• 제목/요약/키워드: Initial concentration

검색결과 3,428건 처리시간 0.034초

산소농도와 압력 변화에 따른 도시가스의 폭발특성 (The Explosion Characteristics of City Gas on the Change of Oxygen Concentration and Pressure)

  • 최재욱;이인식;박성태
    • 한국가스학회지
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    • 제9권1호
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    • pp.38-43
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    • 2005
  • 도시가스의 폭발특성을 평가하기 위하여, 산소의 농도와 초기압력의 변화에 따라 실험을 행하였다 이러한 실험을 행한 결과 산소농도가 낮아짐에 따라 폭발범위는 점차적으로 좁혀졌으며, 산소농도 $12\%$에서 폭발한계산소농도를 구하였다. 도시가스의 초기압력이 증가함에 따라 폭발하한계가 약간 증가하였다. 또한 초기압력이 $0{\~}1.0 kgf/cm^2{\cdot}g$로 변함에 따라 최대폭발압력은 $6.3 kgf/cm^2{\cdot}g,\;12.7 kgf/cm^2{\cdot}g$을 구하였으며, 최대폭발압력상승속도는 $245.63 kgf/cm^2/s,\;427.88 kgf/cm^2/s$를 구하였다.

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Investigation of Nickel Removal from Heavy Metal Containing Industrial Wastewater by Electrocoagulation Method

  • Baybars Ali, Fil;Cansu, Elgun;Sevim Alya, Cihan;Sermin, Gunaslan;Alper Erdem, Yilmaz
    • Journal of Electrochemical Science and Technology
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    • 제13권4호
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    • pp.424-430
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    • 2022
  • In the study, Ni2+ (nickel) removal from synthetically prepared wastewater by electrocoagulation method, which is one of the electrochemical treatment processes, was investigated and parameters such as current density, pH, mixing speed, initial Ni2+ concentration, supporting electrolyte type and concentration were determined to determine Ni2+ removal efficiencies effects were studied. Experiment conditions during 30 minutes of electrolysis; the current density was determined as 0.95 mA/cm2, the initial pH of the wastewater was 6, the mixing speed was 150 rpm, and the initial nickel concentration was 250 mg/L. The Ni2+ removal efficiency was obtained as 75.99% under the determined experimental conditions, while the energy consumption was calculated as 3.15 kW-h/m3. In the experiments, it was observed that the type and concentration of the supporting electrolyte did not have a significant effect on the Ni2+ removal efficiency. In the trials where the effect of the support electrolyte concentration was examined, the Ni2+ removal efficiency was 75.99% in the wastewater environment without the supporting electrolyte, while the Ni2+ removal efficiency was 81.55% when 7.5 mmol/L NaCl was used after the 30-minute reaction, and the energy consumption was 2.15 kW-h/m3 obtained as. As a result of the studies, it was concluded that the electrocoagulation process can be applied in the treatment of wastewater containing Ni2+.

카드뮴, 납, 구리에 대한 슬래그의 흡착특성평가 (Assessment of Sorption Behavior on Slag Against Heavy Metals)

  • 이광헌;최성대;정재식;박준범;남경필
    • 한국지반공학회논문집
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    • 제24권6호
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    • pp.17-25
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    • 2008
  • 폐금속 광산 지역 등지에서 중금속으로 오염된 지하수의 정화 및 오염확산 방지를 위하여 투수성 반응벽체를 사용 할 수 있다. 본 연구에서는 슬래그가 투수성 반응벽체 충진물질로서 적당한지 평가하기 위하여 폐광산 지역에서 문제가 되고 있는 몇 가지 중금속(i.e., Pb, Cu, Cd)에 대한 슬래그의 반응성을 평가하였다. 폐광산 지역 지하수에는 중금속류들이 복합오염의 형태로 존재하며, 음이온 물질인 황산염, 탄산염 등도 공존한다. 중금속으로 오염된 현장의 조건을 고려하여, 1) 중금속 종류에 따른, 2) 초기 농도에 따른, 3) 음이온(황산염)의 존재에 따른 영향을 회분식 실험을 통하여 슬래그의 흡착능을 평가하였다. 슬래그의 흡착특성은 등온흡착평형(equilibrium sorption)과 동적인 흡착(kinetic sorption)인 경우 각 조건에 따른 영향을 확인하였다.

암모늄 이온 및 질산화균의 초기 농도가 질산화에 미치는 영향 (Effects of Initial Concentration of Ammonium Ion and Active Nitrifiers on Nitrification)

  • 김정훈;김영주;박흥석
    • 대한토목학회논문집
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    • 제26권4B호
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    • pp.421-426
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    • 2006
  • 본 연구는 생물학적 질산화 공정에서 암모늄 이온과 활성을 가진 질산화균의 초기 농도가 질산화에 미치는 영향을 확인하고, 이에 따른 동역학식을 제시하고자 하였다. 먼저 실험에 이용된 슬러지의 질산화균 농도는 미생물 호흡률 실험으로 측정하였는데, 배양된 슬러지 중 42.8%가 활성을 가진 질산화균으로 나타났다. 암모늄 이온과 질산화균의 초기 농도를 달리하여 $N_0/X_0$비가 0.025~0.493의 조건에서 잘산화 실험을 실시하였으며, 이를 통해 암모늄 이온과 질산화균의 농도가 상이하더라도 $N_0/X_0$ 비가 동일할 경우 암모늄 산화율이 동일함을 확인하였다. 또한 $N_0/X_0$ 비와 비기질이용율의 관계는 Contois 형태의 관계식으로 표현되었으며, 최대 비암모늄산화율($q_{Nmax}$)은 4.32 gN/gVSS/day, 반 포화속도 상수($K_N{^{\prime}}$)는 0,013 gN/gVSS인 것으로 확인되었다.

포름산 및 황산 촉매를 이용한 자일로스로부터 푸르푸랄 생산 (Furfural Production From Xylose by Using Formic Acid and Sulfuric Acid)

  • 이승민;김준석
    • Korean Chemical Engineering Research
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    • 제61권4호
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    • pp.561-569
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    • 2023
  • 푸르푸랄(furfural)은 리그노셀룰로오스 바이오매스(lignocellulose biomass)의 헤미셀룰로오스(hemicellulose) 성분 중 하나인 자일로스(xylose)로부터 생산되는 플랫폼 화학물질이다. 푸르푸랄은 페놀류 화합물이나 바이오 연료 등의 중요한 원료로 사용될 수 있다. 본 연구에서는 푸르푸랄 생산공정에서 일반적으로 사용되는 산 촉매인 황산(sulfuric acid)과 친환경적 촉매인 포름산(formic acid) 두 가지 촉매를 이용하여 회분식 반응 시스템(batch system)에서 자일로스로부터 푸르푸랄을 생산하기 위한 조건을 비교 및 최적화하였다. 자일로스의 초기 농도(10 g/L~100 g/L), 반응 온도(140~200 ℃), 황산 촉매(1~3 wt%), 포름산 촉매(5~10 wt%), 반응 시간에 따라 자일로스로부터 푸르푸랄 수율에 미치는 영향을 조사하였다. 촉매 종류에 따른 최적 조건은 다음과 같았다. 황산 촉매의 경우, 3 wt%의 촉매농도, 50 g/L의 초기 자일로스 농도, 180 ℃의 온도 10분의 반응시간에서 최대 58.97%의 푸르푸랄 수율을 얻었다. 포름산 촉매의 겨우, 5 wt%의 촉매농도, 50 g/L의 초기 자일로스 농도, 180 ℃의 온도, 150분 반응 시간에서 65.32%의 푸르푸랄 수율을 확보하였다.

단단한 종양 안에 수동 조준된 약물의 전달에 관한 확산에 기초한 모델 이론 (A Diffusion-based Model Theory of Passive-Targeted Drug Delivery in Solid Tumors)

  • 최준혁;강남룡;최상돈
    • 한국의학물리학회지:의학물리
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    • 제18권3호
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    • pp.161-166
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    • 2007
  • 공모양의 단단한 종양안에서 수동조준된 약물의 전달에 관한 모델이론이 적절한 경계조건과 초기조건하에서 픽의 확산법칙으로부터 유도된다. 종양안의 농도는 초기값이 일정하면 시간과 지름의 함수로 나타난다. 생각실험(사고실험)으로부터 예측되는 바와 같이, 농도는 시간이 경과함에 따라 평형값에 접근한다. 시간에 따른 농도의 변화는 조직안의 약물의 확산계수, 종양의 크기, 주입된 약물의 양, 경계면에서의 농도의 물매(gradient)에 의해 결정된다.

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배추무사마병의 뿌리혹 형성에 미치는 묘령, 접종원 농도 및 접종방법의 영향 (Effects of Plant Age Inoculum Concentration and Inoculation Method on Root Gall Development of Clubroot Disease of Chinese Cabbage Caused by Planmodiophora brassicae)

  • 김충회
    • 식물병과 농업
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    • 제5권2호
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    • pp.90-94
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    • 1999
  • Effect of inoculum concentration inoculation method and plant age on development of clubroot disease of Chinese cabbage seedling were examined in growth chambers. Root galls were developed at the concentration of 105 resting spore or above per ml of incoulum and as the inoculum concentration became higher rate of development of root galls was faster. In the plants with root gall development fresh weight of above ground parts was reduced to 30-44% of that of healthy plants but root weight increased by 4-10 times. Growth of diseased plants was greatly reduced as compared to healthy plants. Planting in the diseased soil as a inoculation method was most effective for disease development showing uniform infections but time of initial root gall development was delayed by root soaking inoculation. Some plants inoculated by soil drenching method did not develop root galls. However root gall enlargement after its initial formation did not differ greatly among inoculation methods. Nine-day-old seedlings showed poor development of root gall but 16-days-old seedlings was found to be most adequate for inoculation for gall development.

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Nocardia orientalis 변이주에 의한 고농도 혼합당을 이용한 반코마이신 생산

  • 김창호;고영환;고중환
    • 한국미생물·생명공학회지
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    • 제24권4호
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    • pp.404-407
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    • 1996
  • The effects of carbon sources on vancomycin production were investigated using Nocardia orientalis CSVC 3300. Among carbon sources tested, glucose, maltose and fructose were effective for the production of vancomycin. Glucose was favored for growth, but decrease the production of vancomycin at the concentration above 7.5%. In comparison, maltose did not decrease the production of vancomycin up to the concentration of 20%. When the mixture of glucose and maltose was used in the ratio 1:3 to 1:4, the highest production of vancomycin was achieved. When glucose concentration was set at 3.0%, catabolite repression could not be observed up to total sugar concentration of 16.0%. Fermentation was carried out using commercial hydrolyzed starch composed of glucose, maltose, maltotriose and maltotetraose, The initial glucose concentration was set at 3.0% and subsequent oligosaccharide consumption was monitored by checking their supernatant with HPLC. During initial cultivation for 38 hour, glucose was the sole carbon source leading to rapid growth. After cell growth stopped, the maltose and glucose concentrations increased due to degradation of maltotriose and maltotetraose, but glucose level was maintained at around 3.0%. After 70 hour fermentation, maltose slowly converted to glucose, and vancomycin production continued during the period.

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TiO2 코팅 석탄회 복합체의 기상 Acetaldehyde 광분해 특성 (Photocatalytic Degradation of Gaseous Acetaldehyde through TiO2-Coated Fly Ash Composites)

  • 신대용;김경남
    • 한국세라믹학회지
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    • 제45권1호
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    • pp.43-47
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    • 2008
  • The photocatalyst of $TiO_2$ coated on a fly ash composites (TCF) was prepared from precipitant dropping method to remove the acetaldehyde by photocatalytic reaction. The TCF were characterized by crystal aize, crystal structure and specific surface area. The photodegradation of acetaldehyde has been investigated using a UV-illuminated fixed photocatalytic reactor with TCF catalyst and P-25 catalyst in gas phase. The effect of photodegradation reaction conditions, such as initial concentration of acetaldehyde, concentration of oxidant in mixed gas and the light intensity on the photodegradation of acetaldehyde were investigated. P-25 catalyst showed the highest photodegradation of acetaldehyde and anatase $TiO_2$ coated TCF showed higher decomposition rate than rutile coated TCF. The photodegradation rate of acetaldehyde increased with the decrease of flow rate, initial concentration of acetaldehyde ($C_i$) and water vapor, however, it was increased with the increas of UV light intensity. The optimum conditions were weight of TCF=10 g, flow rate=50 ml/min $C_i$=100 ppm, concentration of oxygen=20%, concentration of water vapor=100 ppm.

Biological production of $H_2$ from glucose by the chemoheterotropic facultative bacterium, Rhodopseudomonas palustris P4

  • Seol, Eun-Hee;Oh, You-Kwan;Noh, Min-Hyun;Park, Sung-Hoon
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.594-597
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    • 2001
  • RhodopseudolllOllas palustris P4 was studied for $H_2$ production from glucose in batch culture. Important conditions studied include phosphate concentration, initial pH, temperature, glucose concentration, and gas-phase replacement. Optimal $H_2$ production was observed at 60 - 300 mM of phosphate and 7.8 - 8.6 of initial pH. The effect of culture temperature was negligible When glucose concentration increased from 0.1 to 5% (w/v), $H_2$ production increased up to 2% and remained constant thereafter. Intermittent purging of the reaction botlle with Ar gas stimulated the Hl production by alleviating the inhibition by $H_2$. The maximum productivity was 111.1 ml $H_2$/h-1.

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