• Journal of the Korean Society of Safety
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• v.30 no.4
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• pp.86-91
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• 2015

The flash point is used to categorize inflammable liquids according to their relative flammability. Such a categorization is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures(n-octane+n-decane and n-octane+n-dodecane) has been measured for the entire concentration range using Seta-flash closed cup tester based on the ASTM D3278 method. The closed cup flash point temperature was estimated using the UNIFAC(Universal Functional Activity Coefficient) group contribution model. The experimentally derived flash point was also compared with the predicted flash point from the UNIFAC model. The UNIFAC model is able to estimate the flash point fairly well for n-octane+n-decane mixture and n-octane+n-dodecane mixture.

• Journal of Energy Engineering
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• v.24 no.4
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• pp.18-23
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• 2015

The flash point is used to categorize inflammable liquids according to their relative flammability. The flash point is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures($CCl_4+o-xylene$ and $CCl_4+p-xylene$) has been measured for the entire concentration range using Tag open cup tester. The flash point temperature was estimated using Raoult's law, UNIQUAC model and empirical equation. The experimentally derived flash point was also compared with the predicted flash point. The empirical equation is able to estimate the flash point fairly well for $CCl_4+o-xylene$ and $CCl_4+p-xylene$ mixture.

• Journal of the Society of Disaster Information
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• v.20 no.1
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• pp.47-59
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• 2024

Purpose: This study aims to propose measures for the prevention of fire and explosion accidents within manufacturing facilities by improving the existing classification criteria for hazardous locations based on the leakage patterns of flammable liquids. The objective is to suggest ways to safely manage ignition sources and combustible materials. Method: The hazardous locations were calculated using "KS C IEC 60079-10-1," and the calculated explosion hazard distances were visualized in 3D. Additionally, the formula for the atmospheric dispersion of flammable vapors, as outlined in "P-91-2023," was utilized to calculate the dispersion rates within the hazardous locations represented in 3D. Result: Visualization of hazardous locations in 3D enabled the identification of blind spots in the floor plan, facilitating immediate recognition of ignition sources within these areas. Furthermore, when calculating the time taken for the Lower Explosive Limit (LEL) to reach within the volumetric space of the hazardous locations represented in 3D, it was found that the risk level did not correspond identically with the explosion hazard distances. Conclusion: Considering the atmospheric dispersion of flammable liquids, it was concluded that safety management should be conducted. Therefore, a method for calculating the concentration values requiring detection and alert based on realistically achievable ventilation rates within the facility is proposed.