• Analytical Science and Technology
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• v.37 no.3
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• pp.174-188
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• 2024

This review summarized research trends regarding sample collection methods, pretreatment method, and types of analysis devices for microplastics (MPs) in soil and groundwater matrices. Soil sampling considers the selection of sampling location, depth, and volume. The typically sampling depth is within 15 cm (topsoil), and about 1 kg of mixed each sample. Among spot sampling and continuous flow sampling, groundwater sampling mainly used a continuous flow sampling, with collection rates 2 to 6 L/min in the range of 300~1,000 L, and followed by immediate on-situ filtration. Pretreatment method, applied to soil and groundwater, consist of organic digestion and density separation. In the organic digestion method, H₂O₂ is recommended among H₂O₂, acidic, alkaline, and enzymatic method. NaCl is primarily used as a reagent in density separation. However, depending on the density of MPs, other regents can be selectively used like ZnCl₂, ZnBr₂, and etc. Representative analysis device includes Fourier Transform Infrared (FTIR) and Raman spectroscopy for non-destructive analysis and Pyrolysis Gas Chromatography Mass Spectrometry (Py-GC/MS) for destructive analysis. µ-FTIR and Raman can count MPs of larger than 10 and 1 ㎛, and analyze MPs materials. However, it is need to sufficiently remove interference, like organic matter, in spectroscopic analysis using essential pretreatment method. Py-GC/MS is being continuously researched because it doesn't require complex pretreatment method and allows quantitative analysis of specific materials.

• Korean Journal of Heritage: History & Science
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• v.56 no.4
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• pp.216-228
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• 2023

The purpose of this study is to apply the handheld Raman spectrometer to identify the coloring materials used in a large Buddhist painting (of Maitreya Buddha) at Janggoksa Temple through cross-validation with HH-XRF. An in situ investigation was performed together with use of a digital microscope and HH-XRF analysis to verify the properties of pigments used in the gwaebul ("large Buddhist painting") via a non-destructive method. However, the identification of coloring materials composed of light elements and mixed or overlaid pigments is difficult using only non-destructive analysis data. Unlike in situ investigation, laboratory analysis often required samples yet the sampling is restricted to a small quantity due to the cultural heritage characteristic. Thus, it is necessary to develop a non-destructive in situ method to supplement the HH-XRF data. The large Buddhist painting at Janggoksa Temple was painted mainly using white, red, yellow, green, and blue colors. The Raman spectroscopy provides molecular information, while XRF spectroscopy provides information about elemental composition of the pigments. Analysis results identified various coloring materials: inorganic pigment, such as lead white, minium, cinnabar, and orpiment, as well as organic pigment such as gamboge and indigo. Therefore, it is possible to obtain more information for the identification of pigments; organic pigment and mixed or overlaid pigments, while at the same time minimizing the collection sample and simplifying the analysis procedure compared to previously used methods. The results of this study will be used as basic data for the analysis of painting cultural heritage through a non-destructive in situ method in the future.

• Journal of the Korean Solar Energy Society
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• v.33 no.5
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• pp.51-59
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• 2013

It is usual to evaluate the performance of the cool roof by measuring in-site rooftop temperature using thermal infra-red camera. The principal advantage of rooftop thermal infrared image acquired in oblique vantage point of super high-rise building as a remote sensor is to provide, in a cost-effective manner, area-wide information required for a scattered rooftop target with different colors, utilizing wide view angle and multi-temporal data coverage. This research idea was formulated by incorporating the concept of traditional remote sensing into rooftop temperature monitoring. Correlations between infrared image of super high-rise building and in-situ data were investigated to compare rooftop surface temperature for a total of four different rooftop locations. The results of the correlations analyses indicate that the rooftop surface temperature by the infrared images of super high-rise building alone could be explained yielding $R^2$ values of 0.951. The visible permanent record of the oblique thermal infra-red image was quite useful in better understanding the nature and extent of rooftop color that occurs in sampling points. This thermal infrared image acquired in oblique vantage point of super high-rise made it possible to identify area wide patterns of rooftop temperature change subject to many different colors, which cannot be acquired by traditional in-site field sampling. The infrared image of super high-rise building breaks down the usual concept of field sampling established as a conventional cool roof performance evaluation technique.

• Proceedings of the KSRS Conference
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• v.2
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• pp.909-912
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• 2006

In this paper a method for remotely-sensed assessment of eutrophication was experimented. The water samples were collected for analysis of COD (chemical oxygen demand) and nutrients concentration, and the remote sensing reflectance data at the sampling points were synchronously measured using above-water method in two cruises, which were conducted in the Pearl River Estuary in January 2003 and January 2004 respectively. Based on the in-situ data the local algorithms for estimation of concentration of nutrients (P and N) and COD were developed by Partial Least Squares (PLS) regression. The algorithms were then applied to atmospheric-corrected SeaWiFS data and the COD and nutrients concentration in Pearl River Estuary were estimated. And then the assessment of eutrophication was carried out by comparison of the estimated nutrients and COD value with the water quality standard. The results show that the whole estuary is seriously in eutrophication.

• Korean Journal of Ecology and Environment
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• v.37 no.4 s.109
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• pp.363-367
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• 2004

For comparative analysis of the eubacterial community structure at 8 sampling sites throughout the Nak-Dong River, FISH (fluorescence in situ hybridization) method was employed. The total ratio of each determined eubacterial group such as ${\alpha}\;{\cdot}\;{\beta}\;{\cdot}\;{\gamma}-subclasses$proteobacteria and Cytophaga-Flavobacterium(CF) group to total counts(DAPI) at each site varied 9.3-42.5% with the highest value at uppermost part. And each ratio of determined eubacterial groups reached mostly under 10% except that of CF group (23%) at uppermost part. Furthermore, compared to lower part, upper part represented unexpectedly higher proportions of ${\gamma}-subclass$ proteobacteria comprised almost fast growing bacteria on degradable organics. Also the variations of ammonia-oxidizing bacteria ranged from $2.7{\times}10^4$ to $18.0{\times}10^4$ cells $mL^{-1}$ with the lowest value in lower part and the highest value in mid part whereas those of nitrite-oxidizing bacteria varied 5.2-7.7{\times}10^4$ cells $mL^{-1}$ without noticeable differences throughout the sites. Additionally, the ratio of nitrifying bacteria to total counts ranged from 1.0% to 13.6% with no differences between ammonia-oxidizing bacteria and nitrite-oxidizing bacteria. In conclusion, FISH method introduced in this study for monitoring, normally used for the quantitative analysis of bacteria, provided also good information on their environmental status in the Nak-Dong River.

• Journal of the Korean GEO-environmental Society
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• v.14 no.7
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• pp.31-38
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• 2013

After debris flow caused damage during recent years, many scholars and engineers have thrown their effort into analyzing risk from debris flow in Korea. But it is hard to predict damage by debris flow taken place in wide area. Recently, SINMAP program is widely well used to estimate the amount of debris flow and its' range. In order to make frequent use of it, the most important thing is selection of accurate input parameters. In-situ experiments, which are avaliable in the mountain, is to be suggested to get dependable input parameters for SINMAP. Those are permeability, cohesion, density, friction angle and thickness in SINMAP. To get those, test pit, block sampling, in-situ density test, auger boring, permeability test on ground surface, borehole shear test and dynamic cone test and so forth were selected. In addition, the reliability of the results will be increased through comparing with those by laboratory tests. Hence, the experiments are hard to enter the sites without temporary road and, if possible, licensing and many times are needed, too. Small size experiments are indeed necessary to get accurate parameters.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2002.10a
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• pp.441-444
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• 2002

In recent, industrialization increases the level of pollution load in sea areas, and the inflows of pollutants to public sea areas cause sudden and wide-range of influence to the water quality and the ecosystem. To prepare for these kinds of unpredictable water pollution issues, the necessity is emerging to build an automatic water quality monitoring system, which can monitor and alarm the water quality changes of the subject sea areas. For the ongoing installation plan of the automatic water quality monitoring system around the Saemankeum sea area, this report compares and analyzes its installation conditions as well as the physical and chemical characteristics of the in-situ type and the water-sampling type of the automatic water quality monitoring equipments, and subjects to provide elementary data for the system installation in the Saemankeum.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.353-360
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• 2000

We developed large diameter sampler (we called KICT type large diameter sampler) to obtain undisturbed clay and sand samples. In-situ test carried out in the In-Chon international airport and Kim-Hae. Also we obtained undisturbed sample with a hydraulic piston sampler in the nearly site and carried out unconfined compression test, consolidation test and triaxial test. The result, unconfined compression strength, secant modules, preconsolidation pressure and undrained shear strength of samples to obtain KICT type large diameter sampler are larger than that of samples to obtain hydraulic piston sampler. But failure strains and volume changes at the consolidation of samples to obtain KICT type large diameter sampler are smaller than that of samples to obtain hydraulic piston sampler

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.216-216
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• 2015

용융아연 도금 공정에서 강판이 도금욕에 침적되는 동안 강판으로부터 용출되는 Fe는 도금욕 내 Al, Zn와 반응하여 다양한 형태의 드로스를 형성시키는 원인이 된다. 이들 드로스는 강판 표면에 다양한 형태의 결함을 야기하므로, 실제 도금 공정에서 도금욕 내 발생하는 드로스의 생성거동에 관한 이해는 필수적이다. 따라서 본 연구에서는 도금욕 내 $Fe_xAl_yZn_z$계 드로스 생성에 미치는 도금욕 내 Al 및 Fe 함량의 영향에 대해 고찰하였으며, in-situ sampling 기법 및 finger rotating method를 이용하였다.

• Journal of the Korean Mathematical Society
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• v.38 no.3
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• pp.523-559
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• 2001

To predict the fate of groundwater contaminants, accurate spatially continuous information is needed. Because most field sampling of groundwater contaminants are not conducted spatially continuous manner, a special estimation technique is required to interpolate/extrapolate concentration distributions at unmeasured locations. A practical three-dimensional estimations method for in situ groundwater contaminant concentrations is introduced. It consistas of two general steps: estimation of macroscopic transport process and kriging. Using field data and nonlinear optimization techniques, the macroscopic behavior of the contaminant plume is estimated. A spatial distribution of residuals is obtained by subtracting the macroscopic transport portion from field data, then kriging is applied to estimate residuals at unsampled locations. To reduce outlier effects on obtaining correlations between residual data which are needed for determining variougram models, the R(sub)p-estimator is introduced. The proposed estimation method is applied to a field data set.