• Environmental Engineering Research
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• v.24 no.3
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• pp.521-528
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• 2019

Electrochemical method was used for the fracturing flow-back fluid treatment in Guangyuan oilfield. After performing electrolysis, we found that the amount of $H_2$ gas produced by electrode was closely related to the combination mode of electrodes and electrode materials. Using an aluminium electrode resulted in a large $H_2$ production of each electrode combination, whereas inert anode and cathode materials resulted in low $H_2$ production. Then, the relationship between the gas production of $H_2$ and the treatment efficiency of fracturing flow-back fluid in Guangyuan oilfield was studied. Results showed that the turbidity removal and decolourisation rates of fracturing flow-back fluid were high when $H_2$ production was high. If the $H_2$ production of inert electrode was large, the energy consumption of this inert electrode was also high. However, energy consumption when an aluminium anode material was used was lower than that when the inert electrode was used, whereas the corresponding electrode combination production of $H_2$ was larger than that of the inert electrode combination. When the inert electrode was used as anode, the gas production type was mainly $O_2$, and $Cl_2$ was also produced and dissolved in water to form $ClO^-$. $H_2$ production at the cathode was reduced because $ClO^-$ obtained electrons.

• Journal of the Korean institute of surface engineering
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• v.25 no.2
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• pp.73-81
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• 1992

The composite coating of suspended inert particles $\alpha$-Al2O3 and copper from acid sulphate bath was investigated at the Rotating Disk Electrode. Effects of rotation speeds of electrode, physical properties of electrolyte, the size and concentration of suspended particles on the codeposition ratio of Al2O3 and the enhancement of mass transfer of copper ions were examined. Particularly, new experimental method for the measurement of the codeposition ratio was suggested and also the characteristics of the composite coating layer were measured by Rutherford Backscattering Spectrometry. Mass transfer of suspended particles system were increased up to 40% more than those of without suspended particles system. Optimum conditions of current density, hydrodynamics of RDE, and particles concentration showing maximum codeposition ratio were appeared in our experimental ranges. It was shown that the suspended inert particles were codeposited mainly near the surface of the composite coating layer.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.1
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• pp.33-41
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• 2022

Liquid Bi pool is a candidate electrode for an electrometallurgical process in the molten LiCl-KCl eutectic to treat the spent nuclear fuels from nuclear power plants. The electrochemical behavior of Bi³⁺ ions and the electrode reaction on liquid Bi pool were investigated with the cyclic voltammetry in an environment with or without BiCl₃ in the molten LiCl-KCl eutectic. Experimental results showed that two redox reactions of Bi³⁺ on inert W electrode and the shift of cathodic peak potentials of Li⁺ and Bi³⁺ on liquid Bi pool electrode in molten LiCl-KCl eutectic. It is confirmed that the redox reaction of lithium with respect to the liquid Bi pool electrode would occur in a wide range of potentials in molten LiCl-KCl eutectic. The obtained data will be used to design the electrometallurgical process for treating actinide and lanthanide from the spent nuclear fuels and to understand the electrochemical reactions of actinide and lanthanide at liquid Bi pool electrode in the molten LiCl-KCl eutectic.

• Journal of Welding and Joining
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• v.20 no.5
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• pp.127-133
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• 2002

In this study, metal transfer characteristics in pulsed current metal inert gas (MIG) welding of aluminum was investigated. Based on the metal transfer characteristics from direct current electrode negative MIG welding, the one drop per one pulse(ODOP) condition was predicted and compared with experimental data. The results indicated that experimental pulse range for the ODOP condition is wider than that predicted from the DCEP MIG welding data. In addition, more stable metal trnasfer behavior was obtained at the higher end of the ODOP condition.

• Proceedings of the KIPE Conference
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• 2000.07a
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• pp.581-586
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• 2000

Gas metal arc welding(GMAW) uses a continuously fed electrode as a filler metal. The arc is shielded from atmospheric contamination by an inert gas active or inert/active gas mixture delivered through the welding gun and cable assembly. The recent research topics on $CO_2$ are welding machines are focused mainly on the reduction method of generated spatter by using new type consumable electrode metal or inverter control method. The various current waveform control methods have been researched for welding performance improvement. Until now current waveform control methods reduce to spatter occurred by instantaneous short circuiting,. but these methods is drawback that no reduce spatter occurred by arc reignition. In this paper the previous arc reignition current control method for welding performance improvement of inverter arc welding machine is studied and compared the various current control methods with the previous arc reignition current control method.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.19 no.2
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• pp.161-176
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• 2021

In this study, the electrochemical behavior of Sm on the binary liquid Al-Ga cathode in the LiCl-KCl molten salt system is investigated. First, the co-reduction process of Sm(III)-Al(III), Sm(III)-Ga(III), and Sm(III)-Ga(III)-Al(III) on the W electrode (inert) were studied using cyclic voltammetry (CV), square-wave voltammetry (SWV) and open circuit potential (OCP) methods, respectively. It was identified that Sm(III) can be co-reduced with Al(III) or Ga(III) to form Al_zSm_y or Ga_xSm_y intermetallic compounds. Subsequently, the under-potential deposition of Sm(III) at the Al, Ga, and Al-Ga active cathode was performed to confirm the formation of Sm-based intermetallic compounds. The X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) analyses indicated that Ga₃Sm and Ga₆Sm intermetallic compounds were formed on the Mo grid electrode (inert) during the potentiostatic electrolysis in LiCl-KCl-SmCl₃-AlCl₃-GaCl₃ melt, while only Ga₆Sm intermetallic compound was generated on the Al-Ga alloy electrode during the galvanostatic electrolysis in LiCl-KCl-SmCl₃ melt. The electrolysis results revealed that the interaction between Sm and Ga was predominant in the Al-Ga alloy electrode, with Al only acting as an additive to lower the melting point.

• Journal of Environmental Science International
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• v.6 no.1
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• pp.1-8
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• 1997

Varing the flow velocity of solution and particle diameter, the mass transfer coefficient of the local electrode on current feeder has been measured in an empty flow reactor, an inert fluidized bed electrode reactor, and an active fluidized bed electrode reactor. It had its maximium value when the bed porosity was 0.6 to 0.65 and decreased with in- creasing the height of local electrode. The mass transfer coefficient was found to be high especially when higher particle was fluidized. Electrochemical deposition of copper dissolved in the synthesized wastewater has been performed in the active fluidized bed electrode reactor. The deduction rate was higher than 90% and the residual concentration of copper decreased to less than 5ppm.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.14 no.2
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• pp.38-43
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• 2015

Tungsten inert gas (TIG) welding is commonly used in industries that require airtightness, watertightness, oiltightness, and precision. It is a non-consumable welding method that is commonly used for the welding of non-ferrous metals, but it can be used to weld most metals. The methods of TIG welding can be divided into three types. The first, manual welding is done directly on the metal by a welder with a torch. The second, semi-automatic welding, gets help from a material supplying machine, but it is conducted by a welder. Lastly, automated welding is conducted fully by a machine during its process and operation. Depending on the selection of electrode, the amount of heat that is applied to the base material and the electrode rod changes and makes the shape of welded parts different. A direct-current positive electrode was used for this study. Through the change of shielding gas type on a structural steel (SS-400) that is commonly used in industry, the composition and shape changes in welded parts were detected after welding. The heat-affected area, hardness value, and tensile strength were also identified through hardness testing and tensile testing. In this study, it was found that the higher hardness value of the heat-affected is, the weaker the tensile strength becomes.

• Journal of Welding and Joining
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• v.21 no.2
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• pp.57-63
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• 2003

Since new types of vehicles or structures made from thin aluminum alloy are under rapid development and some products are already on the market, welding of aluminium sheet is increasing. MIG(Metal Inert Gas), MIG-Pulse, TIG(Tungsten Inert Gas) welding are the typical Ai welding. MIG welding has the advantage of high speed, but it is difficult to apply to the thin plate, because of bum-through by the high heat input and spatter. MIG-Pulse welding can weld without spatter and burn-through, but when the gap exists at the welding joint, there is quite a possibility of bum-through. TIG welding is difficult to weld at a high speed. AC Pulse welding alternates between DCEP(Direct Current Electrode Positive) and DCEN(Direct Current Electrode Negative). DCEN is higher wire melting rate than DCEP, while lower temperature of droplet than DCEP. In AC Pulse welding, far fixed welding current, wire melting rate increases as the EN ratio increases. For fixed wire feed rate, welding current decreases as the EN ratio increases. Because of these features, the temperature of droplet, the depth of penetration, the width of bead decrease and the reinforcement height increases as EN ratio increases, and these are able to weld at a high speed, lower heat input. It is the purpose of this study that design of AC pulse current waveform for MIG welding of Al sheet and estimation of output characteristic.

• Journal of Advanced Marine Engineering and Technology
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• v.18 no.3
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• pp.68-77
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• 1994

TIG welding process is applied for the active metal such as aluminum and titanium, also sometimes for overlay welding of superalloy. However the welding speed to be applied is very low because of the unstable bead formed in the region of high current and high welding speed. The present study was carried out to examine the basic phenomena of high speed TIG melt run welding by the 2% Th - W electrode(dia.3.2mm) of various tip shapes.