• 제목/요약/키워드: Increasing temperature regime

검색결과 63건 처리시간 0.023초

Viscosity and Diffusion Constants Calculation of n-Alkanes by Molecular Dynamics Simulations

  • Lee, Song-Hi;Chang, Tai-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제24권11호
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    • pp.1590-1598
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    • 2003
  • In this paper we have presented the results for viscosity and self-diffusion constants of model systems for four liquid n-alkanes ($C_{12}, C_{20}, C_{32}, and C_{44}$) in a canonical ensemble at several temperatures using molecular dynamics (MD) simulations. The small chains of these n-alkanes are clearly $<{R_{ee}}^2>/6<{R_g}^2>>1$, which leads to the conclusion that the liquid n-alkanes over the whole temperatures considered are far away from the Rouse regime. Calculated viscosity ${\eta}$ and self-diffusion constants D are comparable with experimental results and the temperature dependence of both ${\eta}$ and D is suitably described by the Arrhenius plot. The behavior of both activation energies, $E_{\eta}$ and $E_D$, with increasing chain length indicates that the activation energies approach asymptotic values as n increases to the higher value, which is experimentally observed. Two calculated monomeric friction constants ${\zeta}$ and ${\zeta}_D$ give a correct qualitative trend: decrease with increasing temperature and increase with increasing chain length n. Comparison of the time auto-correlation functions of the end-to-end vector calculated from the Rouse model for n-dodecane ($C_{12}$) at 273 K and for n-tetratetracontane ($C_{44}$) at 473 K with those extracted directly from our MD simulations confirms that the short chain n-alkanes considered in this study are far away from the Rouse regime.

우리나라 주변 해양생태계의 장기 변동 (Long Term Changes Pattern in Marine Ecosystem of Korean Waters)

  • ;이충일
    • 해양환경안전학회지
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    • 제18권3호
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    • pp.193-198
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    • 2012
  • 겨울철 해표면 수온 및 한국 주변역 생태계의 장기 변화 특성 및 상관관계를 분석하였다. 기후 및 해양환경의 변화와 동반된 어획강도의 변화는 1970 년대 이후 어획량 증가의 주요 원인으로 나타났다. 한국 주변역의 겨울철 SST는 1980년대 후반 기후체제변환 시점을 중심으로 상대적으로 저수온에서 고수온으로 변화되었다. 평균영양단계(MTL)는 1970년대 중반 이후 지속적으로 감소하기 시작하였으며, 하위영양단계 어류의 어획량 증가가 중요 변수로 작용하였다. 통합생태계 기반 자원평가 방법중 한가지인 FIB 지수는 1970년 초부터 1970년 후반까지 증가하였으며, 이후 일정 수준을 유지하였다. 특히, 중간영양단계에 위치하는 멸치와 정어리의 개체수 변화는 1970년대 초 이후 MTL 변화의 주요 인자로 작용하였다.

A Study on Oxidation Behaviors of IG and NBG Nuclear Graphites

  • 최웅기;김병주;지세환;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.217-217
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    • 2009
  • In this work, the oxidation-induced characteristics of five nuclear graphites (NBG-17, NBG-18, NBG-25, IG-110, and IG-430) were studied. The oxidation characteristics of nuclear graphites were measured at the three temperature areas (300, 600, and $900^{\circ}C$). As experimental results, the pore size of oxidized graphite was increased with increasing of oxidation time. It was also found that the oxdation rate was propotional to the oxidation temperature and time. This was probably due to the oxidation was occurred on the surface and inner bulk phase of nuclear graphites at the same time by the socalled chemical regime.

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Convective heat transfer of MWCNT / HT-B Oil nanofluid inside micro-fin helical tubes under uniform wall temperature condition

  • Kazemia, M.H.;Akhavan-Behabadi, M.A.;Nasr, M.
    • Advances in nano research
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    • 제2권2호
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    • pp.99-109
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    • 2014
  • Experiments are performed to investigate the single-phase flow heat transfer augmentation of MWCNT/HT-B Oil in both smooth and micro-fin helical tubes with constant wall temperature. The tests in laminar regime were carried out in helical tubes with three curvature ratios of 2R/d=22.1, 26.3 and 30.4. Flow Reynolds number varied from 170 to 1800 resulting in laminar flow regime. The effect of some parameters such as the nanoparticles concentration, the dimensionless curvature radius (2R/d) and the Reynolds number on heat transfer was investigated for the laminar flow regime. The weight fraction of nanoparticles in base fluid was less than 0.4%. Within the applied range of Reynolds number, results indicated that for smooth helical tube the addition of nanoparticles to the base fluid enhanced heat transfer remarkably. However, compared to the smooth helical tube, the average heat transfer augmentation ratio for finned tube was small and about 17%. Also, by increasing the weight fraction of nanoparticles in micro-fin helical tubes, no substantial changes were observed in the rate of heat transfer enhancement.

온도구배가 Taylor-Couette유동의 불안정성에 주는 영향에 관한 연구 (Study of Different Radial Temperature Gradient Effect on Taylor-Couette Flow Instability)

  • 차재은;류동;도흔승;김형범
    • 한국가시화정보학회지
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    • 제8권3호
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    • pp.35-40
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    • 2010
  • We have investigated different radial temperature gradient effect on the stability of Taylor-Couette flow. The radius ratio and aspect ratio of the model was 0.825 and 48, respectively. Two heating exchangers were used for generating different temperature gradient along the radial direction. The change of flow regime in the Taylor-Couette flow was studied by increasing the Reynolds number. The results showed that: as Gr is increased in helical vortex flow regime, the vortices with the same direction of convection flow increased in size, and the vortex moving velocity also increased. It is also shown that the presence of temperature gradient obviously increased the flow instability when the Richardson number is larger than 0.0045.

Effects of thermal boundary conditions and microgravity environments on physical vapor transport of $Hg_2Cl_2-Xe$ system

  • Kim, Geug-Tae;Kwon, Moo-Hyun;Lee, Kyong-Hwan
    • 한국결정성장학회지
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    • 제19권4호
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    • pp.172-183
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    • 2009
  • For the effects of the nonlinear temperature profiles and reduced-gravity conditions we conduct a two-dimensional numerical modeling and simulations on the physical vapor transport processes of $Hg_2Cl_2-Xe$ system in the horizontal orientation position. Our results reveal that: (1) A decrease in aspect ratio from 5 to 2 leads to an increasingly nonuniform interfacial distribution and enhances the growth rate by one-order magnitude for normal gravity and linear wall temperature conditions. (2) Increasing the molecular weight of component B, Xenon results in a reduction in the effect of solutal convection. (3) The effect of aspect ratio affects the interfacial growth rates significantly under normal gravity condition rather than under reduced gravitational environments. (4) The transition from the convection-dominated regime to the diffusion-dominated regime ranges arises near at 0.1g$_0$ for operation conditions under consideration in this study.

단상조직을 갖는 Cu-Zn합금의 고온강도에 미치는 변형속도와 온도의 영향 (Effects of Strain Rate and Temperature on the Hot Strength for Single Phase Cu-Zn Alloy)

  • 권용환;유연철
    • 소성∙가공
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    • 제4권2호
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    • pp.159-168
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    • 1995
  • The torsion tests in the range of $550~800^{\circ}C$, $5.0{\times}10^{-3}~5.0{\times}10^0/sec$ were performed to study the effects of strain rate$(\.{\varepsilon})$ and temperature(T) on the hot strength of Cu-Zn alloy. High temperature flow stresses of this alloy increased with increasing $\.{\varepsilon}$ and/or decreasing T, and than the more grain refinement could be obtained. The flow curves exhibited a peak followed by a steady steady state regime as a result of dynamic recrystallization. The hot strength dependence of $\.{\varepsilon}$ and T was described by a hyperbolic sine law, $\.{\varepsilon}=A(sinh0.017{\sigma})^4.81$exp(-216KJ/mol). Hot strength could be reduced at the arbitary condition, $\.{\varepsilon}$ and T, by constitutive parameter Z(Zenner-Hollomon parameter), $Z=A(sinh{\alpha}{\sigma})^n=\.{\varepsilon}$exp(Q/RT).

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몇가지 환경요인이 돼지풀의 종자발아에 미치는 영향 (Effects of Some Environmental Factors on the Germination of Seeds in Ambrosia artemisiifolia var. elatior)

  • 김종홍;김원희;차승희
    • The Korean Journal of Ecology
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    • 제25권2호
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    • pp.93-100
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    • 2002
  • 돼지풀(Ambrosia artemisiifolia var. elatior D/sub ESCOURTILS/)종자의 발아를 유발시키는 몇가지 환경요인의 영향을 조사한 결과는 다음과 같다. 종자의 휴면은 온도와 토양함수량이 적절하면 채종직후에도 일부분 타파되었고, 주야의 변온(30/20℃)이 휴면타파에 효과적이었다. 온도에 따른 발아율은 12℃∼32℃의 온도처리구에서 모두 발아가 이루어졌고, 발아에 필요한 최적온도는 24℃였다. (P<0.01). 토양함수량의 영향은 30% 처리구에서 증가하기 시작하여 60% 처리구에서 최대치를 나타내고 (P<0.05) 80% 처리구에서 다시 감소하는 경향을 나타내었으며, 토양함수량 7% 처리구에서는 전혀 발아가 이루어지지 않았다. 온도에 대한 광의 영향은 24℃의 온도 처리구에서 광처리시와 암처리시 가장 높은 발아율을 나타내었고, 광의 존재유무에 따른 발아율의 차이는 뚜렷하지 않았다. (P>0.05). 채종시기간에는 9개월 저장기간의 어떤 시기에도 종자의 발아에 특별한 영향을 나타내지 않았다. (P>0.05). 온도상승구(IT)에서 돼지풀종자는 16℃에서 발아하기 시작하였고 온도가 상승함에 따라 발아율이 점차 증가하여 최종발아율은 99.34%에 이르렀다. 반면에 온도하강구(DT)에서는 20℃에서 처음발아가 시작되었으며(1.34℃)에서 5.34%의 최종발아율을 나타내었고, 온도가 하강함에 따라 2차 휴면이 유도되었다. 저온에 의한 종자의 휴면타파가 고온에 의한 휴면타파보다 더 많이 유도되어, 돼지풀 종자는 늦가을에도 발아가 이루어지나 그 다음해 봄에 대부분의 종자발아가 이루어질 것으로 생각되어진다. 이와 같은 돼지풀종자들 내의 발아습성의 변이가 다양한 환경변화에 대해 자신의 생존과 자손의 번식을 위한 생리적·생태적 전략임을 알 수 있었다.

메탄올 액적 화염의 음향파 가진에 의한 재점화 (Reignition of Methanol Droplet Flames Under Acoustic Pressure Oscillation)

  • 김홍집;손채훈;정석호
    • 대한기계학회논문집B
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    • 제23권1호
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    • pp.114-122
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    • 1999
  • Reignition as special cases of acoustic pressure responses of flame are numerically studied by employing methanol droplet flame as a laminar flamelet. Quasi-steady flame responses occur in the range of small amplitude, low frequency oscillation. Reignition phenomena can occur when, by increasing the frequency of large amplitude acoustic pressure, the magnitude of characteristic acoustic time is the same order of that of characteristic reaction time of flames. And more increasing of amplitude of acoustic pressure induces the direct extinction of flame. Flame can sustain its own intensity even under the steady extinction temperature in case of high frequency acoustic oscillation, and this tendency is remarkable with increasing frequency. Reignition regime with respect to amplitude and frequency of acoustic pressure doesn't exist in low frequency($10^2$ Hz, in this study), but broadens with frequency of acoustic pressure.

온도 상승이 개량형 핵연료 피복관과 지지격자 사이의 프레팅 마멸에 미치는 영향 (Influence of Temperature on the Fretting Wear of Advanced Nuclear Fuel Cladding Tube against Supporting Grid)

  • 이영제;박용창;정성훈;김진선;김용환
    • Tribology and Lubricants
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    • 제22권3호
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    • pp.144-148
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    • 2006
  • The experimental investigation was performed to find the associated changes in characteristics of fretting wear with various water temperatures. The fretting wear tests were carried out using the zirconium alloy tubes and the grids with increasing the water temperature. The tube materials in water of $20^{\circ}C,\;50^{\circ}C\;and\;80^{\circ}C$ were tested with the applied load of 20 N and the relative amplitude of $200{\mu}m$. The worn surfaces were observed by SEM, EDX analysis and 2D surface profiler. As the water temperature increased, the wear volume was decreased, but oxide layer was increased on the worn surface. The abrasive wear mechanism was observed at water temperature of $20^{\circ}C$ and adhesive wear mechanism occurred at water temperature of $50^{\circ}C,\;80^{\circ}C$. As the water temperature increased, surface micro-hardness was decreased, but wear depth and wear width were decreased due to increasing stick phenomenon. Stick regime occurred due to the formation of oxide layer on the worn surface with increasing water temperatures