Browse > Article
http://dx.doi.org/10.9713/kcer.2019.57.3.372

Reusing the Liquid Fraction Generated from Leaching and Wet Torrefaction of Empty Fruit Bunch  

Lee, Jae-Won (Department of Wood Science and Engineering, College of Agriculture & Life Sciences, Chonnam National University)
Choi, Jun-Ho (Department of Wood Science and Engineering, College of Agriculture & Life Sciences, Chonnam National University)
Im, Hyeon-Soo (Power Generation Laboratory, Fuel & Combustion Group, KEPCO Research Institute)
Um, Min (Department of Wood Science and Engineering, College of Agriculture & Life Sciences, Chonnam National University)
Lee, Hyoung-Woo (Department of Wood Science and Engineering, College of Agriculture & Life Sciences, Chonnam National University)
Publication Information
Korean Chemical Engineering Research / v.57, no.3, 2019 , pp. 372-377 More about this Journal
Abstract
Leaching ($60^{\circ}C$, 5 min) and wet torrefaction ($200^{\circ}C$, 5 min) of empty fruit bunch (EFB) were carried out to improve the fuel properties; each liquid fraction was reused for leaching and wet torrefaction, respectively. In the leaching process, potassium was effectively removed because the leaching solution contained 707.5 ppm potassium. Inorganic compounds were accumulated in the leaching solution by increasing the reuse cycle of leaching solution. The major component of the leached biomass did not differ significantly from the raw material (p-value < 0.05). Inorganic compounds in the biomass were more effectively removed by sequential leaching and wet torrefaction (61.1%) than by only the leaching process (50.1%) at the beginning of the liquid fraction reuse. In the sequential leaching and wet torrefaction, the main hydrolysate component was xylose (2.36~4.17 g/L). This implied that hemicellulose was degraded during wet torrefaction. As in the leaching process, potassium was effectively removed and the concentration was accumulated by increasing the reuse cycle of wet torrefaction hydrolysates. There was no significant change in the chemical composition of wet torrefied biomass, which implied that fuel properties of biomass were constantly maintained by the reuse (four times) of the liquid fraction generated from leaching and wet torrefaction.
Keywords
Empty fruit bunch; Leaching; Wet torrefaction; Ash; Inorganic compounds;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Smith, A. M., Singh, S. and Ross, A. B., "Fate of Inorganic Material During Hydrothermal Carbonization of Biomass: Influence of Feedstock on Combustion Behavior of Hydrochar," Fuel, 169, 135-145(2016).   DOI
2 Bach, Q. V. and Skreiberg, O., "Upgrading Biomass Fuels via wet Torrefaction: A Review and Comparison with dry Torrefaction," J. Renew. Sustain. Energy, 54, 665-677(2016).   DOI
3 Chin, K. L., H'ng, P. S., Paridah, M. T., Szymona, K., Maminski, M., Lee, S. H., Lum, W. C., Nurliyana, M. Y., Chow, M. J. and Go, W. Z., "Reducing Ash Related Operation Problems of Fast Growing Timber Species and Oil Palm Biomass for Combustion Applications Using Leaching Techniques," Energy, 90, 622- 630(2015).   DOI
4 Persson, H., Kantarelis, E., Evangelopoulos, P. and Yang, W., "Wood-derived Acid Leaching of Biomass for Enhanced Production of Sugars and Sugar Derivatives During Pyrolysis: Influence of Acidity and Treatment Time," J. Anal. Appl. Pyrolysis, 127, 329-334(2017).   DOI
5 Zhang, S., Su, Y., Zhu, S., Zhang, H. and Liu, X., "Effects of Torrefaction and Organic-acid Leaching Pretreatment on the Pyrolysis Behavior of Rice Husk," Energy, 149, 804-813(2018).   DOI
6 Yu, C., Wang, L., Anderson, S. N., VanderGheynst, J. S., Upadhyaya, S. K. and Jenkins, B. M., "Influence of Leaching Pretreatment on Fuel Properties of Biomass," Fuel Process Technol., 128, 43-53(2014).   DOI
7 Zheng, A., Zhao, Z., Chang, S., Huang, Z., Zhao, K., Wei, G. and Li, H., "Comparison of the Effect of Wet and Dry Torrefaction on Chemical Structure and Pyrolysis Behavior of Corncobs," Biomass Bioenergy, 176, 15-22(2015).
8 Lynam, J. G., Coronella, C. J., Yan, W., Reza, M. T. and Vasquez, V. R., "Acetic Acid and Lithium Chloride Effects on Hydrothermal Carbonization of Lignocellulosic Biomass," Bioresour. Technol., 102, 6192-6199(2011).   DOI
9 Na, B., Kim, Y., Lim, W., Lee, S., Lee, H. and Lee, J., "Torrefaction of Oil Palm Mesocarp Fiber and Their Effect on Pelletizing," Biomass Bioenergy, 52, 159-165(2013).   DOI
10 Ho, S., Zhang, C., Chen, W. and Chang, J., "Characterization of Biomass Waste Torrefaction Under Conventional and Microwave Heating," Bioresour. Technol., 264, 7-16(2018).   DOI
11 Saddawi, A., Jones, J. M., Williams, A. and Coeur, C., "Commodity Fuels from Biomass Through Pretreatment and Torrefaction: Effects of Mineral Content on Torrefied Fuel Characteristics and Quality," Energy Fuels, 26, 6466-6474(2012).   DOI
12 Lee, S. and Lee, J., "Optimization of Biomass Torrefaction Conditions by the Gain and Loss Method and Regression Model Analysis," Bioresour. Technol., 172, 438-443(2014).   DOI
13 Kambo, H. S. and Dutta, A., "Comparative Evaluation of Torrefaction and Hydrothermal Carbonization of Lignocellulosic Biomass for the Production of Solid Biofuel," Energy Conv. Manag., 105, 746-755(2015).   DOI
14 Sluiter, A., Hames, B., Ruiz, R., Scarlate, C., Sluiter, J., Templeton, D. and Crocker, D., "Laboratory Analytical Procedure No. TP-510-42618," NREL, Goden, CO(2012).
15 Novianti, S., Nurdiawati, A., Zaini, I. N., Prawisudha, P., Sumida, H. and Yoshikawa, K., "Low-potassium Fuel Production from Empty Fruit Bunches by Hydrothermal Treatment Processing and Water Leaching," Energy Procedia, 75, 584-589(2015).   DOI
16 Thy, P., Grundvig, S., Jenkins, B. M., Shiraki, R. and Lesher, C. E., "Analytical Controlled Losses of Potassium from Straw Ashes," Energy Fuels, 19, 2571-2575(2005).   DOI
17 Tonn, B., Thumm, U., Lewandowski, I. and Claupein, W., "Leaching of Biomass from Semi-natural Grasslands-Effects on Chemical Composition and Ash High-temperature Behavior," Biomass Bioenergy, 36, 390-403(2012).   DOI
18 Supancic, K., Obernberger, I., Kienzl, N. and Arich A., "Conversion and Leaching Characteristics of Biomass Ashes During Outdoor Storage-Results of Laboratory Tests," Biomass Bioenergy, 61, 211-226(2014).   DOI
19 Makela, M., Fullana, A. and Yoshikawa, K., "Ash Behavior During Hydrothermal Treatment for Solid Fuel Applications. Part 1: Overview of Different Feedstock," Energy Conv. Manag., 121, 402-408(2016).   DOI
20 Nurdiawati, A., Novianti, S., Zaini, I.N., Nakhshinieva, B., Sumida, H., Takahashi, F. and Yoshikawa, K., "Evaluation of Hydrothermal Treatment of Empty Fruit Bunch for Solid Fuel and Liquid Organic Fertilizer co-production," Energy Procedia, 79, 226-232 (2015).   DOI
21 Ma, T., Fan, C., Hao, L., Li, S., Song, W. and Lin, W., "Fusion Characterization of Biomass Ash," Thermochim. Acta, 638, 1-9 (2016).   DOI
22 KESIS, "Production of New & Renewable Energy by Region (toe)," Korea Energy Statistics Information System. Ulsan, Korea (2018).
23 Deng, L., Zhang, T. and Che, D., "Effect Water Washing on Fuel Properties, Pyrolysis and Combustion Characteristics, and Ash Fusibility of Biomass," Fuel Process. Technol., 106, 712-720(2013).   DOI
24 Nielsen, H. P., Baxter, L. L., Sclippab, G., Morey, C., Frandsen, F. J. and Dam-johnsen, K., "Deposition of Potassium Saltes on Heat Transfer in Straw-fired Boilers: a Pilot-scale Study," Fuel, 79, 131-139(2000).   DOI