• Title/Summary/Keyword: Inorganic mercury

Search Result 42, Processing Time 0.026 seconds

Preparations and Interfacial Phenomena of Hybrid Composites (Hycom) Containing Wasted Stone Powders and Tire Chips (폐석분과 폐타이어 칩을 충진제로 한 혼성복합재(Hycom)의 제조 및 계면현상 연구)

  • Hwang, Teak-Sung;Cha, Ki-Sik
    • Journal of Adhesion and Interface
    • /
    • v.2 no.1
    • /
    • pp.1-8
    • /
    • 2001
  • In this study, wasted stone powders (WSP) obtained from sludge and Wasted Tire Chips (WTC) as fillers have been used to formulate polymer hybrid composites based on Unsaturated Polyester (UPE) resin. To further enhance not only the interfacial bond between the inorganic filler and the polymer matrix, but also the filler dispersion by wetting the particulate surfaces to uniformly spread the resin during the mixing, silane coupling agent[${\gamma}$-methacryloxy propyl trimethoxy silane (${\gamma}$-MPS)] was used. The influences of organic recycled fillers contents and the concentrations of coupling agent in polymer hybrid composite formulations have been investigated from a mechanical and microstructural point o view through Mercury Porosimeter and SEM.

  • PDF

Biodynamic understanding of mercury accumulation in marine and freshwater fish

  • Wang, Wen-Xiong
    • Advances in environmental research
    • /
    • v.1 no.1
    • /
    • pp.15-35
    • /
    • 2012
  • Mercury (Hg) is a global environmental pollutant that has been the cause of many public concerns. One particular concern about Hg in aquatic systems is its trophic transfer and biomagnification in food chains. For example, the Hg concentration increases with the increase of food chain level. Fish at the top of food chain can accumulate high concentrations of Hg (especially the toxic form, methylmercury, MeHg), which is then transferred to humans through seafood consumption. Various biological and physiochemical conditions can significantly affect the bioaccumulation of Hg-including both its inorganic (Hg(II)) and organic (MeHg) forms-in fish. There have been numerous measurements of Hg concentrations in marine and freshwater fish worldwide. Many of these studies have attempted to identify the processes leading to variations of Hg concentrations in fish species from different habitats. The development of a biokinetic model over the past decade has helped improve our understanding of the mechanisms underlying the bioaccumulation processes of Hg in aquatic animals. In this review, I will discuss how the biokinetic modeling approach can be used to reveal the interesting biodynamics of Hg in fish, such as the trophic transfer and exposure route of Hg(II) and MeHg, as well as growth enrichment (the increases in Hg concentration with fish size) and biomass dilution (the decreases in Hg concentration with increasing phytoplankton biomass). I will also discuss the relevance of studying the subcellular fates of Hg to predict the Hg bioaccessibility and detoxification in fish. Future challenges will be to understand the inter- and intra-species differences in Hg accumulation and the management/mitigation of Hg pollution in both marine and freshwater fish based on our knowledge of Hg biodynamics.

Mercuric Chloride Induces Apoptosis in MDCK Cells (Mercuric Chloride에 의한 MDCK 세포의 세포사멸)

  • Lee, Ju-Hyoung;Youm, Jung-Ho;Kwon, Keun-Sang
    • Journal of Preventive Medicine and Public Health
    • /
    • v.39 no.3
    • /
    • pp.199-204
    • /
    • 2006
  • Objectives: Mercury is a hazardous organ-specific environmental contaminant. It exists in a wide variety of physical and chemical states, each of which has unique characteristics for the target organ specificity. Exposure to mercury vapor and to organic mercury compounds specifically affects the CNS, while the kidney is the target organ for inorganic Hg compounds. Methods: In this study, mercury chloride $(HgCl_2)$ was studied in a renal derived cell system, i.e., the tubular epithelial Madin-Darby canine kidney (MDCK) cell line, which has specific sensitivity to the toxic effect of mercury. MDCK cells were cultured for 6-24 hr in vitro in various concentrations (0.1-100 M) of $HgCl_2$, and the markers of apoptosis or cell death were assayed, including DNA fragmentation, caspase-3 activity andwestern blotting of cytochrome c. The influence of the metal on cell proliferation and viability were evaluated by the conventional MTT test. Results: The cell viability was decreased in a time and concentration dependent fashion: decreases were noted at 6, 12 and 24 hr after $HgCl_2$, exposure. The increases of DNA fragmentation were also observed in the concentrations from 0.1 to 10 M of $HgCl_2$ at 6 hr after exposure. However, we could not observe DNA fragmentation in the concentrations more than 25 M because the cells rapidly proceeded to necrotic cell death. The activation of caspase-3 was also observed at 6 hr exposure in the $HgCl_2$ concentrations from 0.1 to 10 M. The release of cytochrome c from the mitochondria into the cytosol, which is an initiator of the activation of the caspase cascade, was also observed in the $HgCl_2-treated$ MDCK cells. Conclusions: These results suggest that the activation of caspase-3 was involved in $HgCl_2-induced$ apoptosis. The release of cytochrome c from the mitochondria into the cytosol was also observed in the $HgCl_2-treated$ MDCK cells. These findings indicate that in MDCK cells, $HgCl_2$ is a potent inducer of apoptosis via cytochrome c release from the mitochondria.

Experimental study on treatment of waste slurry by vacuum preloading with different conditioning agents

  • Wu, Yajun;Jiang, Haibo;Lu, Yitian;Sun, Dean
    • Geomechanics and Engineering
    • /
    • v.17 no.6
    • /
    • pp.543-551
    • /
    • 2019
  • In China, serious environmental problems are induced by the extremely soft construction waste slurries in many urban areas, and there is no appropriate method to treat it presently. In this paper, four model tests were conducted to investigate the efficiency of waste slurry treatment by combining three conditioning agents which can change characteristics of the slurries with a traditional vacuum preloading method. The tests of size analysis of particle aggregate were conducted to investigate the influence of different conditioning agents on the size distributions of particle aggregate. During the model test, the discharged water volumes were monitored. The pore-size distribution and void ratio of the waste slurries after the vacuum preloading were measured by mercury intrusion porosimetry (MIP). It is found that 1) During the natural precipitation, volume of water out of the organic agent is higher than that of the mixed agent, but it is smaller than that of the mixed agent in the vacuum preloading stage; 2) the mixed agent has a higher total volume of water out than the organic agent and the inorganic agent after test, while the organic agent and the inorganic agent have little difference with respect to the drainage effect. The results demonstrate that the combination of mixed conditioning agent and vacuum preloading for the solid-liquid separation in waste slurry has a satisfactory effect and can be applied in engineering practice.

Influence of sodium selenite on oxygen free radical in mercuric chloride induced renal failure (Mercuric chloride 유발 신부전에서 산소유리기에 미치는 Sodium selenite의 영향)

  • Kim, Hyoung-Chun;Jhoo, Wang-Kee;Huh, In-Hoi
    • YAKHAK HOEJI
    • /
    • v.32 no.4
    • /
    • pp.287-293
    • /
    • 1988
  • Oxygen free radical have recently been found to mediate cell injury after ischemia in the kidney. The purpose of our study was to determine whether selenium had an effect on damge mediated by oxygen free radical in inorganic mercury induced renal failure, toxic model of renal failure. Toxic renal failure model was produced by subcutaneous injection of mercuric chloride (4mg/kg) once a day for 7 consecutive days. In additionally, coadministration of sodium selenite (1mg/kg) was performed by the same condition. As a consequence of this study, we were able to detect partially unequivocal role of selenium as below dipicted. The combination of sodium selenite showed that markedly inhibited production of superoxide radical in mercuric chloride alone. On the other hand, combined sodium selenite was unable to enhance against significantly lowered superoxide dismutase activity after mercuric chloride insult. However, simultaneous administration of sodium selenite was inclined to induce mitochondrial superoxide dismutase and catalase.

  • PDF

A Summary of Recent Pilot Machine and Commercial Machine Trials Comparing a New Microparticle Retention System with Existing Microparticle Technologies

  • Johnson, Gray;Gerli, Alessandra
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.34 no.5
    • /
    • pp.86-92
    • /
    • 2002
  • The benefits of high performance retention systems have been long recognized by the paper maker. The inter-relation between chemical retention and drainage and their effect on paper production efficiency and paper quality is significant. The subject of this paper is a summary of recent studies comparing three microparticle programs made under highly controlled pilot and commercial paper machine conditions. The results presented in this paper suggest that, in addition to improvements in machine operation, the retention, drainage and formation program can have a marked influence on the paper quality. Improvement of the topographical characteristics of the base paper was observed when the microparticle was a colloidal borosilicate inorganic oxide.

Uptake and Fate of Inorganic Mercury in the Eastern Oyster, Crassostrea virginica (이스턴 오이스터 Crassostrea virginica 에서 무기수은의 섭취와 축적)

  • Cho, Jung H.
    • Journal of Environmental Health Sciences
    • /
    • v.9 no.1
    • /
    • pp.63-76
    • /
    • 1983
  • 중금속은 해수에서보다 해수중의 생물계에 그 농도가 더 높은 것으로 알려져 있으며 수은도 무기형으로 생물계에 존재하다가 생물활동으로 인해 알킬형으로 변한다. food chain이 미량금속 축적의 주통로로 알려져 있으나 그외 몇가지 방법이 제시되고 잇다. 특히 연체동물은 미량금속의 축적현상이 온도, 폭로시간, 시간, 생리적 활동에 다라 상당히 달라진다. 또한 유기알킬 수은이 무기수은보다 비교적 낮은 독성을 나타내지만 후자의 피해도 무시할 수는 없다. 굴(crassostrea virginica)은 염화수은농도가 비교적 낮은 상태에서도 상\ulcorner량의 축적현상을 보여주었다. 두개의 compartment system을 연계적인 상태에서 보면 첫 compartment에서의 초기축적은 가역적이었으나 둘째 Compartment에서 측정된 원실율로 보아 비가역적 축적이상을 확인해 주었다. 뿐만 아니라 미량금속이 아가미와 외부 근육에서 가장 높은 축적률을 보인것은 flow system의 regression moder과 매우 흡사함을 암시하며 농도가 낮은 상태에서의 축적이상에 중요한 의미를 부여하였다.

  • PDF

Risk Analysis and Safety Assessment of Microbiological and Chemical Hazards in the Dried Sea Mustard Undaria pinnatifida Distributed in Markets (유통중인 건미역(Undaria pinnatifida)의 미생물학적·이화학적 위해요소 분석 및 안전성 평가)

  • Jeon, Eun Bi;Kim, Ji Yoon;Song, Min Gyu;Kim, Jin-Soo;Heu, Min Soo;Lee, Jung Suck;Park, Shin Young
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.54 no.6
    • /
    • pp.904-911
    • /
    • 2021
  • For the safety assessment of microbiological and chemical hazards in dried sea mustard, fifteen samples of dried sea mustards Undaria pinnatifida were purchased from the supermarkets distributed throughout Korea. The contamination levels of total viable bacteria, coliforms, Escherichia coli, and nine pathogenic bacteria [Staphylococcus aureus, Salmonella spp., Listeria monocytogenes, Bacillus cereus, Vibrio spp., Clostridium perfringens, Enterohemorrhagic Escherichia coli (EHEC), Yersinia enterocolitica and Campylobacter jejuni/coli] were quantitatively or qualitatively assessed. Also, the heavy metals (lead, cadmium, total mercury, and inorganic arsenic), and radioactivity (131I, 134CS+137CS) were quantitatively assessed. This microbial and chemical analysis was performed using standard methods in Korean food code. The total viable bacteria ranged from 4.3×102 (5.0×10-1.5×103) CFU/g. Coliforms and E. coli were not detected in all samples (ND, <1 log10 CFU/g). All nine pathogenic bacteria were qualitatively detected as negative. The contamination levels of lead, cadmium, total mercury, and inorganic arsenic were 0.036 (0.015-0.051), 0.117 (0.088-0.156), 0.030 (0.017-0.048), and 0.058 (0.056-0.064) mg/kg, respectively. Radioactivity was also not detected in any sample. The microbial contamination levels determined in the current study may be potentially used as basis for performing microbial risk assessments of dried sea mustards.

Monitoring of Ambient Air Particles and Inorganic Elements in China and Korea during an Asian Dust Storm

  • Park, Eun-Jung;Kim, Dae-Seon;Park, Chung-Hee;Song, Sang-Whan;Lee, Byung-Hoon;Hong, Yun-Chul;Pan, Xiaochuan;Wang, Jin-Gyu;Zhang, Yi-Xiang;Park, Kwang-Sik
    • Journal of Environmental Health Sciences
    • /
    • v.36 no.5
    • /
    • pp.360-372
    • /
    • 2010
  • Concentrations of ambient air particles such as total suspended particulates (TSP), particulate matter $(PM)_{10}$, and $PM_{2.5}$, were monitored simultaneously from May to June, 2007, at four locations at Alashan and Beijing in China, and Seoul and Gosan in South Korea. These monitoring sites are in the pathway of Asian dust (AD) storms traveling from China to the Korean peninsula. An AD event was observed in the Korean peninsula on May 25-26. During the sampling period, the average concentrations of TSP and PM10 were each higher than $150\;{\mu}g/m^3$ in Alashan and Beijing, but not in Seoul and Gosan. The concentration of TSP in Alashan (where the dust storm originated) on the day of the AD event reached $1824.7\;{\mu}g/m^3$, this being the highest concentration of air particles observed during the sampling period. The level was decreased to 15% of this ($274.7\;{\mu}g/m^3$) in Seoul and to 8.7% ($159.0\;{\mu}g/m^3$) in Gosan when the AD was observed two days later in Korea. Gosan, a representative background site in East Asia, displayed the lowest concentration of particles, with this maximal TSP concentration of $159\;{\mu}g/m^3$. Inorganic element contents in the air particles were also measured, and the concentrations in the four different regions compared. Concentrations of anthropogenically-enriched heavy metals in $PM_{10}$ and $PM_{2.5}$, such as lead, arsenic, cadmium, and mercury, were higher in the metropolitan cities of Beijing and Seoul compared to non-industrialized regions of Alashan and Gosan. However, the concentrations of inorganic soil elements including iron, magnesium, aluminum sodium, and manganese, were higher in Alashan compared to those in other sampling sites.

Nutritional Effects on the Environmental Health (영양과 환경과의 관계)

  • 문현경
    • Journal of environmental and Sanitary engineering
    • /
    • v.6 no.2
    • /
    • pp.17-31
    • /
    • 1991
  • The effects of environmental agents on health are great concern for all. It was recognized that each human has differential susceptibility to environmental effects. Susceptibility are changed by many factors includin gdevelopmpntal processes, genetic factors, nutritional stratus, preexisting disease conditions, life style and personal habits. Of all factors nutritional factors seem to be the area most modifiable. Consequently, It is an area that must be more thoroughly evaluated. In this paper, nutrient and environment interactions are reviewed briefly with published literatures. This paper deals with the influence of micronutrients(energy, protein and fat), Vitamins (vitamin 4, vitamin B-complex, vitamin C, vitamin D and vitamin I) and Minerals(calcium, iron, selenium, zinc and other minerls) on environmental effects. The role of arch nutrient was assessed in modifyine the expression of environmental pollutant toxicity with available litertures. In each nutrient section, the effect of environment was considered in following agents : heavy metals(lead, cadmium, mercury, silver and etc), inorganic agents(nitwits, sulfite, fluoride and etc), organic agents(benzene, carbon tatra-chloride, aflatoxin, auto dye, dialbrin etc), Irritant gas(ozone, carbon monooxide and etc), physical agents(X-irradiation, ultra violet, temperature and noise) and insectcides. The extent to which nutritional status modifies environmental effects 3nd its converse, how envirollments affects nutritional status is very complex. In deed, at the present time there are more than 50 chelnical/phycical agents that affect the nutrient metabolism and/or have their toxicity either directly diminished or enhanced by nutrients of those agents, small number of agents for each nutrients have sufficient evidence to warrant any reasonable degree of confidence in their hypothesized associtation. With these information at this present time it is hard to conclude that the recommended dietary allowance for each nutrient should be reconsidered.

  • PDF