• 폴리머
• /
• 제38권6호
• /
• pp.752-759
• /
• 2014

본 연구에서는 미세 전자 소자용 절연박막 및 차세대 플렉시블 디스플레이 기판으로서 사용이 기대되는 폴리이미드(PI)에 개환 복분해 중합(ring-opening metathesis polymerization)이 가능한 환형 말단 캡핑제(end-capping agent)인 cis-1,2,3,6-tetrahydrophthalic anhydride(CDBA)로 사슬 말단에 가교 반응이 된 가교형 폴리이미드를 합성하였다. 말단 캡핑제의 조성비에 따른 가교형 폴리이미드 박막의 잔류응력 거동은 thin film stress analyzer(TFSA)를 이용한 wafer bending mothod로 온도에 따라 연속적인 거동을 in-situ로 측정하였다. 열특성은 시차 주사 열량계(DSC), 열기계 분석기(TMA) 및 열 중량 분석기(TGA)를 이용하여 측정하였고, 광학 특성은 자외선/가시광선 분광광도계(UV-vis)와 색차계(spectrophotometer)를 이용하였으며, 네트워크 구조의 모폴로지(morphology) 변화를 통해 해석하였다. 말단 캡핑제의 조성비가 증가함에 따라 잔류응력은 27.9에서 -1.3 MPa로 초저응력 및 향상된 열 특성을 나타내었으나, 광학 특성은 감소됨을 보였다. 가교형 폴리이미드 박막의 우수한 특성 발현은 고집적도 다층 구조의 안정성 및 신뢰도가 요구되는 분야의 응용성이 확대될 것으로 기대된다.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
• /
• pp.132-132
• /
• 2013

Colloidal synthesis of nanoparticles with well-controlled size, shape, and composition, together with development of in situ surface science characterization tools, such as ambient pressure X-ray photoelectron spectroscopy (APXPS), has brought new opportunities to unravel the surface structure of working catalysts. Recent studies suggest that surface oxides on transition metal nanoparticles play an important role in determining the catalytic activity of CO oxidation. In this talk, I will outline the recent studies on the influence of surface oxides on Rh, Pt, Ru and Co nanoparticles on the catalytic activity of CO oxidation [1-3]. Transition metal nanoparticle model catalysts were synthesized in the presence of poly(vinyl pyrrolidone) polymer capping agent and deposited onto a flat Si support as two-dimensional arrays using the Langmuir-Blodgett deposition technique. APXPS studies exhibited the reversible formation of surface oxides during oxidizing, reducing, and CO oxidation reaction [4]. General trend is that the smaller nanoparticles exhibit the thicker surface oxides, while the bigger ones have the thin oxide layers. Combined with the nature of surface oxides, this trend leads to the different size dependences of catalytic activity. Such in situ observations of metal nanoparticles are useful in identifying the active state of the catalysts during use and, hence, may allow for rational catalyst designs for practical applications. I will also show that the surface oxide can be engineered by using the simple surface treatment such as UV-ozone techniques, which results in changing the catalytic activity [5]. The results suggest an intriguing way to tune catalytic activity via engineering of the nanoscale surface oxide.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2010년도 추계 학술발표회 3차
• /
• pp.140-145
• /
• 2010

Consolidation in cohesive soils mainly focuses on compressibility of soils, but it affects solute transport in some cases. The consolidation process takes on particular significance for fine grained soils at high water content, such as dredged sediments, but has also been shown to be important for compacted clay liners during waste filling operation. Numerical investigation using CST1 and CST2 was reviewed on consolidation-induced solute transport in this paper, especially with the development of CST2 model, verification by comparing experimental results with numerical simulations, and cases studies regarding transport in a confined disposal facility (CDF) and during in-situ capping. The importance of the consolidation process on solute transport is accessed based on simulated concentration or mass breakthrough curves. Results indicate that neglecting transient consolidation effects may lead to significant errors in transport analyses, especially with soft contaminated cohesive soils undergoing large volume change.

• 한국농공학회논문집
• /
• 제56권2호
• /
• pp.25-35
• /
• 2014

New technology and construction methods in civil engineering area have been noticeably improved associated with the industrial development. However, thicknesses of a lift is strictly specified for subgrade and roadbed embankment as 20 cm and 30 cm in the specification of Korea Highway. Since there has been a problem to get enough amount of soils to be used for compaction, the rocks have been replaced for those. However, there is no guideline for the quality control of rock while changing compaction efficiency of equipment and physical properties of reck while changing compaction method such as thicknesses of a lift, number of compaction and etc. The main objective of this research is to establish the specification for the rock compaction method of embankment which including thickness of lift and quality control method in Korea Expressway.

• 마이크로전자및패키징학회지
• /
• 제21권1호
• /
• pp.41-44
• /
• 2014

We employed UV-Ozone treatment method for the fabrication of dense and highly conductive nanoparticle thin films. We demonstrated the UV-Ozone treatment effect on the silver nanoparticle thin films as a function of time and temperature. The capping layers of nanoparticles were decomposed after UV-Ozone treatment and dense nanoparticle thin films were obtained. Moreover, electrical and mechanical properties of the thin films after UV-Ozone treatment were measured by using resistance measurements under tension in an in-situ tensile tester. The initial resistance of nanoparticle thin films was decreased by 82.6% with optimized UV-Ozone treatment condition of $150^{\circ}C$ for 20 minutes.

• 한국지반공학회논문집
• /
• 제19권3호
• /
• pp.33-38
• /
• 2003

모래를 이용한 해안퇴적층 캡핑은 오염원의 이동을 줄일 수 있는 하나의 방법이다. 캡핑 설계시 자중에 의한 캡 자체의 압밀과 새로 추가된 캡층에 의한 퇴적층의 압밀을 반드시 고려해야만 한다. 이를 위해 원심모형시험기를 이용한 모형실험이 실시되었다. 이 연구에서는 실험의 정확성을 알아보기 위해 모델을 다시 모델링 하는 방법이 이용되었다. 즉, 똑 같은 경계 조건에서 서로 다른 중력가속도를 가지고 실험이 실시 되었다. 두 실험의 결과가 잘 일치함을 알 수 있었다. 이것은 캡이 설치된 해안퇴적층의 압밀침하 거동을 원심모형실험을 이용하여 예측이 가능함을 알 수 있다.

• Applied Microscopy
• /
• 제36권spc1호
• /
• pp.35-40
• /
• 2006

Self-assembled InAs/GaAs quantum dots (QDs) were grown by the atomic layer epitaxy (ALE) and molecular beam epitaxy (MBE) techniques, The structure and the thermal stability of QDs have been studied by high resolution electron microscopy with in-situ heating experiment capability, The ALE and MBE QDs were found to form a hemispherical structure with side facets in the early stage of growth, Upon capping by GaAs layer, however, the apex of QDs changed to a flat one. The ALE QDs have larger size and more regular shape than those of MBE QDs. The QDs collapse due to elevated temperature was observed directly in atomic scale, In situ heating experiment within TEM revealed that the uncapped QDs remained stable up to $580^{\circ}C$, However, at temperature above $600^{\circ}C$, the QDs collapsed due to the diffusion and evaporation of In and As from the QDs, The density of the QDs decreased abruptly by this collapse and most of them disappeared at above $600^{\circ}C$.

• 한국동물위생학회지
• /
• 제22권3호
• /
• pp.247-255
• /
• 1999

Sequential morphologic changes in the lymphoid organs were examined after ocular and cloacal inoculation in 3weekold chicks with a highly virulent strain (SH/92) of infectious bursal disease virus (IBDV). The infected chickens were sacrificed at 6, 12, 24, 48, 72, and 96 hrs post inoculation (Pl), and thymus, harderian gland, ceacal tonsil, and spleen were observed. Histologically, the significant lesions were characterized by lymphocyte depletion and the earliest detectable changes were evident at 12 hrs Pl. In thymic cortex, lymphoid depletion with apoptosis and prominent "tingible body macrophages" were observed. As the infection advanced, the lesions showed more severe changes. Dying cells were characterized either by capping of nuclear chromatin (apoptosis) or by cytoplasmic swelling (necrosis). In situ staining for apoptosis, some lymphoid cells revealed typical positive reaction, even the stainability was variable depend on every lymphoid organs. These results suggest that IBBV (SH/92) cause severe damage both primary and secondary lymphoid organs, and both T and B lymphocytes. Also the lymphoid depletion of these organs is caused by necrosis and apoptosis induced by IBDV.d by IBDV.

• 청정기술
• /
• 제29권1호
• /
• pp.71-75
• /
• 2023

다공성 결정물질(예: 금속유기골격체(Metal-Organic Framework, MOF), 제올라이트(zeolite))로 만들어진 다결정성 분리막의 선택도는 일반적으로 크기가 1 nm 혹은 그 이상으로 알려진 비선택적 결정 간 결함, 즉 결정립계의 존재 때문에 저하된다. 본 논문에서는 다결정성 MOF 분리막 위에 폴리다이메틸실록산(polydimethylsiloxane, PDMS)의 코팅이 결정립계를 캡핑하여 분리막의 선택도를 향상시키는데 효과적임을 증명하였다. 제안된 개념을 증명하기 위해서 in-situ 용매열 합성법을 통해 제조된 지르코늄 기반의 MOF의 일종인 UiO-66 분리막 위에 PDMS를 코팅한 후, 코팅 전후의 성능변화를 관찰하였다. PDMS 코팅 후 UiO-66 분리막의 CO₂/N₂ 단일 기체 분리 선택도는 6에서 14로 증가하였고, 동시에 CO₂ 투과도는 5700 GPU에서 33 GPU로 감소하였다. 선택도의 증가는 PDMS 코팅이 결정립계 결함을 효과적으로 메웠음을 의미하며, 동반된 투과도의 감소는 PDMS 코팅이 결함을 메우는 동시에 분리막 위에 연속적인 층을 형성하여 추가된 투과 저항에서 비롯되었다고 판단된다.

• 한국지반환경공학회 논문집
• /
• 제17권11호
• /
• pp.23-33
• /
• 2016

본 연구에서는 해저에 퇴적된 오염 침전물질을 제올라이트와 모래로 피복하여 중금속 및 오염물질을 격리하는 피복 공법을 적용한 지역의 해저지반의 역학적 안정성 및 변형 예측을 하였다. 문헌조사와 현장조사를 바탕으로 분석해 본 결과, 이 현장에 맞는 피복재는 중금속 흡착효과가 뛰어난 제올라이트가 적합한 것으로 결정되었다. 정밀지반조사 결과를 바탕으로 오염 침전물질을 제올라이트와 모래로 피복한 후 주변 지반에 대한 안정성 평가와 압밀로 인한 장기지반거동을 예측하였다. 역학적 안정해석 결과, 지면이 해수에 포화되는지 여부에 따라 최저 안전율은 약 11.2와 30.1로 계산되어 충분히 안전한 것으로 판단되었다. 압밀량 해석을 진행한 결과 상단면 기준으로 1차 최대압밀량이 209.2mm 정도 발생하고 2차 압밀량은 1.2mm로 아주 적게 예측되었다. 시간에 따른 압밀도를 계산하여 시간에 따른 1차압밀량도 예측하였다.