• Title/Summary/Keyword: Inorganic chemistry

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Effect of FeOX Inorganic Additive in SAGD Process for Oil Sand Recovery (고온 고압 스팀을 주입하는 SAGD 공정에서 FeOX 무기첨가제가 오일샌드 회수율에 미치는 영향)

  • Song, Byung Jin;You, Nansuk;Kim, Ji Man;Lee, Chul Wee
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.113-115
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    • 2014
  • Lab scale simulated steam assisted gravity drainage (SAGD) process devices were used to investigate the effect of inorganic additives for the bitumen recovery from oil sand. An extra heavy oil similar with bitumen and 1.5 mm diameter of the glass bead instead of clay was mixed to simulate the oil sand. In addition, $FeO_X$ synthesized from the inorganic process was introduced as an inorganic additive for improving the recovery. Finally, the steam heat transfer rate of approximately 40% following the introduction of inorganic additives which also increased the recovery rate by about 30%.

Synthesis and Characterization of New Organotin (IV)-phenylenebisdithiocarbamate Complexes

  • Lee, Won-Ho;Jung, Ok-Sang;Sohn, Youn-Soo;Kim, Poong-Zag
    • Bulletin of the Korean Chemical Society
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    • v.7 no.6
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    • pp.421-425
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    • 1986
  • New di- and triorganotin(IV) complexes of meta- and para-phenylenebisdithiocarbamate(m- and p-pbdtc) have been synthesized and characterized by means of chemical analysis, mass spectrometry, and IR spectroscopy. The reaction of the m-pbdtc ligand with diorganotin(IV) halides resulted in 1:1 products, $R_2Sn{\cdot}m$-pbdtc (R = Me, Cy, n-Bu) of dimeric nature whereas the p-pbdtc ligand led to an oligomeric or polymeric structure. The pbdtc ligands were also reacted with triorganotin(IV) halides to form monomeric complexes, $(R_3Sn)_2{\cdot}pbdtc.$ The tin coordination chemistry of these complexes were also discussed in terms of Sn-C and Sn-S bonding modes.

Bistability of $Co^{III}$(N-N)(3,6-DBSQ)(3,6-DBCat):Subtle Diimine Ligand Effect (N-N=4,7-Dimethyl-1,10-phenanthroline, 5-Chloro-1,10-phenanthroline;DBSQ=Di-tert-butylsemiquinonato;DBCat=Di-tert-butylcatecholato)

  • Ok-Sang Jung;Young-A Lee;Younkyoo Kim;Youn Soo Sohn
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.641-643
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    • 1994
  • Studies of Co(N-N)(3,6-DBSQ)(3,6-DBCat)(N-N=4,7-dimethyl-1 ,10-phenanthroline, 5-chloro-1,10-phenanthroline; DBSQ=di-tert-butylsemiquinonato; DBCat=di-tert-butylcatecholato) have been carried out on the bistability by intramolecular cobalt-quinone electron transfer in solid state. The title complexes dominantly exist as $Co^{III}$(N-N)(3,6-DBSQ)(3,6-DBCat) at room temperature and display a significant bistability on temperature variation. Subtle change in optical spectra and magnetic properties is observed when diimine ligands are changed.

One Pot Synthesis and Characterization of Alginate Stabilized Semiconductor Nanoparticles

  • Sundarrajan, Parani;Eswaran, Prabakaran;Marimuthu, Alexander;Subhadra, Lakshmi Baddireddi;Kannaiyan, Pandian
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3218-3224
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    • 2012
  • Uniform and well dispersed metal sulfide semiconductor nanoparticles incorporated into matrices of alginate biopolymer are prepared by using a facile in situ method. The reaction was accomplished by impregnation of alginate with divalent metal ions followed by reaction with thioacetamide. XRD analysis showed that the nanoparticles incorporated in the polymer matrix were of cubic structure with the average particle diameter of 1.8 to 4.8 nm. Field emission scanning electron microscopy and high resolution transmission electron microscopy images indicated that the particles were well dispersed and distributed uniformly in the matrices of alginate polymer. FT-IR spectra confirmed the presence of alginate in the nanocomposite. The crystalline nature and thermal stability of the alginate polymer was found to be influenced by the nature of the divalent metal ions used for the synthesis. The proposed method is considered to be a simple and greener approach for large scale synthesis of uniform sized nanoparticles.

Colorimetric Evaluation of the Time-Killing Assay for Citropin 1.1, Lipopeptide Palm-KK-$NH_2$, and Temporin A

  • Baranska-Rybak, Wioletta;Dawgul, Malgorzata;Bielinska, Sylwia;Kraska, Bartlomiej;Piechowicz, Lidia;Kamysz, Wojciech
    • Journal of Microbiology and Biotechnology
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    • v.21 no.5
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    • pp.536-539
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    • 2011
  • Nowadays, there are a number of colorimetric techniques available for the determination of a time killing assay in a manner much easier and faster than those previously more commonly used, which were much more time-consuming and laborious colony counting procedures. Here, an attempt has been made to test the antimicrobial peptides of Citropin 1.1, Palm-KK-$NH_2$, and Temporin A on a reference strain of Staphylococcus aureus using resazurin as the cell viability reagent. Staphylococcus aureus was exposed to the test compounds over varying periods of time and the metabolic activity measured, with a profile of antimicrobial activity then established. The results are in agreement with data from previous literature, thus confirming the relevance of the application of resazurin for the testing of antimicrobial agents.

COMPOSITION OF SUPERCONDUCTING YBCO THIN FILMS WITH RF REACTIVE SPUTTERING CONDITIONS

  • Kim, H.H.;Kim, S.;Shin, S.H.;Park, J.I.;Park, K.J.
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.829-833
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    • 1996
  • Superconducting YBaCuO thin films were deposited on MgO (100) single crystal substrate by rf reactive sputtering method. Sputtering target was prepared by mixing the original powders of $Y_2O_3$, $BaCO_3$, and CuO at $830^{\circ}C$, and its composition was $YBa_2Cu_{3.3}O_x$ adding the excess CuO to compensate for the loss of Cu in the deposition process. The sputtering conditions for a high quality of YBCO thin film were: substrate temperature of 13$0^{\circ}C$; gas pressure of 10 mTorr; gas mixture ($O_2$: Ar =10: 90); distance of 2.5 inch; and rf power density of 4.87 W /$\textrm{cm}^2$. The deposition rate was 2.4~2.6 nm/min. From the RBS results, it was found that Cu and Ba contents in thin films decreased with the increase of substrate temperature. The increase of gas pressure resulted in significant deficiency of Ba elements.

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