• 대한화학회지
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• 제39권4호
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• pp.275-280
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• 1995

수소이온 존재하에서 $cis-[Co(en)_2(NO_2)_2]^+$과 라세미-$[Co(Y)]^2-(Y=EDTA,\; PDTA,\; CyDTA)$간에 일어나는 전자전달반응속도를 조사하였다. 속도자료로부터 $cis-[Co(en)_2(NO_2)_2]^+$과 라세미-$[Co(Y)]^2$간에 일어나는 전자전달반응은 수소이온이 촉매로 작용하여 내부권으로 진행되는 것을 알 수 있었다. 한편, 광학활성인 △-cis-$[Co(en)_2(NO_2)_2]^+$과 라세미-$[Co(Y)]^2-(Y=EDTA,\; PDTA,\; CyDTA)$간의 입체선택적 전자전달반응에서는 △-[Co(EDTA)]-, △-[Co(PDTA)]- , △-[Co(CyDTA)]-가 각각 6.0, 2.9, 3.0% e.e.(e.e.=enantiomeric excess) 생성되었다. 이것은 두 착물이 접근하여 먼저 선택적 이온회합을 이루고 전자전달반응이 일어나는 것으로 볼 수 있다. 따라서 △-cis-$[Co(en)_2(NO_2)2_]^+$과 라세미-$[Co(Y)]^{2-}$간의 입체선택적 전자전달반응은 산촉매에 의한 내부적 반응과 입체선택적 이온회합에 따른 외부권 반응으로 진행된다고 추정할 수 있다.

• 대한수학회논문집
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• 제33권2호
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• pp.639-650
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• 2018

Finding a solution for the Legendre equation is difficult. Especially if it is as a part of the Laplace equation solving in the electric fields. In this paper, first a problem of the generalized differential transform method (GDTM) is solved by the Sturm-Liouville equation, then the Legendre equation is solved by using it. To continue, the approximate solution is compared with the nth-degree Legendre polynomial for obtaining the inner and outer potential of a sphere. This approximate is more accurate than the previous solutions, and is closer to an ideal potential in the intervals.

• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2599-2606
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• 2011

The fluorescence of ethidium bound to DNA, poly[d(A-T)$_2$], and poly[d(G-C)$_2$] at a [ethidium]/[DNA] ratio of 0.005 was quenched by porphyrins when both ethidium and the porphyrins simultaneously bound to the same polynucleotide. The quenching was tested using the "inner sphere" and the "Forster resonance energy transfer" (FRET) models, with the latter found to contribute, at least in part, to the quenching. Meso-tetrakis(N-methylpyridinium-4-yl)porphyrin (TMPyP) exhibited a higher quenching and FRET efficiency than cis-bis(N-methylpyridinium-4-yl)porphyrin (BMPyP) for all of the tested DNA and polynucleotides, demonstrating that energy transfer efficiency is affected by the number of positive charges of porphyrins.

• 대한화학회지
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• 제39권1호
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• pp.29-34
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• 1995

구리(II)-아민류 착물에 의한 l-ascorbic acid의 산화반응속도를 pH 4.6에서 Onishi 방법으로 측정하였다. 이 반응의 메커니즘은 l-ascorbic acid가 구리(II) 착물에 배위된 다음 속도결정단계에서, 전자이동이 일어나는 내부권 메커니즘에 따라 반응이 진행됨을 알았다.

• Bulletin of the Korean Chemical Society
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• 제27권2호
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• pp.251-254
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• 2006

The formation of polyaniline (PANI) in the reverse micelles of poly(oxyethylene) nonylphenyl ether, $(NP5, H(CH_2)_9Ph(OC_2H_4)_5OH)$, was investigated by small-angle neutron scattering (SANS). The reverse micellar solution containing initiators in the inner part of reverse micelle was prepared with surfactant (NP5), water, cyclohexane and an initiator (ammonium persulfate (APS)). The core-shell sphere model containing smearing effect reveals that the polymerization occurs on the shell layer of the reverse micelles. Shell thickness averages varied from 48 $\AA$ to 109 $\AA$ with increases of monomer concentration.

• Bulletin of the Korean Chemical Society
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• 제11권4호
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• pp.303-306
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• 1990

Kinetic studies were carried out for the redox reaction of $[Co(NH_3)_4(C_2O_4)]^+$ with aqueous $[Fe(H_2O)_6]^{2+}$ solution in the present of $H^+$ by UV/VIS-spectrophotometric method. It was found that the order of $H^+$ for the reaction is first one in the higher $H^+$ concentration range of $1.67×10^{-1} M{\sim}1.00 M,$ while second order in the lower range of $6.30×10^{-2} M{\sim}1.67{\times}10^{-1} M.$ Reaction order of the substrates was found to be first order with respect to each of them. Accordingly overall reactions are third or fourth order. The results of calculation for the Extended Huckel Molecular Orbital theory contribute to estimate the preferred intermediates, bridging form of binuclear complex. On the basis of these results, we propose that this redox reaction proceed via inner-sphere reaction mechanism.

• 대한가정학회지
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• 제44권8호
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• pp.181-198
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• 2006

The purpose of this study is to understand modernization process of korean housing during the past one century. To following up the changes of everyday lives of common peoples, magazines, news papers, tourist's records and gossip items were collected and interpreted from the microscopic point of view. In this study arguments on 'modernity' of korean housing was focused on some issues, thus, separation, differentiation, individualization, as well as privatization. Concrete discourses are; firstly, spatial isolation of housing and urban place each other, secondly, functional division of inner spaces of housing, and lastly, guarantee of privacy sphere. Historical changes of housing showed some meaningful phenomena. Before modernization housing was place of reproduction and consume at the same time. However after modern urban space came into existence and work and rest were separated, housing gained only mono function. Thus, housing have only one meaning as private place for nuclear family, that is "Home, Sweet Home." Instead of past multi-functional rooms, functional prescribed rooms, for example, dinning room, were newly born. In the past, the boundary between public and private sphere was not clear. For examples, everyday experiences of family were extended to the street and in the house in most cases spaces were shared. But after modernization the scale of individual spaces become larger and private life can be secured. Consequently, history of everyday life from traditional agricultural society to industrialized modern society demonstrates the structural context between the micro and macro dimension in the fields of human life. In other words, everyday lives and macro history response each other and create new perception of time-space structure in the modern housing.

• 한국광물학회지
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• 제11권1호
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• pp.20-31
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• 1998

Adsorption of metal elements onto illite and halloysite was investigated at $25^{\circ}C$ using pollutant water collected from the gold-bearing metal mine. Incipient solution of pH 3.19 was reacted with clay minerals as a function of time: 10 minute, 30 minute, 1 hour, 12 hour, 24 hour, 1 day, 2 day, 1 week, and 2 week. Twenty-seven cations and six anions from solutions were analyzed by AAs (atomic absorption spectrometer), ICP(induced-coupled plasma), and IC (ion chromatography). Speciation and saturation index of solutions were calculated by WATEQ4F and MINTEQA2 codes, indicating that most of metal ions exist as free ions and that there is little difference in chemical species and relative abundances between initial solution and reacted solutions. The adsorption results showed that the adsorption extent of elements varies depending on mineral types and reaction time. As for illite, adsorption after 1 hour-reaction occurs in the order of As>Pb>Ge>Li>Co, Pb, Cr, Ba>Cs for trace elements and Fe>K>Na>Mn>Al>Ca>Si for major elements, respectively. As for halloysite, adsorption after 1 hour-reaction occurs in the order of Cu>Pb>Li>Ge>Cr>Zn>As>Ba>Ti>Cd>Co for trace elements and Fe>K>Mn>Ca>Al>Na>Si for major elements, respectively. After 2 week-reaction, the adsorption occurs in the order of Cu>As>Zn>Li>Ge>Co>Ti>Ba>Ni>Pb>Cr>Cd>Se for trace elements and Fe>K>Mn>Al, Mg>Ca>Na, Si for major elements, respectively. No significant adsorption as well as selectivity was found for anions. Although halloysite has a 1:1 layer structure, its capacity of adsorption is greater than that of illite with 2:1 structure, probably due to its peculiar mineralogical characteristics. According to FTIR (Fourier transform infrared spectroscopy) results, there was no shift in the OH-stretching bond for illite, but the ν1 bond at 3695 cm-1 for halloysite was found to be stronger. In the viewpoint of adsorption, illite is characterized by an inner-sphere complex, whereas halloysite by an outer-sphere complex, respectively. Initial ion activity and dissociation constant of metal elements are regarded as the main factors that control the adsorption behaviors in a natural system containing multicomponents at the acidic condition.

• 대한환경공학회지
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• 제31권4호
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• pp.287-293
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• 2009

본 연구에서는 칼럼실험을 이용하여 석영모래와 철피복 모래에서 박테리아(Escherichia coli, Bacillus subtilis, 그리고 Staphylococcus aureus)의 부착 및 탈착에 미치는 이온강도의 영향을 조사하였다. 실험결과, 철피복 모래에서는 이온강도가 1 mM에서 100 mM로 증가함에 따라 질량회수율이 일정(E. coli = 13.7${\pm}$0.5%, B. subtilis = 9.8${\pm}$1.3%, S. aureus = 13.0${\pm}$2.1%)한 반면, 석영모래에서는 80.7%에서 45.3%로 감소하였다(S. aureus). 용출용액의 이온강도가 100 mM에서 0.1 mM로 감소함에 따라, 석영모래에서는 평균 39.1%의 박테리아 탈착이 일어났지만, 철피복 모래에서는 탈착이 관찰되지 않았다. 철피복 모래에서 관찰된 이러한 현상은 박테리아와 철피복 모래사이의 inner-sphere complexes(이온강도의 영향을 받지 않는)에 의한 결합 때문이다. 본 연구는 박테리아와 표면변형 다공성 여재의 상호작용에 대한 지식을 증진시킨다.

• 한국조경학회지
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• 제41권5호
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• pp.57-67
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• 2013

지금까지 별서정원과 관련된 연구들은 고문서 및 현장조사를 통한 통시적인 접근을 많이 해왔다. 전통조경공간의 상징성, 입지 특성 등 그 공간에 내재된 특성에 초점을 둔 연구들이 많았다. 하지만, 입지 특성 중 내원, 외원, 영향권에 대한 특성은 많았으나, 외원 규모에 대한 정량적 연구는 미진하였다. 사생활권역인 내원과 달리 공동생활권역으로서의 역할인 외원에 대하여 정량적인 분석을 하기 위해 서석지원를 대상으로 실시하였다. 서석지원를 대상으로 기존 문헌들과 GIS 프로그램을 통해 가시권 분석을 실시하였으며, 외원 규모를 추정하였다. 선행연구와 일부 차이가 있었지만, 부용봉과 입암 중심으로 확인해본 결과, 거의 유사한 면적으로 나타났다. 또한, 추정된 외원 규모를 통해 서석지원의 다양한 상징성에 대한 프랙탈 차원을 분석해본 결과, 주요 경관요소에서 프랙탈 차원이 상대적으로 집중화되는 경향을 알 수 있었다. 특히, 주요 경관요소는 청기천을 제외하고, 일반 자연경관(논, 밭 등)에 비해 상대적으로 높은 수치 및 넓은 범위의 프랙탈 차원을 가지고 있었다. 이를 통해 외원규모가 그동안 별서정원의 형태 중 내원에 대한 문화재 보호에서 벗어나, 외원에 대한 문화재 보호수단을 위한 기초자료로 활용될 수 있을 것으로 기대한다. 또한, 이번 연구가 경관분석 요소 중 하나로서 프랙탈 구조 개념을 도입하여 주요 경관요소에 대한 시각적 복잡성에 대해 고려하였지만, 각 경관요소에 대하여 시문학과 더불어 좀 더 융합적인 사고의 결과물에 대한 연구가 필요할 것으로 기대한다.