• Title/Summary/Keyword: Inorganic Synthesis

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Carbon-allotropes: synthesis methods, applications and future perspectives

  • Karthik, P.S.;Himaja, A.L.;Singh, Surya Prakash
    • Carbon letters
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    • v.15 no.4
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    • pp.219-237
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    • 2014
  • The element carbon has been used as a source of energy for the past few hundred years, and now in this era of technology, carbon has played a significant and very prominent role in almost all fields of science and technology. So as an honour to this marvellous element, we humans should know about its various forms of existence. In this review article, we shed light on all possible carbon-allotropes; similarities in their synthesis techniques and the starting materials; their wide range of possible availability; and finally, future perspectives and applications. A brief introduction is given on the types, structures, and shapes of the allotropes of carbon for a better understanding.

Synthesis of Polycarbosilane for SiC Precursor (SiC의 Pricursor Polycarbosilan의 합성)

  • Han, Chul;Han, In-Seop;Lee, Hyung-Bock;Chung, Yun-Joong
    • Journal of the Korean Ceramic Society
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    • v.25 no.1
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    • pp.49-53
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    • 1988
  • Polycarbosilane was synthesized from the pyrolysis of polydimethylsilane, which is dechlorinated from dimethyldichlorosilane. The pyrolysis temperature was varied at 280-480$^{\circ}C$ for 2 hours. FT-IR, FT-NMR and GPC measurement were studied on the residue inside the reaction crucible and viscous solution inside the cooling zone respectively. From the viscous solution in the cooling zone at 420$^{\circ}C$, the synthesis of polycarbosilane wa well detected.

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One Pot Synthesis and Characterization of Alginate Stabilized Semiconductor Nanoparticles

  • Sundarrajan, Parani;Eswaran, Prabakaran;Marimuthu, Alexander;Subhadra, Lakshmi Baddireddi;Kannaiyan, Pandian
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3218-3224
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    • 2012
  • Uniform and well dispersed metal sulfide semiconductor nanoparticles incorporated into matrices of alginate biopolymer are prepared by using a facile in situ method. The reaction was accomplished by impregnation of alginate with divalent metal ions followed by reaction with thioacetamide. XRD analysis showed that the nanoparticles incorporated in the polymer matrix were of cubic structure with the average particle diameter of 1.8 to 4.8 nm. Field emission scanning electron microscopy and high resolution transmission electron microscopy images indicated that the particles were well dispersed and distributed uniformly in the matrices of alginate polymer. FT-IR spectra confirmed the presence of alginate in the nanocomposite. The crystalline nature and thermal stability of the alginate polymer was found to be influenced by the nature of the divalent metal ions used for the synthesis. The proposed method is considered to be a simple and greener approach for large scale synthesis of uniform sized nanoparticles.

Synthesis of Tungsten Carbide Powders by SHS Method (SHS법에 의한 탄화텅스텐 분말 합성)

  • Jun, H.B.;Cho, D.H.;Lee, H.B.;Park, S.
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1159-1168
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    • 1994
  • We powders were synthesized from W powders in differnet particle sizes by Self-propagating High-temperature Synthesis process (SHS) using a chemical furnace. The effects of the mole ratio of chemical fuel content, pellet thickness and the mole ratio between carbon and tungsten (C/W Ratio) on synthesis were investigated with the tungsten powders have different particle size each other. Compositional and structural characterization of these powders was carried out by scanning electron microscope (SEM0 and x-ray diffractometer. Powder characterization was carried out by the measurement of particle size distribution with laser-particle size analyzer. The amounts of WC obtained by SHS process depend very much on the particle size of tungsten powder and heat contents given in a product, i.e. as the particle size of W powder is smaller, the amounts of WC produced increase. Also the more heat contents is given, the more amounts of WC increase. By optimizing the synthesis conditions, it is possible to fabricate WC powders which have little secondary phases (W2C, C).

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Lipid Production Characteristics of the Basophilic Blue-Green Algae Arthrospira platensis Depending on pH for Alkaline Wastewater Treatment (알칼리성 폐수처리를 위한 호염기성 남조류 Arthrospira platensis의 pH에 따른 지질생성 특성)

  • Su-Hyeon Lee;Su-min Kwon;Sun-Jin Hwang
    • Journal of Korean Society on Water Environment
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    • v.39 no.6
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    • pp.433-438
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    • 2023
  • This study investigated the growth and metabolic characteristics of Arthrospira platensis (A. platensis) according to pH, which has an alkaline optimal pH. The intake of inorganic carbon was expected to be the highest at the optimum pH 9, but it was different from the expectation, so the cause of the excessive intake of inorganic carbon at pH 7 was investigated. We tried to verify the triacylglycerol (TAG) synthesis metabolic mechanism because it was assumedthat the inorganic carbon intake of A. platensis according to pH is closely related to lipid production inside the cell. To verify this, the effects of pH on inorganic carbon intake were examined through lipid analysis inthe cell of A. platensis according to pH. As a result, in the case of the effect of inorganic carbon intake of A. platensis according to pH on TAG content, pH 9 and pH 11 showed no significant difference in TAG content, but at pH 7, it was two times higher compared to pH 9 and pH 11. It was assumed that the reason why A. platensis excessively consumed inorganic carbon at pH 7 was because itincreased the TAG content in proportion to the intake of inorganic carbon to protect cells from external pH stress. In addition, it is considered that the TAG content produced in proportion to the intake of inorganic carbon is because acetyl-CoA produced in the Calvin cycle is required for the synthesis of TAG.