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Correlation of the Rates of Solvolyses of Benzhydryl Halides Using an Extended Grunwald-Winstein Equation

  • Koh, Han-Joong;Kang, Suk-Jin;Kim, Cheol-Ju
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.378-382
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    • 2009
  • Rates of solvolyses of benzhydryl chloride ($Ph_2$CHCl, 1) and benzhydryl bromide ($Ph_2$CHBr, 2) in ethanol, methanol, and aqueous binary mixtures incorporating ethanol, methanol, 2,2,2-trifluoroethanol (TFE) and acetone are reported. Solvolyses were also carried out in TFE-ethanol mixtures. Application of the extended Grunwald-Winstein equation led to l value of 1.19 (1), 1.29 (2) and m value of 1.00 (1), 0.77 (2), correlation coefficient of 0.965 (1) and 0.970 (2). Sensitivities (l = 1.19 (1), 1.29 (2) and m = 1.00 (1), 0.77 (2)) were similar to those obtained for several previously studied solvolyses, in which an $S_N$2 pathway is proposed for the solvolyses of benzhydryl halides ($Ph_2$CHX, X = Cl or Br).

Interactive Multimedia Authoring Tool using MPEG-4 BIFS and Wireless Network (MPEG-4 BIFS와 무선데이터통신망을 이용한 인터렉티브 멀티미디어 저작 도구)

  • Ryu, Sung-Pil;Kwak, Nae-Jung;Kwon, Dong-Jin
    • Proceedings of the Korea Contents Association Conference
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    • 2006.11a
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    • pp.458-460
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    • 2006
  • MPEG-4 BIFS(Binary Format for Scene) is the format to describe the information of time-spatial location of each visual objects in the scene. This is broadcasting for test through T-DMB in the our country and is able to be converted to various multimedia formats. The DMB receivers used currently are loaded on mobile devices mostly and the supply of the receiver is increasing steadily. These enable various service for convergence of DMB and wireless network to do. Therefore, this paper propose a new method of interactive multimedia authoring tool using wireless network and MPEG-4 BIFS. The proposed method corrects and complements MPEG-4 BIFS and have DMB broadcasting and wireless network co-operate. Also using this method, users can make out contents by themselves and can retransmit them through DMB broadcasting. The proposed method produce interactive multimedia contents reconstructed at user's request.

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Vegetation Mapping of Hawaiian Coastal Lowland Using Remotely Sensed Data (원격탐사 자료를 이용한 하와이 해안지역 식생 분류)

  • Park, Sun-Yurp
    • Journal of the Korean association of regional geographers
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    • v.12 no.4
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    • pp.496-507
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    • 2006
  • A hybrid approach integrating both high-resolution and hyperspectral data sets was used to map vegetation cover of a coastal lowland area in the Hawaii Volcanoes National Park. Three common grass species (broomsedge, natal redtop, and pili) and other non-grass species, primarily shrubs, were focused in the study. A 3-step, hybrid approach, combining an unsupervised and a supervised classification schemes, was applied to the vegetation mapping. First, the IKONOS 1-m high-resolution data were classified to create a binary image (vegetated vs. non--vegetated) and converted to 20-meter resolution percent cover vegetation data to match AVIRIS data pixels. Second, the minimum noise fraction (MNF) transformation was used to extract a coherent dimensionality from the original AVIRIS data. Since the grasses and shubs were sparsely distributed and most image pixels were intermingled with lava surfaces, the reflectance component of lava was filtered out with a binary fractional cover analysis assuming that tile total reflectance of a pixel was a linear combination of the reflectance spectra of vegetation and the lava surface. Finally, a supervised approach was used to classify the plant species based on tile maximum likelihood algorithm.

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Control Packet Transmission Decision Method for Wearable Sensor Systems (웨어러블 센서 시스템에서의 제어 패킷 전송 결정 기법)

  • Yu, Daeun;Kim, Namgi
    • Journal of Internet Computing and Services
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    • v.16 no.5
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    • pp.11-17
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    • 2015
  • In the general transmission power control model that is used for wearable sensor systems, if RSSI value gets out of the Target RSSI Margin, then the sink node finds new transmission power by using TPC(Transmission Power Control) Algorithm. At this time, the sink node sends the control packet to the sensor node for delivering the newly calculated transmission power. However, when the wireless network channel condition is poor, even it is consuming a lot of control packets, the sink node could not find an appropriate transmission power so it only waste of energy. Therefore, we proposed a new control packet transmission decision method that the sink node changes the transmission power when the wireless network channel condition is stabilized. It makes waste of energy decline. In this paper, we apply control packet transmission decision method to Binary TPC algorithms and analyze the results to evaluate the proposed method. We propose three methods that judge the state of wireless network channel. We experiment that methods and analysis the results.

Absolute Dimension and Pulsational Characteristics of the Eclipsing Binary EW Boo with a δ Sct Pulsator

  • Kim, Hye-Young;Hong, Kyeongsoo;Kim, Chun-Hwey;Lee, Jae Woo;Jeong, Min-Ji;Park, Jang-Ho;Song, Mi-Hwa
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.34.4-35
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    • 2021
  • We present the TESS photometry and our high-resolution spectra of the semi-detached Algol EW Boo. For an orbital period study, we collected all available times of minima including ours for the last 30 years. It is found that the eclipse timing variation of the system can be represented by a periodic oscillation of 18.5±1.0 yr plus a secular period increase with a rate of [dP/dt]orb=-6(±3)×10-8 d yr-1. From our observed spectra, the effective temperature of the primary star was determined to be Teff,1=8560±118 K. From a simultaneous analysis of the TESS light and our double-lined radial velocity curves, the absolute masses, radii, and luminosities are M1=2.30±0.07M, M2=0.38±0.01M, R1=1.92±0.02 R, R2=1.27±0.01 R, L1=1.92±0.02 L, and L2=0.752±0.007 L, respectively. Multiple frequency analyses were carried out for the light residuals after subtracting the binary star model. We detected a total of 75 frequencies in the region of 16.50-104.8 day-1. Our results demonstrate that the more hotter primary star of EW Boo is a δ Sct pulsator by considering its position in the δ Scuti region of the Cepheid instability strip and pulsational characteristics.

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Implementation of Face Detection System on Android Platform for Real-Time Applications (실시간 응용을 위한 안드로이드 플랫폼에서의 안면 검출 시스템 구현)

  • Han, Byung-Gil;Lim, Kil-Taek
    • IEMEK Journal of Embedded Systems and Applications
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    • v.8 no.3
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    • pp.137-143
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    • 2013
  • This paper describes an implementation of face detection technology for a real-time application on the Android platform. Java class of Face-Detection for detection of human face is provided by the Android API. However, this function is not suitable to apply for the real-time applications due to inadequate detection speed and accuracy. In this paper, the AdaBoost based classification method which utilizes Local Binary Pattern (LBP) histogram is employed for face detection. The face detection module has been developed by C/C++ language for high-speed image processing, and this module is included to the Android platform using the Java Native Interface (JNI). The experiments were carried out in the Java-based environment and JNI-based environment. The experimental results have shown that the performance of JNI-based is faster than Java-based method and our system is well enough to apply for real-time applications.

ADDITIONAL ASTRONOMICAL INFORMATION FROM THE ASTROMETRIC OBSERVATIONS OF GRAVITATIONAL MICROLENSING EVENTS (중력렌즈 사건의 측성학적 관측을 통한 추가 천문 정보의 획득)

  • HAN CHEONGHO
    • Publications of The Korean Astronomical Society
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    • v.14 no.1
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    • pp.9-22
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    • 1999
  • Current searches for gravitational microlensing events are being carried out only by a photometric method. In this review paper, we demonstrate that the nature of Galactic lenses can be significantly better constrained with the additional astrometric observations of microlensng events. First, by astromerically observing lensing events, one can resolve the lens parameter degeneracy, and thus the lens mass can be determined with improved precision. Second, by being free from the blending problem, astrometric observations of lensing events will allow one to improve the uncertainties in the determined Einstein time scales. Third, the lens brightness, which could not be measured photometrically, can be measured from the astrometric observations of lensing events, and thus the nature of lens matter can be better constrained. Finally, with the help of astrometric followup observations of a binary-lens event, one can uniquely determine the solution of lens parameters, allowing one to obtain important astronomical information about the source star and the lens itself.

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An Efficient If Routing Lookup by Using Routing Interval

  • Wang, Pi-Chung;Chan, Chia-Tai;Chen, Yaw-Chung
    • Journal of Communications and Networks
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    • v.3 no.4
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    • pp.374-382
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    • 2001
  • Nowadays, the commonly used table lookup scheme for IP routing is based on the sc-called classless interdomain routing (CIDR). With CIDR, routers must find out the best matching prefix (BMP) for IP packets forwarding, this complicates the IP lookup. Currently, this process is mainly performed in software and several schemes hale been proposed for hardware implementation. Since the IP lookup performance is a major design issue for the new generation routers, in this article we investigate the properties of the routing table and present a new approach for IP lookups, our approach is not based Gn BMP and significantly reduces the complexity, thus the computation cast of existing schemes can be significantly reduced. We also propose an efficient IP lookup algorithm, with which we improve the binary search on prefixes to 30 millions of packets per second (MPPS) and 5,000 route updates/s under the same experiment setup with an even larger routing table.

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Study on the space frame structures incorporated with magnetorheological dampers

  • Xu, Fei-Hong;Xu, Zhao-Dong;Zhang, Xiang-Cheng
    • Smart Structures and Systems
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    • v.19 no.3
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    • pp.279-288
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    • 2017
  • Magnetorheological damper has received significant attention in recent years due to the reason that it can offer adaptability of active control devices without requiring the associated large power sources. In this paper, performance tests on a MR damper are carried out under different currents, excitation amplitudes and frequencies, the damping characteristics and energy dissipation capacity of the MR damper are analyzed. Elasto-plastic dynamic analysis on a space frame structure incorporated with MR dampers is conducted, and numerical analysis results show that MR dampers can significantly mitigate the structural vibration responses. Finally, the genetic algorithm with the improved binary crossover and mutation technique is adopted to optimize the arrangement of MR dampers. Numerical results show that dynamic responses of the optimal controlled structure are mitigated more effectively.

Chromatographic Separation of Maltopentaose from Maltooligosaccharides

  • Lee, Jae-Wook;Kwon, Tae-Ouk;Moon, Il-Shik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.1
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    • pp.47-53
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    • 2003
  • An experimental study on the chromatographic separation of maltopentaose from a mixture, including glucose, maltose, maltotriose, and maltopentaose, was carried out in a nonionic polymeric sorbent column while varying the operating conditions, such as the solution pH, buffer contents, and isopropyl alcohol (1PA) concentration. Unlike the pH and buffer contents, the IPA concentration had a Significant impact on the single component chromatograms for maltopentaose. The retention times of the maltooligosaccharides with the nonionic polymeric sorbent Sp207 were in the following order: glucose < maltose < maltotriose < maltopentaose. From the experimental binary, ternary, and quaternary chromatograms, gradient chromatographic separation with a changing IPA concentration as a function of time was required to obtain high-purity maltopentaose and reduce the elution time.