• 제목/요약/키워드: Indoor and outdoor concentrations

검색결과 183건 처리시간 0.027초

DNPH 카트리지와 HPLC를 이용한 대기 중 카르보닐화합물의 농도측정 (Measurement of Carbonyl Compounds in Ambient Air using a DNPH Cartridge coupled with HPLC Method)

  • 황윤정;박상곤;백성옥
    • 한국대기환경학회지
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    • 제12권2호
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    • pp.199-209
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    • 1996
  • The purpose of this study is to evaluate analytical method for the measurement of carbonyl compounds and to apply method to the measurement of indoor and outdoor concentrations of these compounds at public facilities. For sampling, 2.4-dinitrophenylhydrazine (DNPH) coated DNPH-Silica cartridges were uwed in this study. DNPH reacts with carbonyl compounds and forms carbonyl hydrazone, The carbonyl hydarzone was eluted from the cartridge with acetonitrile and analyzed by reverse-phase HPLC with UV detection. Possible interference caused by ozone during sampling was eliminated by using KI trap commected in series with the DNPH-Silica cartridge. A number of experimental studies were undertaken to evaluate and validate the analytical method, including collection efficiency, recovery, repeatability, lower limits of detection, and effect of ozone. Indoor and outdoor measurements of carbonyl compounds were simultaneously carried out at 14 public facilities located in Taegu city and Kyungsan city from June to July, 1995. Except for one or two sites, the indoor concentrations were found to be higher than the outdoor concentrations for carbonyl compounds. And the concentrations of carbonyl compounds measured in the morning and afternoon were showed higher than the concentrations measured in the evening.

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Estimation of NO$_2$ Source Generation and Ventilation rate in Residence by Multiple Measurements

  • Won Ho, Yang;Gi Yeong, Lee
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 봄 학술발표회 발표논문집
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    • pp.155-160
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    • 2003
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Although technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Daily indoor and outdoor $NO_2$ concentrations were measured for 30 consecutive days in 28 houses in Brisbane, Australia, and for 21 consecutive days in 37 houses in Seoul, Korea. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and $NO_2$ source strength were estimated. Geometric means of ventilation rate were 1.44 ACH in Brisbane, assuming a residential $NO_2$ deposition constant of 1.05 $hr^{-1}$, and 1.36 ACH in Seoul, with the measured residential $NO_2$ deposition constant of 0.94 $hr^{-1}$. Source strengths of $NO_2$ were 15.8 $\pm$ 18.2 ${\mu}g$/$m^3$.hr and 44.7 $\pm$ 38.1${\mu}g$/$m^3$.hr in Brisbane and Seoul, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

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Estimation of Nitrogen Dioxide Source Generation and Ventilation Rate in Residence Using Multiple Measurements in Korea

  • Chung, Moon-Ho;Yang, Won-Ho
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2004년도 International Conference Current Challenges and Advances in Environmental Health
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    • pp.45-50
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    • 2004
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Alt hough technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Daily indoor and outdoor NO2 concentrations were measured for 30 consecutive days in 28 houses in Brisbane, Australia, and for 21 consecutive days in 37 houses in Seoul, Korea. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and NO2 source strength were estimated. Geometric means of ventilation rate were 1.44 ACH in Brisbane, assuming a residential NO2 deposition constant of 1.05 hr-1, and 1.36 ACH in Seoul, with the measured residential NO2 deposition constant of 0.94 hr-1. Source strengths of N02 were 15.8 ${\pm}$ 18.2 ${\mu}$g/m3${\cdot}$hr and 44.7 ${\pm}$ 38.1 ${\mu}$g/m3${\cdot}$hr in Brisbane and Seoul, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

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공단지역내 이산화질소농도에 관한 연구 (A Study of Nitrogen Dioxide Concentration in Industrial Areas)

  • 손부순;김우재;김윤신
    • 환경위생공학
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    • 제16권3호
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    • pp.42-53
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    • 2001
  • This study were conducted to estimate property of nitrogen dioxide concentration at industrial areas in Korea. The nitrogen dioxide concentrations were measured for 50 dwellings at Ulsan and Yeochon, respectively using the nitrogen dioxide filter badge forming the passive sampler from summer time 1998 to winter time 1999. The major results obtained from this study were as follows: 1. The mean indoor, outdoor, and personal concentrations of nitrogen dioxide during summer time 1998 in Ulsan were 28.9 ppb, 24.8 ppb, 24.8 pub, respectively. 2. The mean indoor, outdoor, and personal concentrations of nitrogen dioxide during winter time 1999 in Yeochon were 11.4 ppb, 12.5 ppb, 15.5 ppb, respectively. 3. The mean concentration of nitrogen dioxide during winter time 1998 were higher than the corresponding levels during summer time 1997 in Ulsan. 4. The mean concentration of nitrogen dioxide in Ulsan were in general higher than the corresponding levels in Yeochon. 5. This results in slightly positive correlation among indoor, outdoor, and personal nitrogen dioxide concentrations for summer time in Ulsan, then it statistical significance is showed(p <.05). These results suggest that nitrogen dioxide concentrations in industrial areas seem to be affected by traffic density and conditions of industrialization.

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여름철 가정집에서의 산성오염물질에 대한 실내 공기질 특성 (Characteristics of Indoor Air Quality of Acidic Air Pollutants in a Private Home During Home During the Summer Season)

  • 이학성;강병욱;강충민;여현구
    • 한국대기환경학회지
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    • 제17권2호
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    • pp.193-201
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    • 2001
  • Acidic air pollutants were collected to characterize indoor air quality in a residential area in the summer. All indoor and outdoor samples were measured simultaneously using an annular denuder system(ADS) in Seoul. The data set was collected from July 26 to September 11, 1997. The mean indoor/outdoor ratios measured from this study were : 0.34 for $HNO_3$; 0.91 for $HNO_2$; 0.22 for $SO_2$; 1.34 for $NH_3$; 0.78 for $PM_{2.5}(d_p$ <2.5 $mutextrm{m}$); 0.90 for $SO_{4}^{2-}$; 0.68 for $NO_{3}^{-}$ and 0.79 for $NH_{4}^{+}$. Indoor concentrations of $HNO_3$, $SO_2$ and $PM_{2.5}$ were highly correlated with the outdoor concentrations. The relationship between indoor and outdoor air is dependent, to a large extent, on the rate of air exchange between these two environments. A tracer-gas decay technique with sulfur hexafluoride ($SF_{6}$) as a tracer gas was used to estimate the air exchange of a private home in the summer. The average air exchange rate was estimated to be 23.7 hr(sup)-1. The deposition velocities for $SO_{4}^{2-}$, $NO_{3}^{-}$ and $NH_{4}^{+}$ calculated were 0.17, 0.69 abd 0.39 cm/sec, respectively.

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실내 및 실외 공기중 이산화질소의 개인 노출량 측정을 위한 수동식 시료채취기의 성능평가 (Evaluation of Passive Monitor for the Measuring of Personal Exposure to Nitrogen Dioxide in Indoor and Outdoor Air)

  • 양원호;이기영;백도명
    • 한국대기환경학회지
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    • 제16권6호
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    • pp.625-631
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    • 2000
  • Practical devices for measuring personal exposure to nitrogen dioxide(NO$_2$) have been made for epidemiological studies of the health effects of air pollution Standard methods for NO$_2$ measurement such as the chemiluminescent method and Saltzman method are not suitable for personal exposure because they are heavy, large and complicated to operate. In this study, a passive monitor was tested for the measurements of indoor and outdoor NO$_2$ level. Through a comparative analysis of data sets obtained by on-site chemiluminescence system, we assessed the accuracy and precision of NO$_2$ passive monitors. We also examined the possibility of passive monitor in the study of indoor, outdoor and personal NO$_2$ exposure. The accuracy and precision of NO$_2$ passive monitor were analyzed assuming measurements of on-site chemiluminescence system is reference value and using duplicated measure- ments, respectively. From these analysis the NO$_2$ passive monitor was useful for measuring indoor, outdoor and personal exposure. And NO$_2$ level from on-site chemiluminescence systems could not properly represent the personal NO$_2$ exposure as well as indoor and outdoor level of ones house. Personal exposures were correlated more strongly with indoor NO$_2$ concentrations than with outdoor NO$_2$ concentrations. Since activity pattern of each person is different, it was considered that personal daily behavior and life-style might prevent the air pollutant exposure.

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휘발유 및 환경 담배 연기 관련 벤젠 노출 (Exposure to Benzene Associated with Gasoline and Environmental Tobacco Smoke)

  • 조완근;문경조
    • 한국환경과학회지
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    • 제8권3호
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    • pp.319-323
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    • 1999
  • This study was designed to evaluate the exposure to benzene by residents in neighborhoods near a major roadways, by persons waiting buses, and by drivers and service station attendants while refueling. It was confirmed that the outdoor air benzene concentrations near the major roadways were higher than those further away from the sources. However, neither the indoor air nor breath concentrations were different for two specified residential areas. Smoking was confirmed as an important factor for the indoor air benzene levels. Persons waiting buses, drivers and service station attendants were exposed to elevated benzene levels compared to even the residents in neighborhoods near a major roadways. The mean benzene concentration at bus stop was 2.7 to 6.9 times higher than the mean ambient air concentration. The mean benzene concentrations in the breathing zone of drivers and service station attendants were 95 to 160 and 120 to 202 times higher than the mean ambient air concentrations, respectively.

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자동차 선적작업장의 공기오염 실태조사 (Investigation into Air Pollution in Car Shipping Workshop in Pyeongtaek Port)

  • 김지호;원종욱;김치년;노재훈
    • 한국산업보건학회지
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    • 제16권1호
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    • pp.44-53
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    • 2006
  • This study purposed to investigate air pollution in car shipping yards and, for this purpose, we selected an outdoor open-air yard and an indoor ramp into the ship and measured the concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10, PM2.5 and heavy metals in the air. The results of this study are as follows. No significant difference was observed in temperature and humidity between the outdoor and indoor workshop, and the average air flow was 0.52 m/s in the indoor workshop, which is higher than 0.19 m/s in the outdoor workshop(p<0.01). The average concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10 and PM2.5 according to workplace were 0.03 ppm(${\pm}0.01$), 0.03 ppm(${\pm}0.01$), 0.46 ppm(${\pm}0.22$), $39.44{\mu}g/m^3$(${\pm}2.45$) and $5.45{\mu}g/m^3$(${\pm}1.15$) respectively in the outdoor workshop, and 0.15 ppm(${\pm}0.05$), 0.22 ppm(${\pm}0.06$), 8.85 ppm(${\pm}3.35$), $236.39{\mu}g/m^3$(${\pm}58.21$) and $152.43{\mu}g/m^3$(${\pm}35.42$) respectively in the indoor workshop. Thus, the concentrations of gaseous substances in the indoor workshop were 4.9-19.2 times higher than those in the outdoor workshop, and the concentrations of fine dusts were 5.9-27.9 times higher(p<0.01). In addition, according to the result of investigating pollutant concentrations according to displacement and the number of car loaded when shipping gasoline cars into the ship, no significant relation between the number of cars loaded and pollutants was observed in shipping passenger cars, but the concentrations of nitrogen dioxide and carbon monoxide got somewhat higher with the increase of the number of cars loaded(p<0.05). In addition, the concentrations of nitrogen dioxide, carbon monoxide, PM10 and PM2.5 in the air were significantly higher when shipping recreational vehicles, the displacement of which is larger than passenger cars, than when shipping passenger cars(p<0.01). On the other hand, the average heavy metal concentrations of the air in indoor workshop were: lead $-0.05{\mu}g/m^3$(${\pm}0.10$); chromium $-0.90{\mu}g/m^3$(${\pm}0.18$); zinc $-0.38{\mu}g/m^3$(${\pm}0.24$); copper $-0.18{\mu}g/m^3$(${\pm}0.22$); and manganese and cadmium not detected. In addition, the complaining rates of 'asthma,' a major symptom of chronic respiratory diseases, were 18.5% and 22.5% respectively in indoor workers and outdoor workers. Thus the rate was somewhat higher in indoor workers but the difference was not statistically significant. The complaining rates of 'chronic cough' and 'chronic phlegm' were very low and little different between indoor and outdoor workers. The results of this study show that the reason for the higher air pollution in indoor than in outdoor workshop is incomplete combustion of fuel due to sudden start and over-speed when cars are driven inside the ship. In order to prevent high air pollution, efficient management measures should be taken including the observance of the optimal speed, the improvement of old ships and the installation of efficient ventilation system.

유아교육시설의 위치 및 실내${\cdot}$실외에 따른 포름알데히드 농도 변화 (Variation of Formaldehyde Concentration in Preschool Facilities by Location and Indoor/Outdoor)

  • 윤충식;정지연;이광용;박동욱;박두용
    • 한국환경보건학회지
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    • 제30권3호
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    • pp.259-263
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    • 2004
  • This study was performed to investigate airborne formaldehyde concentration in preschool facilities. Arithmetic mean of indoor formaldehyde concentration in urban area was 34.9 ppb(Geometric mean 24.4 ppb) whereas outdoor concentration was 21.5 ppb(GM 11.9 ppb). In rural area, formaldehyde concentrations were 36.4 ppb(GM 28.7 ppb), 4.1 ppb(GM 4.1 ppb), respectively. There is no statistical significance between the formaldehyde concentrations of urban classrooms and those of rural area. We verified that the distribution of airborne formaldehyde concentration was log-normal characteristic using Shapiro and Wilk test. The 6.7% of urban indoor samples was exceeded the domestic standard limit of indoor air quality. From our study and other study, we concluded that the major emission sources of formaldehyde in preschool facilities was in indoor rather than outdoor.

1980년대 초 서울의 실내외 대기질 수준 - Sherwood 교수의 측정 자료 활용 (Historical Data on Indoor and Outdoor Air Quality in Seoul, Korea)

  • 이기영
    • 한국환경보건학회지
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    • 제39권1호
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    • pp.99-103
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    • 2013
  • Objectives: This paper was prepared in memory of Jerry Sherwood, who provided a significant contribution to the Korean environmental and occupational health fields. Methods: Rare air quality data in Seoul were gathered by Jerry Sherwood when he visited Korea in the early 1980s. $SO_2$ and TPM concentrations were measured. These air quality measurements were based on ambient stationary monitoring and indoor air quality monitoring in various locations. Measurement during transportation was also applied. Results: Ambient $SO_2$ and TPM concentrations in Seoul were very high in the early 1980s. Ambient $SO_2$ concentrations were higher at nighttime. While ambient $SO_2$ concentrations varied by location, the Guro industrial area showed high levels. When indoor sources were presented, indoor $SO_2$ concentration was higher than outdoor level. Coal briquettes were closely associated with high indoor $SO_2$ concentration. Conclusion: This paper provided valuable historical information of air quality in Seoul.