• Macromolecular Research
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• v.15 no.6
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• pp.565-574
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• 2007

In this study, five representative, commercially available polymers, Ultem 1000 polyetherimide, Kapton polyimide, phenolic resin, polyacrylonitrile and cellulose acetate, were used to prepare pyrolyzed polymer membranes coated on a porous {\alpha}-alumina$ tube via inert pyrolysis for gas separation. Pyrolysis conditions (i.e., final temperature and thermal dwell time) of each polymer were determined using a thermogravimetric method coupled with real-time mass spectroscopy. The surface area and pore size distribution of the pyrolyzed materials derived from the polymers were estimated from the nitrogen adsorption/desorption isotherms. Pyrolyzed membranes from polymer precursors exhibited type I sorption behavior except cellulose acetate (type IV). The gas permeation of the carbon/{\alpha}-alumina$ tubular membranes was characterized using four gases: helium, carbon dioxide, oxygen and nitrogen. The polyetherimide, polyimide, and phenolic resin pyrolyzed polymer membranes showed typical molecular sieving gas permeation behavior, while membranes from polyacrylonitrile and cellulose acetate exhibited intermediate behavior between Knudsen diffusion and molecular sieving. Pyrolyzed membranes with molecular sieving behavior (e.g., polyetherimide, polyimide, and phenolic resin) had a $CO_2/N_2$ selectivity of greater than 15; however, the membranes from polyacrylonitrile and cellulose acetate with intermediate gas transport behavior had a selectivity slightly greater than unity due to their large pore size.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.7
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• pp.889-898
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• 2003

The soot yield is studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effect of turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures and high temperatures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. It is found that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.

• Transactions of the Korean hydrogen and new energy society
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• v.15 no.3
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• pp.220-227
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• 2004

The purpose of this paper is, based on the theoretical background of the principle of gas purification and absorption, and the absorbing ability of metals, to syudy the efficiency of gas purification of inorganic gases using Zr alloys, so as to contribute to the IT industry. To produce and distribute gas with high purity and ultra-high purity, different types of gas purifier are currently being used: distillation type, getter type, catalyst type, absorption at low-temperature type, and membrane separation equipment. From the different purification methods mentioned above, the getter type gas purifier is capable of not only high performance and capacity but also P.O.U(Point Of Use) method. The key of the getter type gas purifier is its efficiency of gas purification, which is the subject chosen for this study.

• Journal of Advanced Marine Engineering and Technology
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• v.23 no.3
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• pp.300-310
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• 1999

A constant-volume combustion chamber is developed to measure the burnt gas temperature over the wide ranges of equivalence ratio from 1.5 to 2.7 and pressure from 0.1 to 2.7 and pressure from 0.1 to 6 MPa by two-color method. The combustion temperature is also calculated by the conventional two-region model. The premixed fuel rich propane-oxygen-inert gas mixtures under high pressures are simultaneously ignited by eight spark plugs located on the circumference of combustion chamber with 45 degree intervals. The eight converging flames compress the end gases to high pressures. The transmissiv-ity in the chamber center during the final stage of combustion at the highest pressure is measured by in situ laser extinction method. Comparisons are made with the combustion temperatures between two-color method and two-region model. It is found that the burnt gas temperature mea-sured by two-color method is higher than that calculated by two-region model because of being the negative temperature gradient on the calculation and the temperature distribution of light path-length on the measurement and the burnt gas temperature for the turbulent combustion is higher than that of the laminar combustion under the same conditions because the heat loss for turbulent combustion is lower due to the shorter combustion period.

• Journal of Powder Materials
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• v.21 no.6
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• pp.422-428
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• 2014

In this study, the reduction kinetics and behaviors of oxides in the water-atomized iron powder have been evaluated as a function of temperature ranging $850-1000^{\circ}C$ in hydrogen environment, and compared to the reduction behaviors of individual iron oxides including $Fe_2O_3$, $Fe_3O_4$ and FeO. The water-atomized iron powder contained a significant amount of iron oxides, mainly $Fe_3O_4$ and FeO, which were formed as a partially-continuous surface layer and an inner inclusion. During hydrogen reduction, a significant weight loss in the iron powder occurred in the initial stage of 10 min by the reduction of surface oxides, and then further reduction underwent slowly with increasing time. A higher temperature in the hydrogen reduction promoted a high purity of iron powder, but no significant change in the reduction occurred above $950^{\circ}C$. Sequence reduction process by an alternating environment of hydrogen and inert gases effectively removed the oxide scale in the iron powder, which lowered reduction temperature and/or shortened reduction time.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.6
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• pp.437-452
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• 2002

The Metropolitan Tracer Experiment (METREX) was performed over the Washington, D.C. area using two inert, non-deposition perfluorocarbon gases for over 1 year period (November 1983∼December 1984). Two perfluorocarbon gas tracers (PDCH, PMCH) were released simultaneously at intervals of every 36 hours for 6 hours, regardless of the meteorological conditions in metropolitan area. Samples were collected continuously for 8 hours at a central downtown and two adjacent suburban locations. Monthly air samples were collected at 93 sites across the whole region (at urban, suburban, and rural locations). The purpose of this study is to simulate INPUFF and ISCST model using METREX data, and to compare calculated and observed concentrations. In the case of INPUFF simulation, two meteorological input data were used. One is result data from wind field model which was calculated by diagnostic wind model (DWM), the other is meteorological data observed at single station. Here, three kinds of model calculation were performed during April and July 1984; they include (1) INPUFF model using DWM data (2) INPUFF model using single meteorological data (3) ISCST model. The monthly average concentration data were used for statistic analysis and to draw their horizontal distribution patterns. Eight-hour-averaged concentration was used to describe movement of puff during the episode period. The results showed that the concentrations calculated by puff model (INPUFF) were better than plume model (ISCST). In the case of puff model (INPUFF), a model run using wind field data produced better results than that derived by single meteorological data.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.8
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• pp.43-54
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• 1999

The effects of equivalence ratio and pressure on burnt gas temperature in premixed fuel rich propane-oxygen-inert gas combustion are investigated over the wide ranges of equivalence ration from 1.5 to 2.7 and pressure from 0.1 to 7 MPa by using a specially designed disk -type constant-voume combustion chamber, The premixtures are simultaneously ignited by eight spark plugs located on the circumference of combustion chamber with 45 degree interals. The eight converging flames compress the end gases to high pressures. The burnt gas temperature is meausured by the nmodifie dtow-colr pyrometry method. The transmissivity in the chamber center during the final stage of combustion at the hightest pressure is meausred by in situ laser extinction method. It is found that a temperature difference between the burnt gas temperature measured by mofidied and conventrational two-color method is 10 to 20 K, but the accuracy of the modified two-color methdo is higher if the local transmissivity in observed region is uniform , and the combustion at higher pressures results gas density conditions and the burnt gas temperature increases as the volume fraction of argon is increased because the specific heat of argon is lower compared to that of nitrogen with a constant equivalence ratio.

• Journal of ILASS-Korea
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• v.15 no.4
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• pp.195-201
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• 2010

Due to its carbon-neutral nature, biogas generated from anaerobic digestion or fermentation of biodegradable wastes is one of the important renewable energy sources to reduce global warming. It is mainly composed of methane and various inert gases such as $CO_2$ and $N_2$, and the actual composition of biogas significantly varies depending on the origin of anaerobic digestion process. Therefore, in order to effectively utilize this fuel as an energy source for electricity, it is important to develop power generation engines which can successfully apply biogas with significant composition variations. In this study, efforts have been made to develop a diesel-biogas duel fuel engine as a way to achieve such a stable power generation. The effects of diesel fuel injection quantity and pressure on stable combustion and engine performance were investigated, and an impact of diesel fuel atomization was discussed. The engine test results show that there exists a 2 stage combustion which consists of diesel pilot fuel burning and premixed biogas/air mixture burning in dual fuel engine operation and optimum diesel injection parameters were suggested for biogases with various compositions and heating values.

• Journal of the Korean Institute of Gas
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• v.15 no.5
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• pp.25-30
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• 2011

Biogas obtained from the biodegradable organic wastes in an anaerobic digester consists of $CH_4$ and inert gases such as $CO_2$ and $N_2$. Since the composition of biogas varies by anaerobic digester conditions and the origin of wastes, it is necessary to respond to these variations so as to make stable combustion and accomplish high efficiency when it is used as a fuel for power generating SI engines. In this study, efforts have been made to investigate the effect of changes in the calorific values of biogas on the engine performance and exhaust characteristics. The biogas was simulated by supplying of $CH_4$ with $N_2$ dilution of various ratios, and ECM was developed to achieve accurate control of ignition and combustion. The results show that as the $CH_4$ concentration of the biogas decreases, the optimal spark timing is advanced due to the elevated thermal capacity and lowered $O_2$ concentration of the in-cylinder charge. Furthermore, since combustion temperature was reduced by increased inert gas, $NO_x$ emissions decreased, whereas THC emissions increased.

• Journal of the Korean Institute of Gas
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• v.16 no.4
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• pp.52-58
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• 2012

Recently, waste gas incineration is increasing due to strong environmental regulatory system in Korea. These incinerating facilities are usually connected with the top of the storage tank through pipeline and incinerate off gas with the flame. Therefore, the flame originated from these facilities is likely to move back into pipeline and might cause an explosion of the storage tank. Accordingly, the purpose of this study is to suggest the preventive measures and the way to improve the safety of these incineration systems through the cause analysis of a major industrial accident occurred in a acrylic acid manufacturing process in Korea. As a result of the study, the preventive measures are suggested as follows. (1) Air or inert gas inflow facilities should be well designed to dilute flammable gases into air or inert gas sufficiently before the blower is restarted in order to prevent the explosion (2) It is needed for the detonation-type flame arresters to be installed on the top of the storage tanks. (3) In case of using the deflagration-type flame arresters, it is necessary to install a rupture disk before the arresters, or blow off the flame outside tanks by connecting the tank top and the incinerator with hood-type pipe. (4) TDR should be installed to be restarted automatically after the momentary power failure.