• Title/Summary/Keyword: Industrial Byproduct

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Strength Characteristic according to the Water Curing Temperature of the Inorganic Binder Mixed PVA Fiber (PVA섬유혼입 무기결합재의 수중양생온도에 따른 강도특성)

  • Lee, Jin-Woo;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.194-195
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    • 2013
  • Recently, it is the tendency that the CO2 gas generated in the manufacturing process is increased every year in case of the portland cement used in the most of constructions and civil engineering field. The method that uses the mineral admixtures as the cement substitute material in order to be more serious and as much as it occupies 7% of the global CO2 gas outlet amount such as 1 ton produces the cement and it ejects the CO2 gas of 0.4~1.0 ton, etc conclude this problem is examined. Therefore, PVA fiber was mixed into the inorganic binder recycling the blast furnace slag, which is the industrial byproduct with the purpose studying the Geo polymer which doesn't use the cement at all silica fume, red mud, and etc. In addition, the water curing temperature was differentiated and the strength characteristic of the curing body tried to be examined.

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Optimized Mixing Design of Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar by Response Surface Analysis (반응표면분석법에 의한 탄소포집 활성 고로슬래그 모르타르의 최적배합 도출에 관한 연구)

  • Jang, Bong Jin;Park, Cheol woo;Kim, Seung Won;Ju, Min Kwan;Park, Ki Tae;Lee, Sang Yoon
    • International Journal of Highway Engineering
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    • v.15 no.6
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    • pp.69-78
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    • 2013
  • PURPOSES : In this study blast furnace slag, an industrial byproduct, was used with an activating chemicals, $Ca(OH)_2$ and $Na_2SiO_3$ for carbon capture and sequestration as well as strength development. METHODS : This paper presents the optimized mixing design of Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar. Design of experiments in order to the optimized mixing design was applied and commercial program (MINITAB) was used. Statistical analysis was used to Box-Behnken (B-B) method in response surface analysis. RESULTS : The influencing factors of experimental are water ratio, Chemical admixture ratio and Curing temperature. In the results of response surface analysis, to obtain goal performance, the optimized mixing design for Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar were water ratio 40%, Chemical admixture ratio 58.78% and Curing temperature of $60^{\circ}C$. CONCLUSIONS : Compared with previous studies of this experiment is to some extent the optimal combination is expected to be reliable.

Mixotrophic Cultivation of Marine Alga Tetraselmis sp. Using Glycerol and Its Effects on the Characteristics of Produced Biodiesel

  • Dang, Nhat Minh;Kim, Garam;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.222-228
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    • 2022
  • As a possible feedstock for biodiesel, the marine green alga Tetraselmis sp. was cultivated under different conditions of phototrophic, mixotrophic and heterotrophic cultures. Glycerol, a byproduct from biodiesel production process, was used as the carbon source of mixotrophic and heterotrophic culture. The effects of glycerol supply and nitrate-repletion were compared for different trophic conditions. Mixotrophic cultivation exhibited higher biomass productivity than that of phototrophic and heterotrophic cultivation. Maximum lipid productivity of 55.5 mg L-1 d-1 was obtained in the mixotrophic culture with 5 g L-1 of glycerol and 8.8 mM of nitrate due to the enhancement of both biomass and lipid accumulation. The major fatty acid methyl esters (FAME) in the produced biodiesel were palmitic acid (C16:0), oleic acid (C18:1), linoleic acid (C18:2), and linolenic acid (C18:3). The degree of unsaturation was affected by different culture conditions. The biodiesel properties predicted by correlation equations based on the FAME profiles mostly complied with the specifications from the US, Europe and Korea, with the exception of the cold-filter plugging point (CFPP) criterion of Korea.

Application Evaluation of Physical and Strength Properties of Paperboard by Kraft Pulp Mixing Made from Agricultural Byproducts (농업부산물 크라프트펄프의 혼합에 따른 판지의 물성변화)

  • Lee, Ji-Young;Lim, Gi-Baek;Kim, Sun-Young;Park, Jong-Hye;Kim, Eun-Hea;Sung, Yong Joo;Heo, Young-Jun;Kim, Young-Hun;Kim, Youn-Ho;Lee, Se-Ran
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.43-50
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    • 2014
  • The cultivation of agricultural crops results in the generation of agricultural byproducts. Researchers have reported that these materials can be useful in a variety of applications. However, over 50% of them are currently discarded because of the lack of specific technologies in industrial applications. Therefore, effective and specific applications must be developed in order to manufacture high-quality materials using discarded lignocellulosic resources. In this study, we determined the possibility of using kraft pulp from major agricultural byproducts as a raw material for the manufacture of paperboard. Rice husks, peanut husks, and garlic stems were obtained and used to prepare many kinds of kraft pulps by controlling the active alkali, sulfidity, reaction time, and liquor ratio. After the production of these kraft pulps, handsheets were manufactured by mixing them with KOCC. After preconditioning, the physical properties and strengths of the handsheets were measured according to the TAPPI test methods. The shapes, lengths, and widths of the pulp fibers varied according to the type of agricultural byproduct and the kraft pulping conditions. Rice husk and garlic stem pulps manufactured under mild pulping conditions resulted in handsheets of higher bulk than other pulps. Garlic stem pulps manufactured under mild pulping conditions were stronger than rice husk pulps and peanut husk pulps.

Study on the Development of Accelerator for Early Strength of Concrete using Industrial by-product (산업부산물을 활용한 조기강도 촉진제 기술 개발을 위한 연구)

  • Lee, Ji-Hwan;Lee, Jin-Woo;Lee, Jae-Sam;Lee, Kang-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.1-10
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    • 2013
  • In this study utilize industry product for OPC(ordinary portland cement) and BFS(blast furnace slag) mixing concrete early age compressive strength elevation and executed study for high strength binder. Association ratio of industry product for high strength binder manufacture is Titanogypsum (4) : Limestone (3) : Waterworks Sludge by ratio of (3) as it is proper move. high strength binder mixing rate appeared that (7~9) % are proper via preliminary test. Could confirm that display high compressive strength incidence rate in early age than plain harmony according as mix high strength binder mixing concrete compressive strength high strength binder. Also, high strength binder generality that give function than high strength binder used in existing displayed more excellent intensity, and compressive strength displayed result that multiply single breadth according as high strength binder substitute that give function increases.

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A Study on the Improvement of the Legal System Related to Electro-Optical Oxidation Slag

  • Kim, Hyeok-Jung;Lee, Young-Woo;Park, Se-Hun
    • Journal of the Korea Society of Computer and Information
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    • v.25 no.12
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    • pp.299-303
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    • 2020
  • Currently, electric furnace oxide slag is mostly used for soil or road use due to its nature. Although electric furnace oxidation slag is an industrial byproduct, not a circulating aggregate, the shortcomings of electric furnace oxidation slag are gradually being resolved due to the development of technology, and it is said that electric furnace oxidation slag is enough to be used as aggregates in light of research and technology conditions outside of Korea. However, there are difficulties in expanding construction and application, given that the current standard for electric furnace oxid slag only defines recycling purposes and does not have specific regulations. Therefore, institutional supplementation is needed to utilize oxidation slag as electricity. In this study, the laws and system related to oxidation slag by electricity are reviewed, laws related to recycled aggregate are examined, and measures for improvement are proposed.

Removal of Styrene Using Different Types of Non-Thermal Plasma Reactors (저온플라즈마 반응기의 형태에 따른 스타이렌 분해 특성에 관한 연구)

  • Park, Jeong-Uk;Choi, Kum-Chan;Kim, Hyun-Ha;Ogata, Atsushi;Futamura, Shigeru
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.2
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    • pp.215-223
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    • 2005
  • Non-thermal plasma decomposition of gas-phase styrene was investigated in this study using three different types of plasma reactors; dielectric-barrier discharge (DBD) reactor, surface discharge (SD) reactor and plasma-driven catalyst (PDC) reactor packed with 2.0 wt% $Ag/TiO_2$ catalysts. The main parameters used for the comparative assessment of the plasma reactors include the decomposition efficiency, carbon balance, byproduct distribution, COx ($CO+CO_2$) selectivity and COx yield. The SD and the DBD reactors showed better conversion efficiency of styrene than that of the PDC reactor due to their larger capability in ozone formation. On the other hand, the PDC reactor showed better carbon balance, the yield and the selectivity of COx. The required specific input energies to achieve 100% carbon balance from the decomposition of 100 ppmv styrene using the plasma alone reactors and the PDC reactor were 420 J/L and 110 J/L, respectively. The major decomposition products in gas-phase were CO, $CO_2$ and HCOOH regardless of the types of plasma reactors. In the case of SD and DBD reactors, the $CO_2$ selectivity ranged in $39.5{\sim}60%$. The $CO_2$ selectivity in the PDC reactor was in range of $68.5{\sim}75.5%$.

Mechanical Properties of Concrete using Alpha-Calcium Sulfate Hemihydrate (알파형 반수석고를 활용한 콘크리트의 역학적 특성)

  • Shin, Kyoung-Su;Kim, Gyu-Yong;Sung, Gil-Mo;Woo, Sang-Kyun;Lim, Byung-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.72-79
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    • 2019
  • Concrete is vulnerable to cracks due to volume changes caused by temperature changes, shrinkage during curing, external forces, or poor construction. In particular, concrete placed in electric power tunnel structures can generate cracks by a variety of factors. As a result, these tunnel structures require continuous maintenance. In this study, we investigated the mechanical properties of electric power tunnel concrete using alpha-calcium sulfate hemihydrate, which is an industrial byproduct that has excellent expansion performance. To compensate for the decrease in compressive strength when substituting alpha-calcium sulfate hemihydrate, based on previous research, we added 9% alpha-calcium sulfate hemihydrate and adjusted the amount of admixture while using the same amount of cement. We then evaluated the mechanical properties of the concrete. The results showed that the compressive strength of the concrete was higher than that of ordinary Portland cement (OPC), and the shrinkage of concrete was reduced by more than 30% compared to that of OPC. Therefore, adding 9% of alpha-calcium sulfate hemihydrate is expected to have a significant effect in reducing concrete cracks.

Engineering Performance of a Rapid Hardening Hydraulic Binder with Hybrid Fiber

  • Li, Mao;Kim, Jin-Man;Choi, Sun-Mi
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.3
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    • pp.279-288
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    • 2016
  • The fundamental performance of any construction material should cover at least two phases: safety and serviceability. Safety commonly represents adequate strength, while serviceability encompasses the control of cracking and deflections at service loads. With respect to rapid hydraulic binders as a construction material, the above two phases should also be considered. Recent research on rapid cooling ladle furnace slag (RC-LFS) has drawn much attention, particularly given that it shows remarkable rapid hydraulic ability to pulverize to a fineness of $6,300cm^2/g$. This industrial byproduct could contribute to developing the sustainability of the rapidly hardening cementitious material system. This paper aims to expand upon the applicability of an RC-LFS-based binder that is composed of two parts. It also seeks to illustrate the engineering performance of an RC-LFS-based hybrid fiber-reinforced composite and to increase the strength of the RC-LFS-based composite. Each step of this experiment followed ASTM standards. The engineering performance, in both fresh state and hardening state, was tested and discussed in this paper. According to the experimental results for fresh concrete, the air content increased following the addition of polypropylene fiber. For hardened concrete, the toughness and strength improved following the addition of a hybrid fiber. The hybrid fiber mixture, which contains 0.75% of steel fiber and 0.25% of polypropylene fiber, shows even better engineering performance than other mixtures.

Recovery of Acetic Acid from An Ethanol Fermentation Broth by Liquid-Liquid Extraction (LLE) Using Various Solvents

  • Pham, Thi Thu Huong;Kim, Tae Hyun;Um, Byung-Hwan
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.695-702
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    • 2015
  • Liquid-liquid extraction (LLE) using various solvents was studied for recovery of acetic acid from a synthetic ethanol fermentation broth. The microbial fermentation of sugars presented in hydrolyzate gives rise to acetic acid as a byproduct. In order to obtain pure ethanol for use as a biofuel, fermentation broth should be subjected to acetic acid removal step and the recovered acetic acid can be put to industrial use. Herein, batch LLE experiments were carried out at $25^{\circ}C$ using a synthetic fermentation broth comprising $20.0g\;l^{-1}$ acetic acid and $5.0g\;l^{-1}$ ethanol. Ethyl acetate (EtOAc), tri-n-octylphosphine oxide (TOPO), tri-n-octylamine (TOA), and tri-n-alkylphosphine oxide (TAPO) were utilized as solvents, and the extraction potential of each solvent was evaluated by varying the organic phase-to-aqueous phase ratios as 0.2, 0.5, 1.0, 2.0, and 4.0. The highest acetic acid extraction yield was achieved with TAPO; however, the lowest ethanol-to-acetic acid extraction ratio was obtained using TOPO. In a single-stage batch extraction, 97.0 % and 92.4 % of acetic acid could be extracted using TAPO and TOPO when the ratio of organic-to-aqueous phases is 4:1 respectively. A higher solvent-to-feed ratio resulted in an increase in the ethanol-to-acetic acid ratio, which decreased both acetic acid purity and acetic acid extraction yield.