• Title/Summary/Keyword: In(III)

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The Effect of PVA-Al(III) Complex on Pore Formation and Grain Growth of $UO_2$ Sintered Pellet (II) (PVA-A(III) 착물이 $Uo_2$ 소결체의 기공형성과 결정립성장에 미치는 영향(II))

  • 이신영;김형수;노재성
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.782-790
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    • 1999
  • The compressibility sinterability sintering behaviour and thermal stability of AlOOH added UO2 pellt and PVA-Al(III) complex added UO2 pellet were investigated respectively. Compared with characteristics of AlOOH added UO2 pellet the green density and the sintered density of PVA-Al(III) complex added UO2 pellet were lowered but the grain size and the pore size of that were more increased in accordance with higher compacting pressure. The AlOOH added UO2 pellet had the grain size of about 14${\mu}{\textrm}{m}$ with monomodal pore size distribution while the PVA-Al(III) complex added UO2 pellet had the grain size of about 42 ${\mu}{\textrm}{m}$ with bimodal pore size distribution. The PVA-A(III) complex added UO2 pellet had a similiar open porosity to the AlOOH added UO2 pellet and a lower resintered density change than the AlOOH added UO2 pellet.

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Purification and Biochemical Characterization of Carboxylesterase-III from Plodia interpunctella Hubner (화랑곡나방(Plodia interpunctella Hubner) Carboxylesterase-III의 정제 및 생화학적 특성)

  • 박희윤;유종명
    • Journal of the Korean Society of Tobacco Science
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    • v.21 no.2
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    • pp.160-170
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    • 1999
  • Purification and biochemical experiments on the carboxylesterases-III (CE-III) from the indian meal moth, Plodia interpunctella (Hubner) were carried out to understand their enzymemological characteristics. The CE-III from the fifth instar larvae was purified by means of ammonium sulfate fractionation, gel permeation choromatography and ion exchange choromatography. The optimal temperature for the reaction of the CE-III on the 4 substrates ($\alpha$-Na, $\alpha$-Nb, $\beta$-Na and $\beta$-Nb) was confirmed at 4$0^{\circ}C$. The optimal pH for the reactions on the substrates $\alpha$-Na and $\alpha$-Nb was 7.5. But the optimal pH on the substrate $\beta$-Na and $\beta$-Nb was 8.0. The optimal substrate concentration for the reactions of the CE-III was 3.16 X 10$^{-3}$ M in $\alpha$-Na and $\beta$-Nb. On the substrate $\beta$-Na and $\alpha$-Nb, the optimal substrate concentration was 1.0 X 10$^{-3}$ M for CE-III. The $V_{max}$ and $K_{m}$ values of the carboxylesterases were varied by the substrates as followings: the $V_{max}$ of CE-III was 45.9 for $\alpha$-Na, 52.6 for $\beta$-Na, 36.4 for $\alpha$-Nb, and 83.3 ($\mu$ mol/min/mg protein) for $\beta$-Nb. The $K_{m}$ of CE-III was 1.43 X 10$^{-4}$ M for $\alpha$-Na, 3.57 x 10$^{-5}$ M for $\beta$-Na, 9.17 X 10$^{-5}$ M for $\alpha$-Nb, and 7.14 X 10$^{-5}$ M for $\beta$ -Nb, respectively. The CE-III seemed to have somewhat high thermostability considering that the temperature for effective denaturation on activity was about 5$0^{\circ}C$ ~ 6$0^{\circ}C$.EX>.EX>.

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Extraction of Taxol and Baccatin III from Needles of Taxus Cuspidata by Using Supercritical Carbon Dioxide with Cosolvents (초임계 이산화탄소와 보조용매를 이용한 주목잎에서의 Taxol과 Baccatin III의 추출)

  • 신혜원;전문균이훈
    • KSBB Journal
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    • v.11 no.1
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    • pp.100-106
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    • 1996
  • The extraction of taxol and baccatin III from the ground needles of Taxus cuspidata were carried out by using supercritical carbon dioxide with and without cosolvents such as ethylacetate and methanol at 300 bar and 313K. Taxol is a promising anticancer agent and baccatin III is a precursor of semisysthesis of taxol. The taxol and baccatin III contents in the extracts were determined by a HPLC. The highest yields of taxol and baccatin III could be obtained by the supercritical extraction with 3wt% methanol and ethylacetate, respectively, as cosolvents. It was also found that the selectivity of taxol and baccatin III were 0.117 and 1.245wt%, respectively, with 0.7wt% ethylacetate, which demonstrated that the selectivity of taxol and baccatin III were increased about 1.8 and 19 times than those of conventional organic solvent extraction.

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Solvent Extraction of Tb(III) from Chloride Solution using Organophosphorous Extractant, its Mixture and Ionic Liquids with Amines (염산용액에서 유기인산과 아민추출제의 혼합용매와 이온성액체에 의한 Tb(III)의 용매추출)

  • Oh, Chang Geun;Son, Seong Ho;Lee, Man Seung
    • Resources Recycling
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    • v.28 no.1
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    • pp.40-46
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    • 2019
  • The solvent extraction of Tb(III) from hydrochloric acid solution was investigated by employing single organophosphorus (D2EHPA, PC88A and Cyanex 272), its mixture with Alamine 336 and ionic liquids with Aliquat 336. The equilibrium pH after the extraction with extractant mixtures and ionic liquids was higher than that by single extractants. Among the mixtures and ionic liquids, only the ionic liquid with Cyanex 272 and Aliquat 336 showed synergism to the extraction of Tb(III). The extraction percentage of Tb(III) by the extractant mixtures was lower than that by single extractant and the extraction order was in the following order : D2EHPA + Alamine 336 > PC88A + Alamine 336 > Cyanex 272 + Alamine 336. The extraction order of Tb(III) by the ionic liquids was Cyanex 272 + Aliqaut 336 > PC88A + Aliquat 336 > D2EHPA + Aliquat 336.

The Comparison of Sintering Characteristics between the PVA-Al(III) Complex added $UO_2$Pellet and AlOOH added $UO_2$pellet (PVA-Al(III) 착물 첨가 $UO_2$소결체와 AlOOH 첨가 $UO_2$소결체의 소결 특성 비교)

  • Lee, Sin-Yeong;Yu, Ho-Sik;Lee, Seung-Jae;Kim, Hyeong-Su;Bae, Gi-Gwang
    • Korean Journal of Materials Research
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    • v.10 no.1
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    • pp.55-61
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    • 2000
  • The sintering characteristics of PVA-Al(III) complex added $UO_2$ pellet and AlOOH added $UO_2$pellet were compared. The major phase of PVA-Al(III) complex and AlOOH decomposed at $1000^{\circ}C$ in $H_2$atmosphere was $\theta-Al_2O_3$. Compared with the apparent density of pure $UO_2$, that of AlOOH added $UO_2$ powder was higher but that of PVA-Al(III) complex was lower. the densification of AlOOH added $UO_2$ pellet was initiated at about $800^{\circ}C$, the densification of PVA-Al(III) complex added $UO_2$ pellet was initiated at about $900^{\circ}C$ respectively. In a view of pore size distribution, the PVA-Al(III) complex added $UO_2$ pellet appeared as monomodal type, whereas the AlOOH added $UO_2$ pellet appeared as bimodal type. The grain size of AlOOH added $UO_2$ pellet was about $13\mu\textrm{m}$ but the grain size of PVA-Al(III) complex added $UO_2$ pellet was increased up to about $36\mu\textrm{m}$.

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Fire Risk Rating Evaluation of Organic Insulation Materials (유기 단열재의 화재위험성 등급 평가)

  • You, Ji Sun;Jeon, Nam;Chung, Yeong-jin
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.417-422
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    • 2021
  • In this study, poly isocyanurate foam (PIR), poly urethane foam (PUR), and phenol foam (PF) of organic insulation materials were selected, and investigated using a cone calorimeter, as per ISO 5660-1. Standard materials (PMMA) were used to standardize the fire hazard assessment, and the fire risk was classified and evaluated by Chung's equations-III and IV. The fire performance index-II value of Chung's equations-II was the highest value with PF of 14.77 s2/kW. And the PUR was 0.08 s2/kW, the lowest value of fire performance index-II value. The fire growth index-II value was the lowest value with PF of 0.01 kW/s2. And the PUR was 1.14 kW/s2, the highest value of fire growth index-II value. The fire performance index-III (FPI-III) of Chung's equations-III had the lowest value for PUR (0.11) and the highest for PF (20.23). The PUR showed the highest value of the fire growth index-III (FGI-III) as 14.25, while the PF exhibited 0.13 regarded as the safest materials. The fire risk index-IV (FRI-IV) value of Chung's equation-IV was in the following order: PUR (130.03) >> PIR (19.13) > PMMA (1.00) > PF (0.01). Therefore, it was concluded that the fire risk associated with PF is the lowest, whereas that associated with PUR is the highest.

CLINICAL AND RADIOGRAPHIC STUDY OF DENTIGEROUS CYSTS ACCORDING TO INVOLVED AREA (함치성 낭의 임상적 및 방사선적 특성)

  • Park, Seung-Youn;Nam, Dong-Woo;Kim, Young-Jin;Kim, Hyun-Jung;Nam, Soon-Hyeun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.2
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    • pp.169-179
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    • 2004
  • The purpose of this study was to discriminate clinically and radiographically among the three groups of dentigerous cysts studied. First, Group I, involved area of dentigerous cyst was successive permanent tooth area beneath deciduous tooth. Second, Group II, involved permanent molar area, and the last, Group III involved maxillary anterior supernumerary tooth area. The author observed and compared the clinico-radiographic features of 49 cases of Group I, 36 cases of Group II, and 15 cases of Group III of dentigerous cyst and this observation and comparison had been done by based on the charts and panoramic films. The obtained results were as follows: 1. The cases of Group I were 29 cases and, those of Group II were 36 and those of Group III were 15. 2. The incidence of dentigerous cyst is high in first decade. In Group I, before first decade and early first decade was 87.8%, in Group II and Group III, was discovered more lately. 3. The frequency of dentigerous cyst is 2.5 times higher in male than in female. 4. The sequence of chief complaint was swelling(50%), routine examination(32%), and pain(9%). 5. When considering the type of the cyst, lateral type is many most in Group I (71.4%) and central type is many most in Group II (94.4%) and Group III (100%). 6. The most size of dentigerous cyst was 2 crown size in Group I, 1 crown size in Group II, above of 4 crown size in Group III. 7. Almost involved teeth showed displacement and some tooth of displaced teeth showed delayed root development and dilaceration of root. 8. The most many response of alveolar bone was buccal bone expansion in Group I (67.3%), no bone expansion in Group II(66.7%) and palatal bone expansion in Group III (60.0%). 9. The percentage of involved teeth were as follows : The mandibular third molar was 31% and many most. The mandibular second premolar was 30%. Mesiodens of maxillary anterior area was 15%. The maxillary canine was 8%. The mandibular first premolar was 5%. 10. In the Group I, causes suggesting of dentigeous cyst are pulpotomized deciduous tooth(59.2%), severe dental caries of deciduous tooth, untreated traumatic history on the deciduous tooth etc. 11. The treatment method of dentigerous was marsupialization in 61.2% of cases of Group I and that was enucleation in 61.1% of cases of Group II and in 80.0% of cases of Group III.

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ON TATE-SHAFAREVICH GROUPS OVER CYCLIC EXTENSIONS

  • Yu, Ho-Seog
    • Honam Mathematical Journal
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    • v.32 no.1
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    • pp.45-51
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    • 2010
  • Let A be an abelian variety defined over a number field K and let L be a cyclic extension of K with Galois group G = <${\sigma}$> of order n. Let III(A/K) and III(A/L) denote, respectively, the Tate-Shafarevich groups of A over K and of A over L. Assume III(A/L) is finite. Let M(x) be a companion matrix of 1+x+${\cdots}$+$x^{n-1}$ and let $A^x$ be the twist of $A^{n-1}$ defined by $f^{-1}{\circ}f^{\sigma}$ = M(x) where $f:A^{n-1}{\rightarrow}A^x$ is an isomorphism defined over L. In this paper we compute [III(A/K)][III($A^x$/K)]/[III(A/L)] in terms of cohomology, where [X] is the order of an finite abelian group X.

Mn(III)-, Fe(III)-porphyrin Catalyzed Oxidation of cycloolefins (Mn(III)-, Fe(III)-porphyrin 유도체를 촉매제로 한 시클로올레핀 화합물의 산화반응)

  • Na, Hun-Gil;Park, Yu-Chul
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.2
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    • pp.41-48
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    • 1998
  • The catalytic oxidations of several cycloolefins in $CH_2Cl_2$ were been investigated using Mn(III)-, Fe(III)-porphyrin complexes as a catalyst and sodium hypochlorite as a terminal oxidant. Porphyrins were $(p-CH_3O)TTP,\;(p-CH_3)TTP,$ TPP, (p-F)TPP, (p-Cl)TPP and $(F_{20})TPP$ (TPP = tetraphenylporphyrin), and olefins were cyclopentene, cyclohexene and cycloheptene. The substrate conversion yield was discussed according to the substituent effects of metalloporphyrin. The conversion yield of substrate by changing the substituent of TPP increased in the order of $p-CH_3O$ < $p-CH_3$ < H < p-F < p-Cl, which was consistent with the sequence of $4{\sigma}$ values of TPP. The conversion of cycloalkene followed the order of $C_5\;<\;C_6\;<\;C_7$.

Validity of Runoff Curve Number Method for Estimating of Effective Rainfall (유효강우량 산정을 위한 곡선번호방법의 적용성)

  • 윤태훈
    • Water for future
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    • v.24 no.2
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    • pp.97-108
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    • 1991
  • A number of different curve numbers are estimated, and three of them are the basin or composite curve numbers (CN-II and CN-III) evaluated from hydrologic soil cover complex, the observed curve numbers computed from rainfal1-runoff observations and the basin median curve numbers as a median of the observed curve numbers. Based on the observed runoff, CM-II underestimates the effective rainfall meanwhile CN-III overestimates. Hence, for the improvement in estimating effective rainfall, a modulating curve number may be defined as a value in between CN-II and CN-III. Basin median curve numbers produces the closest result to the observed runoff and therefore it can be adopted as a representative curve number for gaged basin.

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