• 제목/요약/키워드: Inorganic filler

검색결과 141건 처리시간 0.024초

무기질 충진재와 폴리우레탄을 활용한 유·무기 복합 단열소재의 특성 평가 (Evaluation of Organic-Inorganic Hybrid Insulation Material Using Inorganic Filler and Polyurethane)

  • 이종규;소정섭;노현경
    • 한국재료학회지
    • /
    • 제22권11호
    • /
    • pp.604-608
    • /
    • 2012
  • Recently, inorganic-organic hybrid materials have attracted much attention not only for their excellent thermal conductivity but also for their flame retardant properties. In this study, the properties of organic-inorganic hybrid insulating materials using inorganic fillers and polyurethane foam with different foaming conditions have been investigated. The addition of 1.5 wt% water to polyurethane as foaming agent shows the best foaming properties. The pore size was decreased in the foaming body with increasing of the $CaCO_3$ addition. The apparent density and thermal conductivity were increased by increasing the $CaCO_3$ addition. With an increasing amount of $CaCO_3$ powder, the flame retardant property is improved, but the properties of thermal conductivity and apparent density tend to decrease. When the addition of fine particles of $CaCO_3$, the apparent density and thermal conductivity were increased and, also, with the addition of coarse particles over $45{\mu}m$ in size, the apparent density and thermal conductivity were increased as well. In this study, the adding of $CaCO_3$ with average particle size of $27{\mu}m$ led to the lowest thermal conductivity and apparent density. After evaluation with different inorganic fillers, $Mg(OH)_2$ showed the highest thermal conductivity; on the other hand, $CaCO_3$ showed the lowest thermal conductivity.

신문용지 제조에 있어서 무기 충전제들의 영향 (Effect of Inorganic fillers in Newsprint Papermaking)

  • 채규윤;이준구;김성권
    • 공업화학
    • /
    • 제9권7호
    • /
    • pp.961-967
    • /
    • 1998
  • 종이제조에 있어서 종이의 광학적 성질 및 인쇄적성을 개선하기 위하여 여러 종류의 충전제가 사용되고 있다. 본 연구는 신문용지 제조에 있어서 여러 종류의 충전제, 즉 경질탄산칼슘(PCC), 중질탄산칼슘(GCC), 그리고 혼합된 충전제(PCC+미세활석(MVP) 또는 활석(talc), GCC+MVP 또는 talc))를 종이에 충전시켰을 때 종이의 여러 물성에 미치는 영향을 검토하였다. 얻어진 결과를 요약하면 다음과 같다. 1) 충전제를 지료전건중량당 5% 처리시 동일 처리조건하에서의 충전제 보류율은 PCC 처리시 GCC 처리시보다 16.8% 정도 높게 나타났으며, PCC 및 GCC를 처리했을 때 모두, 배합한 충전제의 입자경이 커질수록($PCC{\leq}GCC<MVP<talc$) 보류율이 증가하는 경향을 나타내었다. 2) PCC 처리시 무처리보다(92.2%) 대비 2.3% 이상의 비교적 높은 불투명도 개선효과를 나타내었으며, 배합한 충전제의 평균 입자경이 클수록 불투명도가 감소하는 경향을 나타내었다. 3) PCC 단독 처리시 GCC 단독 처리시보다 소폭의 인열강도 하락을 나타내었으며 20% 배합처리한 충전제의 평균 입자경이 커질수록 인열강도가 증가하는 경향을 나타내었다. 4) PCC 단독처리시 비교적 높은 인장강도를 나타내었으며, 다른 충전제와 혼합처리시 인장강도의 하락폭은 GCC 처리쪽이 적은 것으로 나타났다. 5) PCC를 처리하였을 경우, 배합한 충전제의 입자경이 커질수록 ($PCC{\leq}GCC<MVP<talc$) 파열강도는 직선적으로 감소하였다. 6) 충전제를 처리하였을때 무처리보다 비교적 우수한 인쇄적성 효과를 나타내었다.

  • PDF

Enhancement of Cycle Performance of Lithium Secondary Batteries Based on Nano-Composite Coated PVdF Membrane

  • Ryou, Myung-Hyun;Han, Young-Dal;Lee, Je-Nam;Lee, Dong-Jin;Park, Jung-Ki
    • 전기화학회지
    • /
    • 제11권3호
    • /
    • pp.190-196
    • /
    • 2008
  • The multilayered membrane for lithium rechargeable batteries based on poly (vinylidene fluoride) (PVdF) is prepared with the coated layer containing nano-sized filler. The prepared membranes were subjected to studies of mechanical strength, morphology, interfacial stability, impedance spectroscopy, ionic conductivity, and cycle performance. The localized inorganic filler in the PVdF composite membrane rendered mechanical strength much reduced because of its low stretching ratio and it results in around half value of the mechanical strength of highly stretched PVdF membrane. In order to achieve high ionic conductivity and interfacial stability without sacrificing high mechanical strength, coating layer with nano-filler was newly introduced to PVdF membrane. The ionic conductivity of the coated membrane was 1.03 mS/cm, and the interface between the coating layer and PVdF membrane was stable when the membrane was immersed into liquid electrolyte. The discharge capacity of the cell based on nano-filler coated PVdF membrane was around 91% of the initial discharge capacity after 250 cycles, which is an improvement in cycle performance compared to the case for the non-coated PVdF membrane.

무기충전제로서 저회의 적용특성 평가 (Evaluation of Applicability of Bottom Ash as Inorganic Filler)

  • 오민택;성용주
    • 펄프종이기술
    • /
    • 제44권5호
    • /
    • pp.80-86
    • /
    • 2012
  • The disposal of the bottom ash originated from a thermoelectric power plant which used the pulverized coal, has been an important issue of the power plants. In order to find the possible way of recycling of the bottom ash, the applicability of the bottom ash as an inorganic filler for paper making was investigated in this study. The pretreatment with acid were applied for upgrading the properties of bottom ash. The effects of the addition of the bottom ash to the different pulp stocks, Sw-BKP, DIP(Deinked Pulp), Sw-UBKP were evaluated in terms of the change in paper properties. The brightness and tensile strength decreased as the increase of the amount of the bottom ash addition. The bulk and the opacity were increased by the addition of bottom ash. The pretreatment of bottom ash resulted in the increase of improvement of the brightness and the strength properties comparing with those of untreated bottom ash.

펄프 조성 및 무기 충전제가 담배 연포장지 물성에 미치는 영향 (Effects of pulp composition and inorganic fillers in the furnish on the properties of parcel wrapper for cigarettes)

  • 서만석;임병삼;문성열;김종열;나도영
    • 한국연초학회지
    • /
    • 제32권1호
    • /
    • pp.12-18
    • /
    • 2010
  • The parcel wrapper for cigarettes has been used as the package and media materials for protection and design of product brands. The design of parcel wrapper has been contributed to the delivery of brand image and motivated consumer to purchase the brand. Therefore, the properties of parcel wrapper have been paid attention to highlight the design image, and increasing opacity of media materials has been one of the effective ways to obtain clear design on the paper surface. This study was carried out to improve the opacity of parcel wrapper for cigarettes. The effects of pulp composition and inorganic fillers in the furnish on the optical and mechanical properties were investigated. The use of hardwood in the stock preparation gave the increased opacity of paper than that of softwood. The application of higher refractive indices of fillers was effective to improve opacity. Brightness, tensile strength and stiffness were affected by the retained filler amount on the paper. Increase of filler contents decrease the tensile strength and stiffness due to the lesser bonding ability of fibers.

투명 유-무기 하이브리드 하드코팅 필름 제조 및 SiO2 또는 ZrO2함량에 따른 필름의 물성 (Preparation of Transparent Organic-Inorganic Hybrid Hard Coating Films and Physical Properties by the Content of SiO2 or ZrO2 in Their Films)

  • 설현태;나호성;권동주;김정섭;김대성
    • 한국재료학회지
    • /
    • 제27권1호
    • /
    • pp.12-18
    • /
    • 2017
  • Transparent organic-inorganic hybrid hard coating films were prepared by the addition of $SiO_2$ or $ZrO_2$, as an inorganic filler to improve the hardness property, filler was highly dispersed in the acrylic resin. To improve the compatibility in the acrylic resin, $SiO_2$ or $ZrO_2$ is surface-modified using various silanes with variation of the modification time and silane content. Depending on the content and kind of the modified inorganic oxide, transparent modified inorganic sols were formulated in acryl resin. Then, the sols were bar coated and cured on PET films to investigate the optical and mechanical properties. The optimized film, which has a modified $ZrO_2$ content of 4 wt% markedly improved in terms of the hardness, haze, and transparency as compared to neat acrylate resin and acrylate resin containing modified $SiO_2$ content of 8 wt%. Meanwhile, the low transparency and high haze of these films slowly appeared at $SiO_2$ content above 10 wt% and $ZrO_2$ content of 5 wt%, but the hardness values were maintained at 2H and 3H, respectively, in comparison with the HB of neat acrylate resin.

치과 수복재용 복합레진의 기계적 물성에 대한 연구 (Mechanical properties of composite resins for dental restorative)

  • 류호남;이광래
    • 산업기술연구
    • /
    • 제35권
    • /
    • pp.31-34
    • /
    • 2015
  • The purpose of the study was to investigate the mechanical properties (diametral tensile strength, flexural strength, compressive strength, Vickers hardness) of 4 kinds of composit resins; Bis-GMA based composit, Bis-EMA based composit, Bis-GMA/UDMA based composit, and Bis-EMA/UDMA based composit, The composit resin based Bis-GMA showed stronger mechanical properties than Bis-EMA. It was found that the addition of UDMA to both Bis-GMA based composit and Bis-EMA based composit highly improved mechanical properties. However, the mechanical properties of the composit resins prepared in this study were lower than those of the commercialized products in market(Charmfil flow(Denkist), Quadrant flow(CAVEX)), since the composit resins prepared in this study has much lower inorganic filler content of 43wt% comparing with 50~70wt% inorganic filler content of the commercialized products.

  • PDF

유리섬유/에폭시 복합절연재료의 계면 접착력 개선에 관한 연구 1

  • 이종호;황영한;이규철
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제8권2호
    • /
    • pp.136-143
    • /
    • 1995
  • With the contact angle of phase dropping epoxy resin on the inorganic filler(glass plate) surface treated with air plasma, we have studied about the interfacial wettability between epoxy resin and glass plate as a simple model of glass fiber reinforced composite materials. The contact angle on the inorganic filler surface varied with surface treatment conditions. The contact angle significantly depends on plasma treating time and environment temperature in the oven. From the view point of plasma treatment condition in this work, when discharge conditions were pressure 200mtorr, voltage 800V, magnetic flux density 8OGauss, optimum treatment time were proved as 3,4 and 5 minutes for the environment of >$80^{\circ}C$, >$100^{\circ}C$ and >$120^{\circ}C$, respectively.

  • PDF