• Resources Recycling
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• v.26 no.3
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• pp.32-38
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• 2017

For the massive recycling of mine tailings, which are an inorganic by-product of mining process, in the field of civil engineering, pretreatments to extract heavy metals are required. This study focuses on the use of pre-treated tailings as substitute fillers for controlled low-strength material (CLSM). As a comparative study, untreated tailing, microwave-treated tailing and magnetic separated with microwaved tailing were used in this study. Cement contents amounting to 10%, 20% and 30% by the weight of the tailings were designed. Both compressive strength and flowability for all types of mixture were satisfied with the requirements of the American Concrete Institute (ACI) Committee 229, i.e., 0.3-8.3 MPa of compressive strength and longer than 200 mm flowability. Furthermore, all mixtures showed settlements less than 1% by volume of the mix.

• Journal of Adhesion and Interface
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• v.3 no.4
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• pp.44-52
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• 2002

Composite materials are created by combining two or more component to achieve desired properties which could not be obtained with the separate components. The use of reinforcing fillers, which can reduce material costs and improve certain properties, is increasing in thermoplastic polymer composites. Currently, various inorganic fillers such as talc, mica, clay, glass fiber and calcium carbonate are being incorporated into thermoplastic composites. Nevertheless, lignocellulose fibers have drawn attention due to their abundant availability, low cost and renewable nature. In recent, interest has grown in composites made from lignocellulose fiber in thermoplastic polymer matrices, particularly for low cost/high volume applications. In addition to high specific properties, lignocellulose fibers offer a number of benefits for lignocellulose fiber/thermoplastic polymer composites. These include low hardness, which minimize abrasion of the equipment during processing, relatively low density, biodegradability, and low cost on a unit-volume basis. In spite of the advantage mentioned above, the use of lignocellulose fibers in thermoplastic polymer composites has been plagued by difficulties in obtaining good dispersion and strong interfacial adhesion because lignocellulose fiber is hydrophilic and thermoplastic polymer is hydrophobic. The application of lignocellulose fibers as reinforcements in composite materials requires, just as for glass-fiber reinforced composites, a strong adhesion between the fiber and the matrix regardless of whether a traditional polymer matrix, a biodegradable polymer matrix or cement is used. Further this article gives a survey about physical and chemical treatment methods which improve the fiber matrix adhesion, their results and effects on the physical properties of composites. Coupling agents in lignocellulose fiber and polymer composites play a very important role in improving the compatibility and adhesion between polar lignocellulose fiber and non-polar polymeric matrices. In this article, we also review various kinds of coupling agent and interfacial mechanism or phenomena between lignocellulose fiber and thermoplastic polymer.

• Resources Recycling
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• v.3 no.3
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• pp.27-31
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• 1994

We tested the limestone sludge produced in Pohang Iron & Steel Co., Ltd. as a filler powder for the effective use of portland cement. Hydration process was investigated by measuring the hydration rate, the amounts of non-evaporable water and compressive strength of cement-limestone sludge paste prepared by mixing limes-tone sludge with cement. The results obtained in this study can be summarized as follows: 1. There is no significant difference between the cases of adding up to 10% limestone sludge and those of unmixed cement system. However the reaction rate increases in the 5% limestone sludge system(due to the effects of fine). 2. The compressive strength increases proportionally with increasing the measured amount of non-evaporable water, Adding 5% limestone sludge also increases the strength a little higher, and the compressive strength and calcium silicate hydrates. In the case of the mixed limestone sludge, $2\theta$=$11.7^{\circ}$ peak appears in the samples of 28 days hydration. This peak indicted the presence of calcium carboaluminate hydrate. Although limestone sludge is generally regarded as a inert materials, some kinds of cement can produce a calcium carboaluminate by reacting with aluminate in cement pastes.

• Journal of Conservation Science
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• v.28 no.2
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• pp.141-151
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• 2012

It was the 1900s that the damaged materials of stone heritages began to be preserved and managed for the purpose of reuse, especially since cement, an inorganic material, began to be used during the Japanese colonial period. Epoxy resin, an organic material, was introduced to architecture around the turn of the 1990s, and has been being used across the board. In particular, filler mixtures began to be aggressively used for the structural reinforcement of severed materials. The problem was metal stiffeners used for structural reinforcement. The anchorage length varied depending in different conservation scientists, and as a result the secondary damage was apt to occur in the materials. In this study, hereat, a calculation was made of the most effective anchorage length with the minimization of material damage. The results were as in the following: the anchorage length of an 8-milimeter-across (ø8) metal stiffener was found to be most effective at 60.88mm. Those of ø12 and ø16 were 60.88mm and 91.32mm respectively. In the case of other calibers, the anchorage length was calculated by a formula ${\ell}_d=a_tf_y/u{\Sigma}_0$. In the experiment, helically-threaded round bars were used as metal stiffeners in order that they could bear surcharge loads such as bending, shear and constriction.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.29 no.1
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• pp.36-42
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• 1997

The fiber wall filling(FWF) technology, which is based on Precipitatin of fillers in the micropores of the cell wall structure of never-dried chemical pulp fiber, has been developed to improve filling and loading process in papermaking. In presenting FWF technique here, micropores of pulp fiber are first impregnated with an ionic solution of water soluble salt and consecutively impregnated with the second salt solution. This procedure generates an insoluble precipitate within the micropores of cell wall by chemical interaction of these two ionic salt solutions This is the first attempts to use FWF technology for the quality of waste paper grade which is recycled in papermaking, even though this FWF technology has been impressively improved for never-dried chemical pulp in filling and loading process of papermaking. The precipitated amount of CaCO$_3$ and SrCO$_3$ reached 5-6% and 4-5% of the waste paper weight respectively, which was measured by ash content of the burned waste paper fiber. On the other way the precipitated amounts of those materials impregnated into never-dried chemical pulp fiber have reached 17-18% and 16-18% respectively. The micropore loading technique gives optical and physical properties to the handsheets formed with celt-wall-filled fibers which are better than those handsheet properties resulting from conventional loading. The papers made from the cell-wall-filled pulps are stronger than those with the customary location of filler between the fibers.

• Journal of Conservation Science
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• v.25 no.3
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• pp.323-333
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• 2009

The Jincheonsagongnimaaeyeoraeipsang is a great stone relief Buddha in Goryeo Dynasty, transmitting sculptural styles of the Silla Kingdom. The Buddha was carved on the biotite granite basement, and was undergone cleaning treatment in 2007. The basement rock was opened in plenty cracks bringing out structural instability. And the top of the basement rock was colonized by trees obstructing sunshine and raising humidity. As a result of failure analysis, the basement rock of the Buddha had a major possibility of wedge failure in the parts of the face, hands and cloths. Therefore, the cracks were filled up with epoxy resin L-50, and titanium bars and wire ropes were applied to bind cracked rock blocks. The surface of the crack filler was colored by granite and talc powder with inorganic pigment and L-30. The crack meters were installed on the stone relief Buddha to monitor further behavior, lastly.

• Korean Chemical Engineering Research
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• v.54 no.2
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• pp.145-151
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• 2016

In response to the cavitation caused by the partial vacuum caused by the fluid flow, a paint was developed by dispersing the lamella-shaped glass-flake in resin for anti-cavitation. This composite paint was developed by using the inorganic filler (lamella shaped glass-flake) and the NBR (Acrylonitrile-butadiene rubber) which was modified epoxy resin. Especially, the glass-flake was a thin film with a thickness of about 100~200 nm and length of about $20{\sim}30{\mu}m$, the aspect ratio was about 200 to 300 times that of the plate-shaped. So the paint for anti-cavitation have shown excellent performance in corrosion resistance. The results of evaluating anti-cavitation performance was below, tensile strength $4.8{\sim}6N/mm^2$ or more, rupture elongation 30% or higher, abrasive speed $10mm^2/h$ or less. In particular, it showed more than twice the superior performance compared to existing advanced foreign products in anti-cavitation performance evaluation.

• Restorative Dentistry and Endodontics
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• v.25 no.1
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• pp.123-132
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• 2000

To overcome problems of conventional glass ionomers, resin components have been added to glass ionomers. On a continuum between glass ionomers and composites are a variety of blends, employing different proportions of acid-base and free radical reactions to bring about cure. Popular groups defined between the ends are resin-modified glass-ionomers(RMGIs), polyacid-modified composite resins(Compomers) and ionomer modified resins. These groups show different clinical properties, and in selecting these materials for a restoration, one should sufficiently understand these different setting properties. In this study, some difference in the setting characteristics of different groups of hybrid ionomers were examined. Two RMGIs (Fuji2 LC,GC / Vitremer, 3M), three Compomers (Dyract AP, Dentsply / F2000, 3M / Elan, Kerr) were involved in this study. The identification of the setting characteristics of different groups was achieved by a two-stage study. First, thermal analysis was performed by a differential scanning calorimeter, and then the hardness of each group at different depth and time were measured by a micro-hardness tester. Thermal analysis was performed to identify the inorganic filler content and to record the heat change during setting process. The setting process was progressed for each material by chemical set mode and light-cured mode. In the hardness test, samples of materials were prepared with a 6mm-diameter metal ring, and the hardness was measured at the top, and 1mm, 2.5mm, 4mm below at just after a 40 second-cure, and after 10 minutes, 24 hours, and 7 days. Statistical analysis was performed by Mann-Whitney rank sum test to assess significant differences between set modes and types of materials, and by ANOVA and T-test to evaluate the statistical meanings of data at different times and depths of each materials. Followings are findings and conclusions derived from this study. Thermal analysis; 1. Compomers show no evidence of chemical setting while RMGIs exhibit heat output during the process of chemical setting. 2. Heat of cure of RMGIs exceed Compomers. 3. The net heat output of RMGIs through light-cured mode is higher than through chemically set mode. Hardness test; 1. Initial hardness of RMGIs immediately after light cure is relatively low, but the hardness increases as time goes by. On the contrary, Comomers do not show evident increase of the hardness following time. 2. Compomers show a marked decrease of setting degree as the depth of the material increases. In RMGIs, the setting degree at different depths does not significantly differ.

• Polymer(Korea)
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• v.28 no.5
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• pp.426-432
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• 2004

To reduce volumetric shrinkage of the commercially available polymeric dental composite during curing reaction, (2,2-bis [4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (bis -GMA) derivatives, i.e., (2,2-bis[3-methyl, 4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propan) (DMBis-GMA) and (2,2-his [3,5-dimethyl ,4- (2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (TMBis-GMA) were synthesized and then new dental composite resin composed of Bis-GMA derivatives, diluent, spiro orthocarbonate (SOC), and inorganic filler was produced. Among the Bis-GMA derivative/Bis-GMA derivative/diluent mixtures, Bis-GMA/ TMBis-GMA/TEGDMA mixture exhibited the lowest volumetric shrinkage. Volumetric shrinkage of this mixture was further reduced by adding SOC. Volumtric shrinkage of dental composite prepared from commercially available resin monomer mixture was $2.5\%$, while that prepared from resin monomer mixture having minimum volumetric shrinkage was reduced to $0.7\%$. Mechanical strength of this dental composite was nearly the same with that of commercial products but the time required for the curing reaction was retarded.

• Membrane Journal
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• v.16 no.4
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• pp.268-275
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• 2006

Novel SILEMs were prepared by multi-stage phase separation process combined by the low temperature phase separation (LTPS) and the high temperature phase separation (HTPS) using room temperature ionic liquids (RTILs) which have a high ionic conductivity. PVDF and imidazolium series ionic liquids were used as membrane material and electrolyte, respectively. To study the ion conducting properties, the SILEMs were tested using LCR meter at temperature controlled from 30 to $130^{\circ}C$. Under humid conditions, with increasing temperature from 30 to $100^{\circ}C$, the ion conductivity of the cast $Nafion^{(R)}$ membrane increased linearly, but then started to decrease after $100^{\circ}C$. However, in the case of the SILEMs, with increasing operating temperature, the ion conductivity increased. Also, the ion conductivity behaviors of the SILEMs were almost same, regardless of humidity. The ion conductivity of the SILEMs was $2.7{\times}10^{-3}S/cm$ and increased almost linearly up to $2.2{\times}10^{-2}S/cm$ with increasing temperature to $130^{\circ}C$. The effects of an inorganic filler on the physical properties of the SILEMs were studied using the $SiO_2$. The addition of $SiO_2$ could improve the mechanical strength of the SILEMs, though the ionic conductivity was decreased slightly.