• Title/Summary/Keyword: Inorganic Compounds

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Detection of Volatile Organic Compounds (VOCs) using Organic-Inorganic Hybrid Perovskite Nanoparticles (유무기 페로브스카이트 나노입자의 휘발성 유기화합물 감응특성)

  • Choi, Hansol;Choi, Jihoon
    • Korean Journal of Materials Research
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    • v.30 no.10
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    • pp.515-521
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    • 2020
  • Organic-inorganic hybrid perovskite nanocrystals have attracted a lot of attention owing to their excellent optical properties such as high absorption coefficient, high diffusion length, and photoluminescence quantum yield in optoelectronic applications. Despite the many advantages of optoelectronic materials, understanding on how these materials interact with their environments is still lacking. In this study, the fluorescence properties of methylammonium lead bromide (CH3NH3PbBr3, MAPbBr3) nanoparticles are investigated for the detection of volatile organic compounds (VOCs) and aliphatic amines (monoethylamine, diethylamine, and trimethylamine). In particular, colloidal MAPbBr3 nanoparticles demonstrate a high selectivity in response to diethylamine, in which a significant photoluminescence (PL) quenching (~ 100 %) is observed at a concentration of 100 ppm. This selectivity to the aliphatic amines may originate from the relative size of the amine molecules that must be accommodated in the perovskite crystals structure with a narrow range of tolerance factor. Sensitive PL response of MAPbBr3 nanocrystals suggests a simple and effective strategy for colorimetric and fluorescence sensing of aliphatic amines in organic solution phase.

A Probabilistic Risk Assessment for Inorganic Arsenic (무기비소에 의한 확률론적 위해도 평가)

  • 유동한;하재주
    • Environmental Analysis Health and Toxicology
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    • v.13 no.3_4
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    • pp.95-104
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    • 1998
  • INTRODUCTION : Arsenic is a ubiquitous element present in various compounds throughout the earth's crust. The use of arsenic compounds increased greatly during the 18th and 19th centuries, including its use in pigments and dyes, as a preservative of animal hides, in glass manufacture, agricultural pesticides, and various pharmaceutical substances. The causal association between human arsenic exposure, usually in the form of inorganic compounds containing trivalent arsenite (As$^{III}$) or pentavalent arsenate (As$^V$), and various forms of human cancer has been known for many years.

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Effect of indole acetic acid on the contents of various phosphate compounds in the growth phase of saccharomyces uvarum (Saccharomyces uvarum의 배양시기에 따른 여러가지 인산화합물의 함량에 미치는 IAA의 효과)

  • 이종삼;조선희
    • Korean Journal of Microbiology
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    • v.19 no.2
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    • pp.52-62
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    • 1981
  • In order to interpret the effect of IAA on the phosphate metabolism and biosynthesis of organic compounds, Saccharomyces uvarum were cultured in the media treated with various concnetration of IAA $(10^{-3}M,\;10^{-5}M,\;10^{-7}M)$. Sampling at the beginning and intervals of culture, yeast cells fractionated were traced the contents of inorganic phosphate and organic compounds of various fractions. 1. Growth of Saccharomyces uvarum were enhanced by IAA $(10^{-3}M,\;10^{-5}M)$ and phosphate contents in DNA and RNA fractions treated with IAA were accelerated 2.3 times and 2 times in comparison with those of control. 2. Amounts of poly-P"A" and poly-p"B" were increased but poly-P"C" decreased during the culture. Therefore, it is considered that poly-P"C" play on most important role as a phosphate pool. 3. It is suggested that because phosphate contents in DNA, protein and lipid fractions increased, inorganic phosphates required phosphates required RNA were transferred from phosphates in cytoplasm, because these increased slowly during the culture. 4. Alkali-labile protein were accelerated by IAA and alkali stable protein only were inhibiction were enhanced by IAA while, ethanol : ether soluble fraction was induced by $10^{-7}M$ IAA in comparison with those control.X> IAA in comparison with those control.

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Analysis of Chemical Components of Elephant-foot (Amorphophallus konjac. k) (구약감자 성분분석(成分分析))

  • Lee, Hee-Duck;Lee, Jung-Il
    • Korean Journal of Medicinal Crop Science
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    • v.4 no.3
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    • pp.261-264
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    • 1996
  • This study was carried out to obtain a basic informations for the improvement of human health and the development of variety through analysis of inorganic compounds, contents of amino acids and saccharids to three elephant- foots (Amporphophallus Konjac. K) collected from Kumsan, Japan and China. Mannan as a carbohydrate of major component of an elephant-food was slightly high in Kumsan than that of Japan and China variety. Degree of viscosity of an elephant-foot depends upon the soluble free sugar contents and amino acid, contents of these free sugars were high in the order of Kumsan, China and Japan elephant-foot powder. Results of analysis of inorganic compounds to an elephant-foot used; Kumsan variety was shown to be high than those of China and Japan, especially. K, P and Fe in Kumsan variety were high, while Na and Ca were appeared to be high in China elephant-foot.

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Kinetics of Removing Nitrogenous and Phosphorus Compounds from Swine Waste by Growth of Microalga, Spirulina platensis

  • Kim, Min-Hoe;Chung, Woo-Taek;Lee, Mi-Kyung;Lee, Jun-Yeup;Ohh, Sang-Jip;Lee, Jin-Ha;Park, Don-Hee;Kim, Dong-Jin;Lee, Hyeon-Yong
    • Journal of Microbiology and Biotechnology
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    • v.10 no.4
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    • pp.455-461
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    • 2000
  • Abstract Spirulina platensis was grown in SWlUe waste to reduce inorganic compowlds and simultaneously produce feed resources. Spirulina platensis prefers nitrogenous compounds in Ibe order: $NH_4^{+}-N>NO_3^{-}-N>simple-N$ such as urea and simple amino acids. It even consumes $NH_4^{+}-N$ first when urea or nitrate are present. Therefore, the content of residual $NH_4^{+}-N$ in Spimlina platensis cultures can be determined by the relative extent of the following processes: (i) algal uptake and assimilation; (ii) ammonia stripping; and (iii) decomposition of urea to NH;-N by urease-positive bacteria. The removal rates of total nitrogen ffild total phosphorus were estimated as an indicator of the treatment effIciency. It was found that Spirulina platensis was able to reduce 70-93% of $P_4^{3-}-P$, 67-93% of inorganic nitrogen, 80-90% of COD, and 37-56% of organic nitrogen in various concentrations of swine waste over 12 days of batch cultivation. The removal of inorganic compounds from swine waste was mainly used for cell growth, however, the organic nitrogen removal was not related to cell growlb. A maximum cell density of 1.52 dry-g/l was maintained with a dilution rate of 0.2l/day in continuous cultivation by adding 30% swine waste. The nitrogen and phosphorus removal rates were correlated to the dilution rates. Based on the amino acid profile, the quality of the proteins in the Spirulina platensis grown in the waste was the same as that in a clean culture.ulture.

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Comparison of Chemical Components among varieties of Elephant-food (Amorphophallus konjac, K.) (수집종긴의 구약감자 성분비교)

  • HeDuckLee
    • Korean Journal of Plant Resources
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    • v.9 no.3
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    • pp.218-223
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    • 1996
  • This study was carried out to obtain a basic information for the improvement of human health and the development of variety through the analysis of inorganic compounds. contents of amino acids and polysaccarides on three elephant foods, Amorphophallus konjac, collected from Kumsan, Japan and China. The contents of mannan as a carbohydrate of a major component in an elephant food was slightly high in Kumsan than that of Japan and China variety. Degree of VIscosity of an elephant food depends upon the contents of soluble free sugars and amino acids contents of these free sugars were high in the order of Japan, China and Kumsan variety. The analytical results on inorganic compounds in an elephant food were shown as follows; The contents of potasium, phosphate and ferrin of Kumsan variety were shown to be higher than those of China and Japan, while sodium and caleium were appeared to be highter in China chip

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Effect of Extracting Conditions on the Mineral Content of Korean Red Ginseng Extract (추출조건(抽出條件)이 홍삼(紅蔘)엑기스의 무기성분(無機成分) 조성(組成)에 미치는 영향)

  • Sung, Hyun-Soon;Cho, Si-Houng;Park, Myung-Han;Yang, Cha-Bum
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.4
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    • pp.387-390
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    • 1985
  • The effect of extracting conditions on the content of inorganic compounds of red ginseng extract was studied with respect to the change in ethanolic concentration ranges of $0{\sim}90%$ and temperature of $70{\sim}100^{\circ}C$ during $1{\sim}5$ times of extraction. Each extraction time was taken 8 hours at given temperature. Little effect of temperature on inorganic compounds was observed, while higher ethanol concentrations, particularly higher than 70%, were resulted a significant decreased in their contents. The yield of inorganic compounds in water was shown 80% over after 3rd extraction, while content of crude ash was observed similar tendency and their contents were significant increased in water than in 70% ethanolic concentration. In the process of extraction with water, 1.55% of the potassium content was the highest value, and the smallest was 11ppm of the copper. But in the extraction ratio to raw mateirls, the highest ratio was 91.4% of the calcium, and smallest was 30.4.% of the magnesium.

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Influence of inorganic compounds on nanofiltration membrane fouling with Al hydrolysis products (알루미늄 수화물 나노여과 막오염에 대한 공존염의 영향에 관한 연구)

  • Choi, Yang-Hun;Kweon, Ji-Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.479-488
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    • 2011
  • Nanofiltration was performed with polyaluminium chloride solutions at different pH conditions to understand effects of inorganic compounds on aluminum hydrolysis products, i.e., three distinctive groups of aluminum species: polymeric Al at low pH; $Al(OH)_3$ at neutral pH; and ${Al(OH)_4}^-$ at high pH. The PACl solution was prepared to be approximately 4.0mM and adjusted to the designated pH. The influence of inorganic compounds on Al species fouling was investigated with 4.9mM $CaCl_2$ and 3.5mM $MgSO_4$ because $Ca^{2+}$, $Mg^{2+}$, $Cl^-$, ${SO_4}^{2-}$ are the most common inorganics in the drinking water. NF membrane fouling was measured by flux decline rate. The impact of $CaCl_2$ was not significant on the individual Al hydrolysis products fouling. However, the flux decline rate was drastically changed in the presence of $MgSO_4$. The concentration of particulate matters was considerably increased possibly due to interaction between Al species and ${SO_4}^{2-}$ where $MgSO_4$ was introduced. The particulates were accumulated on the membrane and enhanced the hydraulic resistance of the cake layer. In addition, conductivity removal of the membrane was decreased when Al-hydroxide was dominant due to reduction of membrane surface charge. The rejection of $Ca^{2+}$and $Mg^{2+}$ were considerably different, which implys that composition of inorganics paly a role on conductivity removal.

A Study on Detoxication of Coal Briquette by Additives (첨가제에 의한 연탄제독에 관한 연구)

  • Chang Tuwon;Young Sun Uh;Youn Soo Sohn
    • Journal of the Korean Chemical Society
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    • v.30 no.1
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    • pp.118-125
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    • 1986
  • A small scale combustion unit was built to evaluate the CO suppression effects by various chemical additives added to coal briquettes. Among the additives tested comprising various transition metal compounds with catalytic activities, natural minerals and oxidizing agents, the copper component has shown the best CO suppression effect, and in particular, copper oxide dispersed on porous supports such as ${\gamma}-Al_2O_3$ was most effective. For instance, 0.5% of copper added to coal briquettes in this way bas exhibited 1.4 % CO in the combustion gas at the ignition and beginning stage of combustion and 0.3 % CO at the final stage. The effects of calcium compounds on the fixation of sulfur in coal were also evaluated to reduce the contents of sulfur compounds in the combustion gases.

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Reusing the Liquid Fraction Generated from Leaching and Wet Torrefaction of Empty Fruit Bunch

  • Lee, Jae-Won;Choi, Jun-Ho;Im, Hyeon-Soo;Um, Min;Lee, Hyoung-Woo
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.372-377
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    • 2019
  • Leaching ($60^{\circ}C$, 5 min) and wet torrefaction ($200^{\circ}C$, 5 min) of empty fruit bunch (EFB) were carried out to improve the fuel properties; each liquid fraction was reused for leaching and wet torrefaction, respectively. In the leaching process, potassium was effectively removed because the leaching solution contained 707.5 ppm potassium. Inorganic compounds were accumulated in the leaching solution by increasing the reuse cycle of leaching solution. The major component of the leached biomass did not differ significantly from the raw material (p-value < 0.05). Inorganic compounds in the biomass were more effectively removed by sequential leaching and wet torrefaction (61.1%) than by only the leaching process (50.1%) at the beginning of the liquid fraction reuse. In the sequential leaching and wet torrefaction, the main hydrolysate component was xylose (2.36~4.17 g/L). This implied that hemicellulose was degraded during wet torrefaction. As in the leaching process, potassium was effectively removed and the concentration was accumulated by increasing the reuse cycle of wet torrefaction hydrolysates. There was no significant change in the chemical composition of wet torrefied biomass, which implied that fuel properties of biomass were constantly maintained by the reuse (four times) of the liquid fraction generated from leaching and wet torrefaction.