• Title/Summary/Keyword: In situ measurements

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Semi-Automatic Hydride Generation and Atomic Absorption Determination of Bismuth with in situ Concentration in a Graphite Furnace

  • Yong-Keun Lee;Dong Soo Lee;Byung Mok Yoon;Hoon Hwang
    • Bulletin of the Korean Chemical Society
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    • v.12 no.3
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    • pp.290-295
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    • 1991
  • A semi-automatic method for the determination of dissolved bismuth at parts per trillion levels is described. The method involves bismuthine generation, in situ collection of bismuthine in a graphite furnace, and atomic absorption detection. In order to facilitate semi-automation of bismuthine generation and separation from aqueous solution, Gore-tex microporous PTEE membrane is used. The absolute detection limit, taken as three times the standard deviation of the instrument noise is 2 pg. The precisions are 3.1% for 100 pg and 1.9% for 1 ng of bismuth, respectively. As many as 90 measurements can be made in an hour.

Back Analysis of Displacements Measured During Excavation of Underground Storage Caverns

  • Lee, Chung-In;Lee, Youn-Kyou;Kim, Chee-Hwan
    • Geotechnical Engineering
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    • v.12 no.3
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    • pp.83-98
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    • 1996
  • In this paper, the results of back analysis based on, the inverse method are presented. Using the field measurements obtained from the two different underground storage caverns in Korea during their construction, the deformation modulus and the initial in-situ stresses of the rock masses around the access tunnels are calculated. The finite element analysis is carried out by usinB these results as input parameters. The calculated displacements are compared with the measured ones.

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Bearing Capacity of In-situ Cast Piles in Weak Sedimentary Rocks (미고결 퇴적암층에서의 현장타설말뚝 지지력 특성 연구)

  • Sim, Dong-Hyun;Kim, Ki-Seop;Yu, Seok-Joon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.100-109
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    • 2004
  • Is this study, results of static pile load tests of in-situ cast piles in weak or uncemented sedimentary rock layers have been analyzed and presented. Consdierations on the characteristics of soils sedimentary rocks have been made. From the measurements of strain gauges and extensometers the relationship of unit skim friction versus displacement and that of unit end bearing versus displacement have been obatined to verity the characteristics of bearing capacity of this uncemented sedimentary rock layers. Also, a comparison has been made between ultimate skin friction in compression and tension.

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Optical Interferometry as Electrochemical Emission Spectroscopy of Metallic alloys in Aqueous Solutions

  • Habib, K.;AI-Mazeedi, H.
    • Corrosion Science and Technology
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    • v.2 no.6
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    • pp.277-282
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    • 2003
  • Holographic interferometry, an electromagnetic method, was used to study corrosion of carbon steel, aluminum and copper nickel alloys in NaOH, KCI and $H_2SO_4$ solutions respectively. The technique, called electrochemical emission spectroscopy, consisted of in-situ monitoring of changes in the number of fringe evolutions during the corrosion process. It allowed a detailed picture of anodic dissolution rate changes of alloys. The results were compared to common corrosion measurement methods such as linear polarization resistance measurements and electrochemical impedance spectroscopy. A good agreement between both data was found, thus indicating that holographic interferometry can be a very powerful technique for in-situ corrosion monitoring.

Effect of Various Supports on the Physico-chemical Properties of V-Sb Oxides in the Oxidative Dehydrogenation of Isobutane

  • Shamilov, N.T.;Vislovskiy, V.P.
    • Journal of the Korean Chemical Society
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    • v.55 no.5
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    • pp.812-818
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    • 2011
  • [ $V_{0.9}Sb_{0.1}O_x$ ]systems, bulk and deposited on different supports (five types of ${\gamma}$-aluminas, ${\alpha}$-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. This statement is derived from the data obtained by a set of characterisation techniques(specific surface area measurements, X-ray diffraction, X-ray photoelectron spectroscopy, laser Raman spectroscopy, in situ differential scanning calorimetry and in situ diffuse reflectance-absorption infrared Fourier transform spectroscopy).

In-situ Performance Test and Prediction of a 10 RT Air Source Heat Pump (10RT급 공기열원 열펌프의 현장 성능측정 및 예측)

  • 김영일;백영진;장영수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.3
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    • pp.221-230
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    • 2002
  • In this study, in-situ performance test of an air source heat pump which has a arted capacity of 10 RT is carried out. Since test conditions, such as indoor and outdoor air conditions cannot be controlled to satisfy the standard test conditions, experiments are done with the inlet air conditions as they exist. To estimate the performance for other conditions, he heat pump is modeled with a small number of selected parameters. The values of the parameters are determined from the few measurements measured on-site during normal operation. A simulation program is developed to calculate cooling capacity and power consumption t any other operating conditions. The simulation results are in good agreement with the experiment. This study provides a method of an on-site performance diagnosis of an air source heat pump.

Estimation of in-situ Stresses and the Effect of a Preexisting Inclined Fracture by Hydraulic Fracturing (수압파쇄를 이용한 초기지압측정과 기존경사균열의 영향)

  • 신중호;신희순;최성웅;이희근
    • Tunnel and Underground Space
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    • v.4 no.1
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    • pp.55-62
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    • 1994
  • The hydraulic fracturing in a field site was performed for the measurement of in-situ stresses. For the estimation of the effect of a preexisting inclined fracture, the test on a preexisting fracture zone was also conducted. From the measurements at three shallow depths, the ratios of max. to min. horizontal stress showed the range of 1.19-1.56 and the K values showed the range of 2.62-3.86. In case of a preexisting fracture with the inclination of 15 degrees, the stresses calculated as upper bound values by considering it. It seemed from this that the inclination less than 15 degrees had small effect on the stress calculation.

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Development and Application of Penetration-type Bender Elements Probe for Stiffness Measurements of Soft Soils (연약지반의 강성도 측정을 위한 관입형 벤더 엘리먼트 프로브의 개발 및 적용)

  • Mok, Young-Jin;Jung, Jae-Woo;Kim, Hak-Sung
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.119-126
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    • 2008
  • Ground stiffness(shear wave velocity) is one of the key parameters in geotechnical earthquake engineering. An In-situ seismic technique has its own advantages and disadvantages over the others in stiffness measurements. By combining the crosshole and seismic cone techniques and utilizing favourable features of bender elements, a new hybrid probe has been developed in order to enhance data quality and easiness of testing. The basic structure of the probe, called "MudFork", is a fork composed of two blades, on each of which source and receiver bender elements were mounted respectively. To evaluate the disturbance caused by the penetration of the probe, shear wave velocity measurements were carried out in the Kaolinite slurry in the laboratory. Finally, the probe was penetrated in coastal mud near Incheon, Korea, using SPT(standard penetration test)rods pushed with a routine boring machine and shear wave velocity measurements were carried out. The results were verified with data from laboratory and cone testing. The performance of the probe turns out to be excellent in terms of data quality and testing convenience.

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Error Characteristics of Satellite-observed Sea Surface Temperatures in the Northeast Asian Sea (북동아시아 해역에서 인공위성 관측에 의한 해수면온도의 오차 특성)

  • Park, Kyung-Ae;Sakaida, Futoki;Kawamura, Hiroshi
    • Journal of the Korean earth science society
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    • v.29 no.3
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    • pp.280-289
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    • 2008
  • An extensive set of both in-situ and satellite data regarding oceanic sea surface temperatures in Northeast Asian seas, collected over a 10-year period, was collocated and surveyed to assess the accuracy of satellite-observed sea surface temperatures (SST) and investigate the characteristics of satellite measured SST errors. This was done by subtracting insitu SST measurements from multi-channel SST (MCSST) measurements. 845 pieces of collocated data revealed that MCSST measurements had a root-mean-square error of about 0.89$^{\circ}C$ and a bias error of about 0.18$^{\circ}C$. The SST errors revealed a large latitudinal dependency with a range of $\pm3^{\circ}C$ around 40$^{\circ}N$, which was related to high spatial and temporal variability from smaller eddies, oceanic currents, and thermal fronts at higher latitudes. The MCSST measurements tended to be underestimated in winter and overestimated in summer when compared to in-situ measurements. This seasonal dependency was discovered from shipboard and moored buoy measurements, not satellite-tracked surface drifters, and revealed the existence of a strong vertical temperature gradient within a few meters of the upper ocean. This study emphasizes the need for an effort to consider and correct the significant skin-bulk SST difference which arises when calculating SST from satellite data.

Dispersive White-light Interferometry for in-situ Volumetric Thickness Profile of Thin-film Layers and a refractive index (분산형 백색광 간섭계를 이용한 미세 박막 구조물의 삼차원 두께 형상 및 굴절률의 실시간 측정)

  • Ghim Y.S.;Kim S.W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.23-24
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    • 2006
  • We present a dispersive scheme of white-light interferometry that enables not only to perform tomographical measurements of thin-film layers but also to measure a refractive index without mechanical depth scanning. The interferometry is found useful particularly for in-situ 3-D inspection of micro-engineered surfaces such as liquid crystal displays, semi-conductor and MEMS structure, which requires for high-speed implementation of 3-D surface metrology.

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