• Title/Summary/Keyword: Inertness

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Synthesis of Porous Carbon Particles for the Absorption of Mercury (액상수은 제어를 위한 다공성 탄소입자 제조에 관한 연구)

  • Lee, Jung-Min;Kang, Shin-Jae;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.305-305
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    • 2009
  • The carbon nano-structured materials could be applied to the fields of advanced fillers, templates, electrode materials, sensor, storage, and absorption materials. The polyacrylonitrile (PAN) based carbon nano-particles provide the remarkable properties of high specific surface area, large pore volume, chemical inertness, and good mechanical stability. In this study, well-defined carbon nano-particles were obtained through pyrolysis of polyacrylonitrile based particles. The precursor nano-particles were prepared by modified aqueous dispersion polymerization using hydrophilic poly(vinyl alcohol) in a water/ N,N-dimethylformamide mixture media. Synthesized precursor nanoparticles have relatively monodisperse particles ranging 80 ~ 250nm. Stable spherical particles are obtained without coagulum or secondary particles in our system. The characteristic of the carbon nanoparticles were investigated in terms of surface area, morphology, and size distribution.

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A Study on the Tensile Characteristics of Spectra/Vinylester Composites with Ion Beam Treatment of Spectra Fibers. (이온빔으로 표면처리한 스펙트라/비닐에스테르 복합재의 인장특성)

  • 신동혁;이경엽
    • Journal of the Korean institute of surface engineering
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    • v.35 no.4
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    • pp.206-210
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    • 2002
  • The use of Spectra fibers as fiber cloth is increasing because of their excellent impact resistance. However, a major limitation on the use of Spectra fibers is a chemical inertness. In this Study, Spectra fibers were surface-treated using Ar$^{+}$ ion beam under oxygen environment to improve the tensile property of Spectra/vinylester composites. The effect of surface treatment of Spectra fibers on the tensile property of Spectra/vinylester composites was determined from tensile tests using Spectra/vinylester composite specimens with and without a hole. It was found that the tensile stiffness and strength of surface-treated case were 22% and 17% higher than those of untreated case for specimens with no hole. The maximum load of surface-treated case was about 15% higher than that of untreated case for specimens with a hole.

An Experimental Study on the Characteristics of Deformation of Repaired Epoxy Resin by Flexural Strength Test (휨시험에 의한 에폭시 균열주입제의 변형특성에 관한 실험적 연구)

  • Kim Jae Sung;Bae Jun Young;Kim Kyung Deok;Kang Suk Pyo;Kawk Ju Ho;Kim Jung Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.269-272
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    • 2005
  • Epoxy resins are gradually becoming some of the most important and versatile polymers in modem civil engineering. Because epoxy resins have some unigue properties, such as toughness, versatility of viscosity and curing conditions, good handling characteristics, high adhesive strength, inertness, low shrinkage compared to most other thermo-setting resins and concrete, and resistance to chemicals, they have found many applications in construction castings, repair materials, road or bridge deck pavements, coatings, and as structural or non structural adhesives. In this applications, epoxy resins are widely used for polymer concretes, grouting materials, injection glues, and sealants. In this paper, characteristics of deformation of repair material after repaired have been investigated by viscosity of repair material and the width of crack. It is believed that flexural strength of epoxy resin with low viscosity is high because tensile strength is high and elongation at break is low, fracture energy is low.

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Characterization of Tribological Properties of DLC Films Prepared by Different Deposition Method (증착방법에 따른 DLC 막의 마찰-마모 특성평가)

  • Oh, Yoon-Suk
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.497-504
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    • 2009
  • DLC is considered as the candidate material for application of moving parts in automotive components relatively in high pressure and temperature operating conditions for its high hardness with self lubrication and chemical inertness. Different deposition method such as arc plating, ion gun plating and PECVD were used for comparing mechanical and tribological properties of each DLCs deposited on stainless steel with 1 um thick respectively. Among these 3 types of DLCs, the arc plated DLC film showed highest value for wear resistance in dry condition. From the results of analysis for physical properties of DLC films, it seems that the adhesion force and crack initiation modes were more important factors than intrinsic mechanical properties such as hardness, elastic modulus and/or roughness to the wear resistance of DLC films. Raman spectroscopy was used for understanding chemical bonding natures of each type of DLC films. Typical D and G peaks were identified based on the deposition method. Hardness of the coating layers were identified by nanoindentation method and the adhesions were checked by scratch method.

A Study on the Chromatographic Separation of Proteins Using Fibrous Beds(I) -Adsorbent Fiber Manufactures and Data Handling- (섬유층을 이용한 단백질의 크로마토그래피적 분리에 관한 연구(I) -흡착성 섬유제조 및 자료처리-)

  • 박돈희;박주정
    • KSBB Journal
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    • v.9 no.2
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    • pp.98-103
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    • 1994
  • A bed configuration wherein sheets of modified fibrous polyethylene are potted within a Millipore Filter Cartridge matrix has been developed. Polyethylene fibers form sturdy beds but the native hydrophobicity and inertness of polyethylene have precluded their use in protein chromatography The polyethylene fibers used in this system were modified by plasma oxidation and further derivatization. The resulting fibers are hydrophilic, bind protein reversibly and serve as an anion-exchange stationary phase. Separation of Bovine Serum Albumin on this bed, as well as results of basic studies on capacity and reversibility of binding within a fibrous bed and experimental data handling system are shown.

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Friction on the Tool-chip Interface Under Liquid Nitrogen Cooling (공구와 칩 사이에서의 Liquid Nitrogen의 마찰 효과)

  • Jun Seong Chan
    • Journal of the Korea Safety Management & Science
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    • v.4 no.2
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    • pp.237-249
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    • 2002
  • A cutting fluid can improve machining quality and tool life by maintaining the tool toughness and by providing a lubrication effect to reduce the friction between the chip and tool interface. Although liquid nitrogen as an environmentally safe coolant has been widely recognized in cryogenic machining, its function as a lubricant is plausible due to its chemical inertness, physical volatility and low viscosity. Since a reduced friction is a direct witness of the lubrication effect from a tribological viewpoint, this paper presents an evaluation of the apparent friction coefficient on the tool-chip interface in cryogenic cutting operations to prove and characterize the lubricity of LN2 in cryogenic machining. The mathematical approaches have been formulated to derive the normal and frictional forces on the tool-chip interface for the oblique cutting tests.

The Effects of Interlayer on the DLC Coating (중간층이 DLC 코팅에 미치는 영향)

  • Song, Jin-Soo;Nam, Tae-Woon
    • Corrosion Science and Technology
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    • v.10 no.2
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    • pp.65-70
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    • 2011
  • DLC is considered as the candidate material for application of moving parts in automotive components relatively in high pressure and temperature operating conditions for its high hardness with self lubrication and chemical inertness. The properties of interlayer between the substrate and the DLC film were studied. Arc ion plating method have been employed to deposit onto substrate and sputtering method was used for synthesizing DLC onto interlayer. Among these six types of interlayer, deposited DLC film onto TiCN showed excellent value for characteristics. From the results of analysis for physical properties of DLC films, it seems that the adhesion forces were more important factors than intrinsic mechanical properties such as hardness, roughness and wear resistance of DLC films. AFM(Atomic Force Microscope) was used for understanding roughness of DLC films. Hardnesses of the coating layers were identified by nano-indentation method and adhesions were checked by scratch method.

Carbon Fibers (I): General Understanding and Manufacturing Techniques of Carbon Fibers

  • Seo, Min-Kang;Choi, Kyeong-Eun;Min, Byung-Gak;Park, Soo-Jin
    • Carbon letters
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    • v.9 no.3
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    • pp.218-231
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    • 2008
  • Carbon fibers are a new breed of high-strength materials which have been described as a fiber containing at least 90% carbon obtained by the controlled pyrolysis of appropriate fibers. Carbon fiber composites are ideally suited to applications where strength, stiffness, lower weight, and outstanding fatigue characteristics are critical requirements. They also can be used in the occasion where high temperature, chemical inertness and high damping are important. In recent decades, carbon fibers have found wide applications in commercial and civilian aircraft, recreational, industrial, and transportation markets. Therefore, understanding the basic structure, synthesis and physicochemical properties of carbon fibers is very important to apply them as a precursor of above applications. This review paper discuss the general information and manufacture technique of carbon fibers used for improving the performance of composite materials in various industries for the present.

Platinum and carbon nano tube addition in carbon black counter electrode for dye-sensitized solar cells

  • Lee, Su Young;Kim, Sang Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.229-230
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    • 2012
  • Platinum (Pt) has been commonly used as a counter electrode material in dye-sensitized solar cells, because it has high catalytic activity and electric conductivity as well as chemical inertness with iodide electrolyte. However, Pt is too expensive to be commercialized. Therefore, in the present study, carbon black counter electrode with Pt and carbon nano tube (CNT) was investigated. The power conversion efficiency with Pt added carbon black electrode was lower than hat of pure Pt electrode which was 6.47 %. By adding 3 wt% Pt to the carbon black counter electrode, the power conversion efficiency was maximized at 5.88 %. On them, additional adding of 1 wt % CNT, the power conversion efficiency (${\eta}$)wasincreasedupto6.21%. The reason of power conversion efficiency improvement with a proper amount of Pt and CNT was examined by comparing the impedance properties measured using EIS.

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Tandem laser-induced breakdown spectroscopy laser-ablation inductively-coupled plasma mass spectrometry analysis of high-purity alumina powder

  • Lee, Yonghoon;Kim, Hyang
    • Analytical Science and Technology
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    • v.32 no.4
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    • pp.121-130
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    • 2019
  • Alumina is one of the most important ceramic materials because of its useful physical and chemical properties. Recently, high-purity alumina has been used in various industrial fields. This leads to increasing demand for reliable elemental analysis of impurities in alumina samples. However, the chemical inertness of alumina makes the sample preparation for conventional elemental analysis a tremendously difficult task. Herein, we demonstrated the feasibility of laser ablation for effective sampling of alumina powder. Laser ablation performs sampling rapidly without any chemical reagents and also allows simultaneous optical emission spectroscopy and mass spectrometry analyses. For six alumina samples including certified reference materials and commercial products, laser-induced breakdown spectroscopy (LIBS) and laser-ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) analyses were performed simultaneously based on a common laser ablation sampling. LIBS was found to be useful to quantify alkali and alkaline earth metals with limits-of-detection (LODs) around 1 ppm. LA-ICP-MS could quantify transition metals such as Ti, Cu, Zn, and Zr with LODs in the range from a few tens to hundreds ppb.