because of non-toxic, stable physico-chemical property, and black colority. In this study, mesoporous silica samples were synthesized by sol-gel reaction using surfactants-template method; TEOS (tetraethoxysilane) - a) PEO/lecithin, b) PEO/polyethylene glycol, c) lecithin/polyethylene glycol in ethanol/water solution. Synthesized organic-inorganic hybrid - silica were heat-treated in N2 condition at 500$^{\circ}C$. Mesoporous silica with black carbon in pore have the effective density and show the good dispersity in both hydrophilic and hydrophobic solvent. Properties of the samples were measured; specific surface area (750㎡/g) and pore size (4-6nm) using BET, pore structure (cylindrical type) using XRD, morphology (spherical powder with 0.1-0.5$\mu\textrm{m}$ partical size) of the samples using SEM. Carbon-silica black color applied to mascara, it shows a dark black colority and good dispersity as compared with the general black color titania pigment. Moreover, it is possible to control the density of black color pigment because it is possible to control pore volume and particle size of mesoporous silica properly. It show the good volume effects in mascara. That is why possible to apply all kinds of cosmetic products.

• Journal of the Korean Applied Science and Technology
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• v.32 no.3
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• pp.528-535
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• 2015

Humanity has tended pursuing beauty. Pearls has been loved by many people for thousands of years as a symbol of wealth and status. Today, Artificial pearl were made using organic pigment due to bright colors and easy coating process. But the new coating technique is required due to low durability, weather resistance and difficulty of luxurious luster expression. This study, nitrocellulose and urethane were used as binder and inorganic pigment were used to expression of colors. Experimental variable of artificial pearl with nitrocellulose and solvent ratio, urethane and curing agent ratio, the amount of pearl number of coating, drying temperature and time, and coating technology was developed. The coated artificial pearl was evaluated with color-difference meter, ultraviolet ray resistance, promotion weathering. Urethane was better than nitrocellulose when compared with weather resistance, acid-alkalinity resistance.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.4
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• pp.153-159
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• 2015

Inorganic pigments have been received a great attention for various applications including paint, glazed ceramic ink, art tile, and building exterior due to their excellent thermal and chemical stability. Traditionally, the compositions of $PbCrO_4$, CdS and CdSe have been widely used as a yellow inorganic pigment. However, the use of these compositions has been restricted in recent years, because they contain harmful elements such as Cd, Cr, Pb and Se. In this study, new environment-friendly ceria-based pigment was synthesized using solid state reaction. Crystal structure and morphology of the obtained $Ce_{1-x}Zr_xBi_yO_{2-y/2}$ yellow pigment were analyzed using XRD and SEM, respectively. Substitutional effect of Zr and Bi on the pigment color was analyzed using UV-vis. spectrophotometer and CIE $L^*a^*b^*$ analysis. The crystal structure of the obtained pigments was dependent on the calcination temperature. The color characteristics and absorption band of the pigments were dependent on the calcination temperature and Zr, Bi contents. As a result, all the obtained yellow pigments showed the effective absorption ranged from ultraviolet to visible light, and $Ce_{0.44}Zr_{0.36}Bi_{0.20}O_{0.19}$ (x = 0.36, y = 0.20) pigment showed the most brilliant yellow color.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.1197-1205
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• 2018

UV protection cosmetics belong to functional cosmetics and contain organic or inorganic UV blocking pigments. The inorganic UV blocking pigments are mainly zinc oxide and titanium dioxide. It is known that inorganic UV blocking pigment has a diameter of 60 to 100 nm and has good blocking ability of UVA and UVB. Also, it has high inactivity against sunlight including UV and is excellent in safety. In addition, it is not absorbed or accumulated on the skin like organic pigments and does not cause skin irritation or allergy. In this study, mica, a plate-shaped inorganic pigment, nanosized titanium dioxide, an UV blocking material, and hydrophobic silica were surface-treated with surfactants. And then, titanium dioxide nanoparticles and silica were physically adsorbed on the mica by non-chemical mutual attraction due to differences in charge. Thereafter, the mica complex was surface-treated with silane to prepare a hydrophobic UV blocking pigment complex. The plate-shaped UV blocking composite improves the cohesiveness of a general nanoparticle material titanium dioxide, enhances UV blocking effect due to uniform dispersion, and can greatly improve dispersion stability in cosmetic formulations by surface treatment with hydrophobic property. The surface charge of the pigment was evaluated by zeta potential. The properties of the UV blocking pigment complex were evaluated by FE-SEM, XRD, FT-IR and UV-VIS.

• Journal of the Korean Society of Food Science and Nutrition
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• v.30 no.6
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• pp.1147-1151
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• 2001

We investigated stabilities of blue pigment extracted from Gardenia jasminoides at various conditions to check its applicability for beverages. Gardenia blue pigment with maximum absorption at 587 nm was obtained from the reaction of glycine and genipin (aglycone of geniposide). The blue pigment was found to be relatively unstable at acidic pH but very stable at alkaline conditions with half-life values of 102 days and 126 days at PH 9.0 and PH 11.0, respectively. The pigment also showed high thermal stability with half-life value of 55, 18, and 2 days at 50, 70, and 9$0^{\circ}C$, respectively. The addition of inorganic ions, sugars, and amino acids to model beverage containing this blue pigment increased retention rate at room temperature while addition of vitamin C decreased the stability. The sensory evaluation of the model beverage showed that inorganic ions and amino acids increased overall acceptability, indicating that the blue pigments of Gardenia jasminoides can be used as a natural colorant for leverage.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.5
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• pp.8-13
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• 2012

The flexography ink has disadvantage in a deinking process because it tends to form too fine particles in alkali condition to be removed in flotation deinking. The influence of pH conditions on the particle size of phthalocyanine cyan ink used for flexo-printing was investigated to see the effect of pH conditions on flexography ink dispersion. Flexography ink particles prepared by grinding dried ink films were used in this experiment. Greater reduction of the ink particle size was noticed under alkaline pH condition, which was attributed to dissolution of resin component of the ink. Adsorption behavior of flexography ink onto pigment particles was examined using clay and talc as substrate pigments. Pretreatment of inorganic pigments with a cationic poly-DADMAC increased the surface adsorption of flexography ink particles, which improved the removal of the inks by centrifugal sedimentation of inorganic pigments. Most efficient removal of the ink particles was achieved when an optimal addition level of the cationic polymer was used for pretreatment of inorganic pigments, and this optimal addition level corresponds to the surface saturation point of the polyelectrolyte. Adsorption of flexography ink particles onto inorganic pigments improved the ink removal in flotation deinking since the pigment particles has the optimal particle size for flotation deinking.

• Journal of the Korean Ceramic Society
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• v.56 no.3
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• pp.298-301
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• 2019

This paper details the synthesis of α-FeOOH (goethite) rods through the reaction of iron (III) nitrate with KOH as a strong base, and shape control of the particles for use as a yellow inorganic pigment. The crystal phase of the α-FeOOH crystal with OH content according to the addition of KOH and the change in morphology were investigated. The optical properties varied with the aspect ratios, and the yellowness increased with increasing aspect ratio. However, the enhanced chromaticity characteristics reversed beyond a certain critical aspect ratio. Thus, the relative optimal aspect ratio of the α-FeOOH rods as a vivid yellow inorganic pigment was derived. The morphology and coloration of the prepared rods were investigated in detail using X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis spectroscopy, and CIE Lab color parameter measurements.