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Enhancement of Membrane Performance through Surface Hydrophilization of Hydrophobic Porous Flat-sheet Membranes (소수성 다공성 평막의 표면 친수화를 통한 막성능 향상)

  • Kim, Baek-Ahm;Lee, Hak-Min;Lee, Bo-Seong;Kim, Sung-Pyo;Cheong, Seong-Ihl;Rhim, Ji-Won
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.438-443
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    • 2011
  • In order to enhance water permeability through the improvement of fouling phenomena and wettability of hydrophobic porous membranes, various adsorption materials, i.e., poly(vinyl amine), poly (styrene sulfonic acid), poly(vinyl sulfonic acid), and poly(acrylamide-co-acrylic acid) were adsorbed onto the surface of polyethylene (PE) porous membrane. The concentration of adsorption solutions, adsorption time, the sort of salts and their ionic strength were varied, and the pure water permeability of their resulting adsorbed membranes was measured. In general, water permeability increased with an initial increase in the concentration of adsorption solution, adsorption time, and ionic strength and then decreased with a further increase. The pure water permeability of 375 $L/m^2h$(LMH), 35% enhancement, was obtained at a condition of poly(vinyl sulfonic acid) 1000 ppm, $Mg(NO_3)_2$ ionic strength(IS) 0.1, and adsorption time 150 sec, while the 50% (411 LMH) and 35% (374 LMH) enhancements were obtained at conditions of poly(styrene sulfonic acid) 1000 ppm, adsorption time 60 sec, and NaCl IS 0.1 and 0.2, respectively.

SOME PHYSIOLOGICAL STUDIES ON THE UTILIZATION OF ORGANIC SUBSTRATES BY EUGLENA GRACILIS VAR. BACILLA 10616 IN LIGHT AND IN DARKNESS ("유-그레나"의 명암배양에 따르는 유기질의 이용과 호흡 및 생장에 대하여)

  • Lee, Min-Jai
    • Journal of Plant Biology
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    • v.2 no.1
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    • pp.1-12
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    • 1959
  • 1) The comparative studies of the quantitative measurement of growth characteristics and utilization of substrates by Euglena gracilis var. bacilla 10616 in the light and in darkness have been carried out. Eodogenous respiration, effect of respiratory inhibitors and responses to the added substrates for the exogenous respiration are also investigated. 2) All cultures are grown in the open air under the continuous illumination of fluorescent light of 3500 lux at room termperature, the growth rate of the culture in the basal medium added 0.5% lactate is found to be the highest. The growth rate decreases successively for the cultures of 0.5% sucinate, 0.5% Na-acetate, 0.5% malate, and control. There is no growth in the basal meidum added 0.5% butyrate and 0.5% hydroquinone. The similar results are obtained for the mentioned cultures in the darkness. However, the growth rate in basal medium added 0.5% glucose and 0.5% sucrose does seem to increase in the darkness unlike the illumination. 3) The endogenous rate of respiration for the organism cultured photosynthetically is about 12.94ul 02/mg/hr, in basal medium and the respiratory quotient is about 0.84. The rate is decreased by starvations to 6.5ul 02/mg/hr, about to a half, but the respiratory quotient does net change. 4) The oxygen consomption during initial 2 hours in suspending solution ranging from pH 4.5 to pH 9.3 is highest at pH 4.5 in which the algae had grown, at pH 5.5 and at pH 6.9. 5) Endogenous respiration of the cells is strongly inhibited by 0.1M of potassium cyanide, malomic acid, sodium fluoride and iodo-acetic acid. It is also strongly inhibited by 0.01M of potassium cyanide. 6) The respiratory response to added substrates for the exogenous respiration in the organism is coincided with the rate in the basal medium added the substrate in light and in darkness, whether the cells are fed or starved. 7) According to the results of this study, there seems to be the flexibility of the interconversion between photosynthesis and chemosynthesis, heterotropic mode of metabolism, in Euglena gracilis var. bacillaris, and that this organism utilizes the lactate most. It also may be suggested that the enayme systems linked in the each steps of Embden-Myerhof-Parnas path way and TCA cycle seem to exist in this organism.

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Adsorption Properties for Heavy Metals Using Hybrid Son Exchange Fibers with Sulfonated PONF-g-Styrene by Radiation Polymerization and Cation Exchange Resin (방사선 중합 설폰화 PONF-g-스티렌과 양이온교환수지 복합 이온교환섬유의 중금속 흡착 특성)

  • Baek, Ki-Wan;Cho, In-Hee;Nho, Young-Chang;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.525-531
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    • 2006
  • In this study, Sulfonated PONF-g-styrene ion exchange fibers were synthesized by radiation induced graft copolymerization. And also, hybride ion exchange fibers, which was combined sulfonated PONF-g-styrene fibers and cationic ion exchange resin, were fabricated by hot melt adhesion method and then their adsorption properties were investigated. ion exchange capacity and water content of hybrid ion exchange fibers increased as compared with those of bead and ion exchange fiber. Their maximum values were 4.76 meq/g and 23.5%, respectively. Adsorption breakthrough time for mercury of hybrid ion exchange fiber was slower than those of bead resin and fibrous ion exchanger. It's value was 130 minutes. Their breakthrough time become short as increasing of pH, and concentration. The initial breakthrough time was observed before and after 10 minutes as increasing of concentration. The adsorption of hybrid ion exchange fibers for $Hg^{2+}\;Pb^{2+},\;Cd^{2+}$ among heavy metals in the mixed solution was observed before 20 min. And also, The adsorption for $Hg^{2+}$ among the heavy metals by hybride ion exchange fibers was observed.

The Effect of Potassium Phosphate as a pH Stabilizer on the Production of Gellan by Sphingomonas paucibilis NK-2000 (Sphingomonas paucibilis NK-2000에 의한 젤란의 생산에 미치는 pH 안정제로서의 인산칼슐의 영향)

  • Lee, Nam-Kyu;Jo, Young-Bae;Jin, Il-Hyuck;Son, Chang-Woo;Lee, Jin-Woo
    • Journal of Life Science
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    • v.19 no.8
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    • pp.1033-1038
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    • 2009
  • Maximal productions of gellan by Sphingomnas paucibilis NK2000 from 20 g/l glucose and 10 g/l soybean pomace were 7.46 g/l in a flask and 7.35 g/l in a 7 l bioreactor, when the initial pH of media was 6.8. Maximal production of gellan in a 7 l bioreactor under pH control by sodium hydroxide was 8.42 g/l, whereas that under control by potassium phosphate was 8.50 g/l. The optimal concentration of potassium phosphate in a medium for production of gellan by S. paucibilis NK2000 was found to be 5.0 g/l. Maximal production of gellan in a medium containing 5.0 g/l potassium phosphate without pH control was 8.93 g/l in a 7 l bioreactor. In this study, a simple process without pH control was developed to enhance the production of gellan, with optimized concentration of potassium phosphate in the medium.

Effect of Pasteurization on Quality Characteristics of Low Salt Dongchimi Juice (저염 동치미 쥬스의 저온살균이 품질 특성에 미치는 영향)

  • Um, Dae-Hyun;Chang, Hak-Gil;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.29 no.4
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    • pp.730-736
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    • 1997
  • Pasteurization of low salt dongchimi juice was studied for the effect of heating temperature and time on total viable counts and some physicochemical and sensory properties. The juice was prepared by fermentation of the radish at $20^{\circ}C$ in 0.5% NaCl solution. Heating the juice (pH 3.8) at $60{\sim}100^{\circ}C\;for\;5{\sim}30$ min caused little changes in pH and total acidity while the lightness (L value) was decreased and the turbidity, a and b values of color were increased as the heating temperature and time increased. The total viable counts of microorganisms was significantly decreased to 18 at $60^{\circ}C$ and 6 at $70^{\circ}C$ after 30 min heating and was not detected after heating at 90 and $100^{\circ}C$ for 10 min. The sensory test showed that heating up to $70^{\circ}C$ for 20 min caused a little cooked off-flavor. After storage of the pasteurized juices at $30^{\circ}C$ for 10 days, the pH, total acidity and color were changed little while the unheated juice changed significantly. The total viable counts of microorganisms was also remained initial level after pasteurization. Therefore pasteurization at $60^{\circ}C$ for 30 min or $70^{\circ}C$ for 20 min was recommendable in the aspects of storage stability and quality characteristics.

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Physiological Characterization of Lactobacillus sp. JK-8 Isolated from Shrimp Aquaculture Pond (새우양식장에서 분리한 Lactobacillus sp. JK-8의 생리적 특성)

  • Chun Jae-Woo;Ma Chae-Woo;Oh Kye-Heon
    • Korean Journal of Microbiology
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    • v.41 no.1
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    • pp.18-23
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    • 2005
  • The purpose of this work was to investigate the physiological characteristics of Lactobacillus sp. JK-8 isolated from a shrimp aquaculture pond. The strain JK-8 was grown on MRS media, and morphological and physiological characteristics of the strain were examined. The bacterium was identified as a strain of the genus Lactobacillus on the basis of BIOLOG test. Strain JK-8 produced both lactic acid and acetic acid, which were responsible for the pH decrease during growth. Concentrations of lactic acid and acetic acid increased to 192.8 mM and 43.6 mM, respectively, and the initial pH 7.0 of the cultures decreased to 3.8 at the end of incubaction. The bacteriocidal effect against eight target bacteria was examined with 5-fold concentrated culture supernatants. All bacteria tested in this work were completely killed within 3 hrs after treatment with the culture supernatant. The bacteriocidal effects were clearly observed, only when the pH of the culture supernatants were not adjusted. HPLC was used to reslove lactic acid and acetic acid in the culture solution, and GC-MS was used to verify the metabolites.

The Solubility of Ozone in Deionized Water and its Cleaning Efficiency (초순수내에서의 오존의 용해도와 세정효과)

  • Han, Jeoung-Hoon;Park, Jin-Goo;Kwak, Young-Shin
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.532-537
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    • 1998
  • The purpose of this study was to investigate the behavior of ozone in DI water and the reaction with wafers during the semiconductor wet cleaning process. The solubility of ozone in DI water was not only dependent on the temperature but also directly proportional to the input concentration of ozone. The lower the initial ozone concentration and the temperature, the longer the half-life time of ozone. The reaction order of ozone in DI water was calculated to be around 1.5. The redox potential reached a saturation value in 5min and slightly increased as the input ozone concentrations increased. The completely hydrophilic surface was created in Imin when HF etched silicon wafer was cleaned in ozonized DI water containing higher ozone concentrations than 2ppm. Spectroscopic ellipsometry measurements showed that the chemical oxide formed by ozonized DI water was measured to be thicker than that by piranha solution. The wafers contaminated with a non-ionic surfactant were more effectively cleaned in ozonized DI water than in piranha and ozonized piranha solutions.

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Prediction of Pathway and Toxicity on Dechlorination of PCDDs by Linear Free Energy Relationship (다이옥신의 환원적 탈염화 분해 경로와 독성 변화예측을 위한 LFER 모델)

  • Kim, Ji-Hun;Chang, Yoon-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.125-131
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    • 2009
  • Reductive dechlorination of polychlorinated dibenzo-p-dioxins (PCDDs) and its toxicity change were predicted by the linear free energy relationship (LFER) model to assess the zero-valent iron (ZVI) and anaerobic dechlorinating bacteria (ADB) as electron donors in PCDDs dechlorination. Reductive dechlorination of PCDDs involves 256 reactions linking 76 congeners with highly variable toxicities, so is challenging to assess the overall effect of this process on the environmental impact of PCDD contamination. The Gibbs free energies of PCDDs in aqueous solution were updated to density functional theory (DFT) calculation level from thermodynamic results of literatures. All of dechlorination kinetics of PCDDs was evaluated from the linear correlation between the experimental dechlorination kinetics of PCDDs and the calculated thermodynamics of PCDDs. As a result, it was predicted that over 100 years would be taken for the complete dechlorination of octachlorinated dibenzo-p-dioxin (OCDD) to non-chlorinated compound (dibenzo-p-dioxin, DD), and the toxic equivalent quantity (TEQ) of PCDDs could increase to 10 times larger from initial TEQ with the dechlorination process. The results imply that the single reductive dechlorination using ZVI or ADB is not suitable for the treatment strategy of PCDDs contaminated soil, sediment and fly ash. This LFER approach is applicable for the prediction of dechlorination process for organohalogen compounds and for the assessment of electron donating system for treatment strategies.

A Study on the Stability of Langmuir-Blodgett(LB) Films of L-${\alpha}$-Phosphatidylethanolamine Monolayer (L-${\alpha}$-Phosphatidylethanolamine 단분자층 LB막의 안정성에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.44-49
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    • 2014
  • We were investigated by cyclic voltammetry to the stability through the electrochemical characteristics of phospholipid(L-${\alpha}$-phosphatidylethanolamine, LAPE) monolayer LB films. LAPE monolayer LB films was deposited by the LB method on the indium tin oxide(ITO) glass. The electrochemical properties was measured by cyclic voltammetry with a three-electrode system in 0.5 N, 1.0 N, 1.5 N and 2.0 N $KClO_4$ solution. The measuring range is continuously oxidized to 1650 mV, with an initial potential of -1350 mV was reduced. Scanning rates of 50, 100, 150, 200, and 250 mV/s was set. As a result, LB monolayer films of LAPE was appeared on irreversible processes by the oxidation current from the cyclic voltammogram. Diffusion coefficient (D) of LAPE was calculated 195, 15.9, 5.75, 1.38 and $0.754cm^2s^{-1}{\times}10^{-9}$ at 0.01 N, 0.05 N, 0.10 N, 0.15 N and 0.20 N $KClO_4$ solutions, respectively.

A Study on CSV of Social Economy and Consumer Perspective (사회적경제와 소비자 관점의 공유가치창출(CSV) 연구)

  • Lee, Young-Il;Kim, Young-Shin
    • Journal of Distribution Science
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    • v.13 no.12
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    • pp.53-63
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    • 2015
  • Purpose - Recently, creating shared value (CSV) has attracted attention through plan sustainability and the growth of corporate management. Porter and Kramer (2011) defined the core concept of CSV as social value, economic profits, improvements in the economic social condition, and reinforcing competitiveness. The purpose of CSV, which is to pursue economic profits through a social solution to the problem, agrees with managing the objective of a social enterprise that prioritizes the pursuit of profits through the realization of a social purpose. Today, CSV studies focus on CSR and sustainability and reinforce competitiveness. However, few studies focused on the social economy. Precedent studies examined CSV using a company example, and few studies exist from the perspective of consumers and the point of view of a market society. Research design, data, and methodology - Therefore, this study examines CSV in comparison to a background of the social economy. This study also investigates and analyzes the concept of social value from the point of view of consumers, social problems, consumption value, corporate value, and the influence of consumers. This article develops three hypotheses. Hypothesis 1 investigates the correlation with social innovation that consumers thought as being necessary for social innovation by a company. Hypothesis 2 is used to confirm the influence of consumers in CSV. Therefore, this article investigates the influence of consumers on consumption action for companies that are indifferent to social problems. Hypothesis 3 is used to verify the correlation between the value that consumers demand through consumption and the corporate value that companies pursue other than profits. The three hypotheses were adopted and met the standard for suitability. Results - The importance of the CSV study from the consumer perspective was confirmed using the influence of consumers on CSV. Because the objective of company activities is either the consumer or the market, the influence that extends to interactions between the company and consumers to ensure the success of a business is significant. Regarding the CSV study, because it was an initial study, various approaches are subsequently developed. However, conceptual and practical case studies on CSV currently exist that may be used to verify the factors that comprise CSV. Therefore, the company example may enable verification of the factors that influence the composition of CSV through identification from the consumer perspective. In addition, studying CSV as an action result (of consumer satisfaction, of a company's profits and competitiveness, and of society's cancellation of a social problem) may enable the realization of a practice paradigm as opposed to simply thought and faith. Conclusions - First, this study confirms the social value of a business through the feasible and common pursuit of consumers by corporations. Second, customer influence accounts for an important part of CSV. Third, shared value commonly provides a necessary advantage to consumers, corporates, and society, and contributes to the economy and healthy social development. Fourth, corporates can conduct a business, generate profits, and realize value through improvements in social problems and by addressing their competitive strengths and weaknesses.