• Title/Summary/Keyword: In-water cleaning

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The Study on Optimum Operation Conditions of Ceramic MF Membrane Process in Y Water Treatment Plant (Y 정수장 세라믹막 여과공정 최적 운영인자 평가)

  • You, Sang-Jun;Ahn, Hyo-Won;Park, Sung-Han;Lim, Jae-Lim;Hong, Sung-Chul;Yi, Pyong-In
    • Membrane Journal
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    • v.24 no.3
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    • pp.201-212
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    • 2014
  • This study was performed to discover the optimum operation conditions for the advanced water treatment using the ceramic membrane, introduced the first in the nation at the Y water treatment plant (WTP). The result of investigation to find the optimum operation conditions which can continue preserving the filtration performance as well as satisfying both the economics and the water quality is as follows. In the ordinary water quality condition of the Y WTP, the optimum filtration time(the backwash period), which can minimize the production of backwash waste and preserve the membrane performance was examined to be 4.0 hours on basis of institution capacity ($16,000m^3/day$). Examining the recovery rate of TMP from the chemical cleaning (CIP) discovered that the inorganic contaminants, which cause membrane fouling, such as iron, manganese, aluminum, were removed through the acidic cleaning using citric acid, whereas the membrane recovery rate was found to be low. But, on the other hand, the TMP was recovered to the initial value from the alkali cleaning using the NaOCl. Therefore, the main contaminant causing the fouling was determined to be hydrophilic organic compound( biopolymer). The membrane recovery rate is highly influenced by the temperature of the cleaning chemical. That is, the rate increased with increasing temperature.

Evaluation of Washing Method for Sterilization of Gel Container for Ultrasound Inspection (초음파검사용 젤 용기의 제균을 위한 세척방법 평가)

  • Lee, Hee-Jeong;Lee, Suk-Jun;Seoung, Youl-Hun
    • Journal of radiological science and technology
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    • v.41 no.3
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    • pp.241-247
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    • 2018
  • The purpose of this study was to compare the ultrasound gel container washing methods for the sterilization of contaminants and to find the useful methods for the prevention of infection caused by the ultrasonic gel containers. In this experiment, a 250 mL ultrasonic gel container was used, and the ultrasonic gel used was a non-sterile gel (ECO GEL 99, SeungWon Medical, Korea). In order to evaluate the degree of contamination, new 250 mL 15 containers were divided into 5 groups to perform five types of washing by no treatment, washing with water, washing with soap, washing with bottle cleaner and high disinfection level washing. After the washing process, filled the gel container with gel and after 2 weeks, the number of colonies in the gel container was sampled repeatedly twice in the same ultrasonic laboratory and compared before and after washing. As a result of among the five cleaning methods used in this study, 87.2% and 88.9% of the soapy water washing (p = 0.028) and high level washing (p = 0.027) showed significant bacterial reduction rates, respectively. Our findings conclusively an ultrasonic gel container cleaning method for removing contaminants has been found to be an effective sterilization method at a low cost with a soapy water cleaning method. Therefore, it is expected that it will be helpful to prevent the infection caused by the ultrasonic gel container by suggesting the sterilization cleaning method that is practically useful in this study.

A Study on environmental-friendly Cleaning for Si-wafers (환경친화적인 실리콘 웨이퍼 세정 연구)

  • Yoon, Hyoseob;Ryoo, Kunkul
    • Clean Technology
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    • v.6 no.1
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    • pp.79-84
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    • 2000
  • In this study, to reduce the consumption of chemicals in cleaning processes, Si-wafers contaiminated with metallic impurities were cleaned with electrolyzed water(EW), which was generated by the electrolysis of a diluted electrolyte solution or ultra pure water(UPW). Electrolyzed water could be controlled for obtaining wide ranges of pH and ORP(oxidation-reduction potential). The pH and oxidation-reduction potential of anode water and cathode water were measured to be 4.7 and +1000mV, and 6.3 and -550mV, respectively. To analyze the amount of metallic impurities on Si-wafer surfaces, ICP-MS was introduced. Anode water was effective for Cu removal, while cathode water was more effective for Fe removal.

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Durable Water and Oil Repellent Finish of Wool Fabric(II) (양모직물의 내구성 발수 및 발유가공(II))

  • 나도춘;정순량;박병기;정경락
    • Textile Coloration and Finishing
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    • v.10 no.4
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    • pp.1-6
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    • 1998
  • It is important in the durable water and oil repellent finishing for wool fabric what kinds of water-repellent agents will be used. Water repellent agents and its concentration were aleady chosen in the previous paper, one of the crosslinking agents which has less damages(harsh handle or yellowing) to the treated fabrics was a low molecular weight urethane-based resins(eg. Elastron BN-11). In repellent finishing, fabrics were padded in a bath which contained aqueous solution of water-repellent agents, and crosslinking agents, and wetting agents, followed by drying and curing. The most suitable treating condition for excellent repellency and durability to dry-cleaning was as follows : Fabrics are padded at liquor pick-up ratio of 50%, with aqueous solution which contained $30g/\ell$ of water-repellent agents, and $1g/\ell$ of crosslinking agents, and 40g/s of wetting agents. And the padded fabrics were dried at $110^\circ{C}$ for 1 minute, and cured at $160^\circ{C}$ for 1 minute. For the fabrics, water and oil repellencies and durability to repeated dry-cleanings were observed. For enhancing the durability to dry-cleaning, the role of crosslinking agents was important for they bonds water-repellent agents and fibers to 3-dimensional net structure. Therefore, the most suitable drying and curing conditions should be selected according to the kinds of crosslinking agents.

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Review of Problems with Use of Halogenated Cleaning Solvents Revealed through Case Studies of Cleaning Solvent Poisoning and Analysis of Domestic and Overseas Regulations (세척제 용매 중독 사례와 국내·외 규제 검토를 통한 할로겐화 용매 세척제 사용의 문제점 고찰)

  • Naroo Lee;Hye Jin Lee;Sujin Jeong;Dohee Lee;Arom Shin
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.33 no.4
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    • pp.517-527
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    • 2023
  • Objectives: We examine cases of chemical poisoning that occurred in the cleaning of metal parts and the regulations on halogenated solvents in other countries and propose regulations necessary to prevent chemical poisoning from halogenated solvents. Methods: We collected cases of chemical poisoning through the website of the Korea Occupational Safety and Health Agency. A review of the literature was conducted focusing on regulations related to halogenated solvents in the United States and the European Union, particularly for cleaning metal parts. Among the Material Safety Data Sheets submitted to the government, MSDS containing eleven substances were extracted to confirm the composition and product use. We investigated cleaning methods for metal parts used in South Korea. For the hazard classification, the European Chemicals Agency or Japan's NITE's website was used. Results: In the case of poisoning, the cleaning methods involving trichloromethane were dipping and dry, which was not found in the literature. It was confirmed that many halogenated solvents and dimethyl carbonate were used for metal cleaning in South Korea. In vapor degreasing using TCE in the USA, even if the facility is strictly managed, such as by installing cooling coils in open cleaning facilities, the risk of exposure to TCE is considered to be not only carcinogenic but also a concern for acute and chronic effects. In comparison, exposure through Korean work methods such as dipping and drying operations is inevitably much higher. Conclusions: The transition to water-based cleaning with low-hazard chemicals should be a priority in the cleaning process. In the case of metal parts that require precise cleaning, if the use of a halogenated solvent is inevitable, a closed degreasing facility should be used to minimize exposure. The current regulations in the Occupational Safety and Health Act, the Chemical Substances Control Act, and the Air Environment Conservation Act do not require cleaning facilities to minimize emissions. To protect the health of workers using halogenated solvents to clean metal parts, regulations that require a fundamental reduction in exposure will be necessary.

Study on Aluminum Frame Surface Cleaning Process for Photomask Pellicle Fabrication (포토마스크 펠리클 제조를 위한 Aluminum Frame 표면 세정공정 연구)

  • Kim, Hyun-Tae;Kim, Hyang-Ran;Kim, Min-Su;Lee, Jun;Jang, Sung-Hae;Choi, In-Chan;Park, Jin-Goo
    • Korean Journal of Materials Research
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    • v.25 no.9
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    • pp.462-467
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    • 2015
  • Pellicle is defined as a thin transparent film stretched over an aluminum (Al) frame that is glued on one side of a photomask. As semiconductor devices are pursuing higher levels of integration and higher resolution patterns, the cleaning of the Al flame surface is becoming a critical step because the contaminants on the Al flame can cause lithography exposure defects on the wafers. In order to remove these contaminants from the Al frame, a highly concentrated nitric acid ($HNO_3$) solution is used. However, it is difficult to fully remove them, which results in an increase in the Al surface roughness. In this paper, the pellicle frame cleaning is investigated using various cleaning solutions. When the mixture of sulfuric acid ($H_2SO_4$), hydrofluoric acid (HF), hydrogen peroxide ($H_2O_2$), and deionized water with ultrasonic is used, a high cleaning efficiency is achieved without $HNO_3$. Thus, this cleaning process is suitable for Al frame cleaning and it can also reduce the use of chemicals.

A Study on Estimating Diffuse Pollution Loads Removal by Road Vacuum Cleaning (도로청소에 의한 비점오염부하 삭감량 산정방법 연구)

  • Lee, Taehwan;Cho, Hong-Lae;Jeong, Euisang;Koo, Bhon K.;Park, Baekyung;Kim, Yongseok
    • Journal of Korean Society on Water Environment
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    • v.33 no.2
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    • pp.123-129
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    • 2017
  • The purpose of this study is to identify potential methodologies to reasonably estimate the effectiveness of road vacuum cleaning in terms of pollution loads reduction. In this context, this study proposes two empirical equations to estimate the amount of diffuse pollution loads removed by road vacuum cleaning. The proposed equations estimate the removed amount of pollution loads respectively taking into consideration of: a) the distance of road vacuum cleaning; and b) the amount of road-deposited sediment(RDS). All of the parameters in these equations were evaluated based on results of field monitoring and laboratory analyses, except for the RDS generation rate. The results of this study suggest that pollutant removal efficiency is 46.3% for $BOD_5$ and 56.4% for TP; discharge ratios for particulate and dissolved $BOD_5$ are 35.0% and 21.2%, respectively; discharge ratios for particulate and dissolved TP are 35.0% and 19.4%, respectively. Average concentrations of pollutants in RDS are $BOD_5$ 977.3 mg/kg and TP 317.6 mg/kg. Some results of a case study imply that both equations can be potentially useful if the adopted parameters are reasonably evaluated. In particular, the RDS generation rate should be evaluated based on monitoring data collected from various road conditions.

Evaluation of membrane fouling characteristics due to manganese and chemical cleaning efficiency in microfiltration membrane process (막여과 정수처리공정에서 망간에 의한 막오염 특성 및 화학세정효율 평가)

  • Kang, Joon-Seok;Park, Seogyeong;Song, Jiyoung;Jeong, Ahyoung;Lee, Jeong-Jun;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.6
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    • pp.539-549
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    • 2017
  • In water treatment process using microfiltration membranes, manganese is a substance that causes inorganic membrane fouling. As a result of analysis on the operation data taken from I WTP(Water Treatment Plant), it was confirmed that the increase of TMP was very severe during the period of manganese inflow. The membrane fouling fastened the increase of TMP and shortened the service time of filtration or the cleaning cycle. The TMP of the membrane increased to the maximum of $2.13kgf/cm^2$, but it was recovered to the initial level ($0.17kgf/cm^2$) by the 1st acid cleaning step. It was obvious that the main membrane fouling contaminants are due to inorganic substances. As a result of the analysis on the chemical waste, the concentrations of aluminum(146-164 mg/L) and manganese(110-126 mg/L) were very high. It is considered that aluminum was due to the residual unreacted during coagulation step as a pretreatment process. And manganese is thought to be due to the adsorption on the membrane surface as an adsorbate in feed water component during filtration step. For the efficient maintenance of the membrane filtration facilities, optimization of chemical concentration and CIP conditions is very important when finding the abnormal level of influent including foulants such as manganese.

Removal of Organic Wax and Particles on Final Polished Wafer by Ozonated DI Water

  • Yi, Jae-Hwan;Lee, Seung-Ho;Kim, Tae-Gon;Lee, Gun-Ho;Choi, Eun-Suck;Park, Jin-Goo
    • Korean Journal of Materials Research
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    • v.18 no.6
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    • pp.307-312
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    • 2008
  • In this study, a new cleaning process with a low cost of ownership (CoO) was developed with ozonated DI water ($DIO_3$). An ozone concentration of 40 ppm at room temperature was used to remove organic wax film and particles. Wax residues thicker than $200\;{\AA}$ remained after only a commercial dewaxer treatment. A $DIO_3$ treatment in place of a dewaxer showed a low removal rate on a thick wax layer of $8000\;{\AA}$ due to the diffusion-limited reaction of ozone. A dewaxer was combined with a $DIO_3$ rinse to reduce the wax removal time and remove wax residue completely. Replacing DI rinse with the $DIO_3$ rinse resulted in a surface with a contact angle of less than $5^{\circ}$, which indicates no further cleaning steps would be required. The particle removal efficiency (PRE) was further improved by combining a SC-1 cleaning step with the $DIO_3$ rinsing process. A reduction in the process time was obtained by introducing $DIO_3$ cleaning with a dewaxing process.

A Study of the Salt Rejection from the Surface of Marine Waste using Ultra Fine Bubble (초미세기포를 이용한 해양쓰레기 표면 내 염분제거에 관한 연구)

  • Kim, Bo-Min;Kim, Kwang-Koo;Park, Chan-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.6
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    • pp.11-18
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    • 2021
  • Nano bubble water is used in various washing processes, including cleaning of solar panels, salt rejection of roads, and cleaning precision parts of machines. High cleaning efficiency and water conservation are obtained by applying nano bubbles during pretreatment of the marine waste cleaning system. This study compared the salt rejection of nano bubble water, and it was revealed that marine waste was produced by wood immersed in 200,000 mg/L NaCl solution. Using tap water and nano bubble water for washing, comparisons of the surface salt concentrations of wood were determined according to the nozzle, orifice diameter, pump speed and washing time. Decreased surface salt concentration was observed on the wood surface with increasing washing time. Water consumption was optimal between 5- and 10-seconds washing time. Increasing orifice diameter of the nozzle reduced the spraying pressure, with consequent increase in the wood surface salt concentration, thereby establishing the importance of orifice diameter of the nozzle. Compared to levels obtained with tap water, salt concentration of the wood surface after washing with nano bubble water was 2.2% lower with sector nozzle, and 30.9% lower with circular nozzle. In the washing experiment using nano bubble water, the salt concentration on the wood surface was about 9.5 mg/L lower when washed with sector nozzle than the circular nozzle.