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Degradation of perchloroethylene by ferrate(VI) (Ferrate(VI)를 이용한 퍼클로로에틸렌의 분해특성 연구)

  • Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.1
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    • pp.39-46
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    • 2015
  • The degradation characteristics of perchloroethylene by ferrate(VI) oxidation have been studied. The degradation efficiency of perchloroethylene in aqueous solution was investigated at various values of ferrate(VI) dosage, pH, initial concentration of perchloroethylene and aqueous solution temperature. GC-ECD has been used to analyze the changes of perchloroethylene concentration. The optimum conditions of perchloroethylene degradation were obtained at pH 7.0 and $25^{\circ}C$ of aqueous solution temperature. Also, the experimental results showed that perchloroethylene removal efficiency increased with the decrease of initial concentration of perchloroethylene. Lastly intermediate products were identified by GC-MS techniques. Trichloroethylene and chloroform were identified as reaction intermediates.

Studies on the Natural Dyes(11) -Dyeing Properties of Cochineal Colors for Wool Fibers- (천연염료에 관한 연구(11) -코치닐 색소의 양모섬유 염색성-)

  • 조경래
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.39-49
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    • 1999
  • In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

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A Study on Methodology of the Snow Removal Operation of Air Wing Using Hybrid ACS Algorithm (하이브리드 ACS 알고리즘을 이용한 군 비행단 제설작전 방법연구)

  • Choi, Jung-Rock;Kim, Gak-Gyu;Lee, Sang-Heon
    • Korean Management Science Review
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    • v.30 no.2
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    • pp.31-42
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    • 2013
  • The vehicle routing problem (VRP) can be described as a problem to find the optimum traveling routes from one or several depot (s) to number of geographically scattered customers. This study executes a revised Heterogeneous Vehicle Routing Problem (HVRP) to minimize the cost that needs to conduct efficiently the snow removal operations of Air Wing under available resources and limited operations time. For this HVRP, we model the algorithm of an hybrid Ant Colony System (ACS). In the initial step for finding a solution, the modeled algorithm applies various alterations of a parameter that presents an amount of pheromone coming out from ants. This improvement of the initial solution illustrates to affect to derive better result ultimately. The purpose of this study proves that the algorithm using Hybrid heuristic incorporated in tabu and ACS develops the early studies to search best solution.

Experimental Study on the freezing of Aqueous Binary Solution Saturated Packed bed in a Square Cavity (다공성 물질이 충전된 정방형 밀폐용기 내에서 수용성 혼합용액의 동결거동에 관한 실험적 연구)

  • Choi, J.Y.;Kim, B.C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.4 no.3
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    • pp.175-182
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    • 1992
  • Freezing of the binary solution ($H_2O-NaCl$) saturating a packed bed of spheres is investigated experimentally. The system is cooled through its top surface, and the bottom is maintained at a temperature above the liquidus. Experiments are performed on the hypolutectic side, and the cold wall temperature is lower than the eutectic point. The effects of initial mixture concentration, superheat and glass bead diameter on temperature and concentration distributions are investigated. Supercooling was observed only at early times of the freezing process for experiments with 5% initial salt concentration. Flow visualization experiments and mushy-liquid interface position observations revealed natural convection in the liquid region. Remelting phenomena was not observed at both the solid-mushy and mushy-liquid interfaces.

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FLUX DECLINE DURING THE ULTRA-FILTRATION OF DILUTE SI COLLOIDAL SOLUTION WITH HOLLOW FIBER MEMBRANE

  • Park, Ho-Sang;Nam, Suk-Tae;Jeon, Jae-Hong;Lee, Seok-Ki
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.95-96
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    • 1999
  • The ultrafiltration behavior of dilute colloidal solution containing Si particles has been investigated. The experiments in cross flow mode have been performed at different operating condition by using the membrane with 20 kDa cut-off. The flux decline was due to the development of membrane fouling which was a dynamic process of two distinctive stages. For the high trans-membrane pressure, the pore blocking resistance was dominant at the initial period of filtraion and was followed by the cake resistance. And for the low cross flow velocity, the membrane fouling was governed by the cake filtration model at the initial stage of filtration process. Flux jump was observed temporally during the membrane filtration of mixed feed solution.

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Adsorption Characteristics of Malachite Green Employing Waste Garnet as Adsorbent (폐석류석을 흡착제로 이용한 말라카이트그린 흡착 특성)

  • Baek, Mi-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.216-221
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    • 2007
  • The adsorption characteristics of malachite green on waste garnet have been investigated for its treatment from aqueous solution by employing waste garnet which is generated from the abrasive production process as an adsorbent. The influential factors examined were the initial concentration of malachite green in solution, reaction temperature, and the amount of adsorbent. Also, the effect of the modification of the surface of adsorbent on adsorption was examined. As the initial malachite green was increased with reaction temperature and the color removal of malachite green-containing solution was promoted with the amount of adsorbent. Finaly, increased adsorption of malachite green could be attained when the surface of glass was modified by hexamethyldisilazane.

A theoretical analysis on the inviscid stagnation-flow solidification problem (비점성 정체 유동 응고 문제에 대한 이론적 해석)

  • 유주식
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.1-11
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    • 2000
  • This study investigates the problem of phase change from liquid to solid in the inviscid stagnation flow. The solution of dimensionless governing equations is determined by the three dimensionless parameters of (temperature ratio/conductivity ratio), Stefan number, and diffusi-vity ratio. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The equilibrium state is dependent on (temperature ratio/conductivity ratio), but is independent of Stefan number and diffusivity ratio. The effect of fluid flow on the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state, and the characteristics of the solidification process for all the dimensionless parameters are elucidated.

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An Iterative Local Search Algorithm for Rural Postman Problems (Rural Postman Problem 해법을 위한 Iterative Local Search 알고리즘)

  • 강명주
    • Journal of the Korea Society of Computer and Information
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    • v.7 no.1
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    • pp.48-53
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    • 2002
  • This paper Proposes an iterative Local Search (ILS) algorithm for Rural Postman Problems (RPPs). LS searches neighbors from an initial solution in solution space and obtains a nearoptimal solution which can be a local-minima. As an extension of LS, the ILS algorithm is a method that uses various initial solutions for LS. Hence. ILS can overcome the defect of LS. This paper proposes LS and ILS methods for 18 RPPs and analyzes the results of LS and ILS. In the simulation results, the ILS method obtained the better results than the LS method.

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SOLUTIONS OF A CLASS OF COUPLED SYSTEMS OF FUZZY DELAY DIFFERENTIAL EQUATIONS

  • Wu, Yu-ting;Lan, Heng-you;Zhang, Fan
    • Nonlinear Functional Analysis and Applications
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    • v.26 no.3
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    • pp.513-530
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    • 2021
  • The purpose of this paper is to introduce and study a class of coupled systems of fuzzy delay differential equations involving fuzzy initial values and fuzzy source functions of triangular type. We assume that these initial values and source functions are triangular fuzzy functions and define solutions of the coupled systems as a triangular fuzzy function matrix consisting of real functional matrices. The method of triangular fuzzy function, fractional steps and fuzzy terms separation are used to solve the problems. Furthermore, we prove existence and uniqueness of solution for the considered systems, and then a solution algorithm is proposed. Finally, we present an example to illustrate our main results and give some work that can be done later.

An analytical solution for equations and the dynamical behavior of the orthotropic elastic material

  • Ramady, Ahmed;Atia, H.A.;Mahmoud, S.R.
    • Advances in concrete construction
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    • v.11 no.4
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    • pp.315-321
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    • 2021
  • In this article, an analytical solution of the dynamical behavior in an orthotropic non-homogeneity elastic material using for elastodynamics equations is investigated. The effects of the magnetic field, the initial stress, and the non-homogeneity on the radial displacement and the corresponding stresses in an orthotropic material are investigated. The analytical solution for the elastodynamic equations has solved regarding displacements. The variation of the stresses, the displacement, and the perturbation magnetic field have shown graphically. Comparisons are made with the previous results in the absence of the magnetic field, the initial stress, and the non-homogeneity. The present study has engineering applications in the fields of geophysical physics, structural elements, plasma physics, and the corresponding measurement techniques of magneto-elasticity.