• 한국광학회지
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• 제2권3호
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• pp.121-126
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• 1991

칼날주사형 OTF 측정장치를 개선하여 비축상 OTF 측정 정확도를 향상시켰으며 SIRA 연구팀이 개발한 50mm 평면-볼록형 표준렌즈를 사용하여 OTF 측정장치의 성능을 평가하였다. 공간 주파수 0~100 cm / mm 영역에서 표준렌즈의 MTF 측정값은 극소수의 공간 주파수를 제외하고 축상에서 $\pm$0.02, 비축상에서 $\pm$0.03 이내에서 SIRA 측정값과 일치하였으며 PTF 측정값은 SIRA 측정값과 $\pm$$5^{\circ}$이내에서 일치하였다.

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3600-3604
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• 2010

Rhodium(III)-$Cp^*$ complexes containing labile ligands, $[Cp^*RhCl_2]_2$, [$Cp^*Rh({\eta}^2-NO_3)$(OTf)], and $[Cp^*Rh(OH_2)_3](OTf)_2$, reacted with potential linking ligands [$L^1$ = (2-thiophene)-CH=N-N=CH-(2-thiophene); $L^2$ = (2-furan)-CH=N-N=CH-(2-furan)] to give two molecular compounds, [$Cp^*Rh(L^1)Cl_2$] (1) and [$Cp^*Rh({\eta}^2-NO_3)(L^1)$]$(OTf){\cdot}CH_2Cl_2$ ($2{\cdot}CH_2Cl_2$), and one 1-dimensioanl coordination polymer, $\{[Rh(L^2)]{\cdot}(OTf)}_{\infty}$ (3). Whereas one imine nitrogen atom within the ligand is coordinated to the Rh metal in compounds 1 and 2, both nitrogen atoms are bound to two neighboring Rh metals in compound 3 to lead to a 1-D chain polymer.

• Bulletin of the Korean Chemical Society
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• 제23권1호
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• pp.132-136
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• 2002

$Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)\;(OTf=CF_3SO_3^-)$ readily reacts with various amines to afford cationic amine complexes $[Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(amine)](OTf)\;(amine=NH_3,\;NHMe_2,\;NHC_4H_8,\;NH_2Ph,\;NH_2(Tol-p))$ in high yields. These complexes have been fully characterized by IR, $^1H-,\;^{19}F{^1H}-,\;and\;^{31}P{^1H}-NMR$ spectroscopy, and elemental analyses. Reaction of $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)$ with acrylonitrile quantitatively produced the ${\pi}$-olefinic complex $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(CH_2=CHCN)](OTf)$ which is only stable in solution in the presence of acrylonitrile. Attempt at isolating this complex in the pure solid state was failed due to partial decomposition into $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)$ The equilibrium constants $(K_{eq}=[Pt(PCP)-(NH_2R)^+][CH_2=CHCN]/[Pt(PCP)(CH_2=CHCN)^+][NH_2R]:\;[Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(CH_2=CHCN)]^++NH_2R{\rightleftarrows}[Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(NH_2R)]^++CH_2=CHCN=Ph,\;p-tolyl)$ were calculated to be 0.28 (for R = Ph) and 3.1 (R = p-tolyl) at $21^{\circ}C$. The relative stability of the ${\sigma}$-donor amine versus the ${\pi}$-olefinic acrylonitrile complex has been found largely dependent upon the amine-basicity $(pK_b)$, implicating that acrylonitrile practically competes with amine in the platinum coordination sphere. On the contrary to the formation of the acrylonitrile complex, no reaction of $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)$ with other olefins such as ethylene, styrene and methyl acrylate was observed.

• 한국축산식품학회지
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• 제38권6호
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• pp.1226-1236
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• 2018

Ovotransferrin (OTF) is a well-known protein of the transferrin family with strong iron chelating activity, resulting in its antimicrobial activity. Furthermore, OTF is known to have antioxidant, anticancer, and antihypertensive activities. However, there have been few studies about the immune-enhancing activity of OTF. In current study, we investigated the immune-enhancing activity of OTF using the murine macrophage cells in vitro. The effect of OTF on production of pro-inflammatory mediators and cytokines were determined using Griess assay and quantitative real-time PCR. Using Neutral Red uptake assay, we confirmed the effect of OTF on phagocytic activity of macrophages. Ovotransferrin significantly increased the production of nitric oxide (NO) and secretion of inducible nitric oxide synthase (iNOS) mRNA with no cytotoxic activity. Ovotransferrin (2 mg/mL) stimulated NO production up to $31.9{\pm}3.5{\mu}M$. Ovotransferrin significantly increased the mRNA expression levels of pro-inflammatory cytokines which are tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$), Interleukin-$1{\beta}$ (IL-$1{\beta}$), and IL-6: OTF (2 mg/mL) treatment increased the secretion of mRNA for TNF-${\alpha}$, IL-$1{\beta}$, and IL-6 by 22.20-, 37.91-, and 6.17-fold of the negative control, respectively. The phagocytic activity of macrophages was also increased by OTF treatment significantly compared with negative control. Also, OTF treatment increased phosphorylation level of MAPK signaling pathways. These results indicated that OTF has immune-enhancing activity by activating RAW 264.7 macrophages via MAPK pathways.

• Journal of Astronomy and Space Sciences
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• 제23권3호
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• pp.269-288
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• 2006

We revised the OTFTOOL which was developed in Five College Radio Astronomy Observatory (FCRAO) for the On-The-Fly (OTF) observation. Besides the improvement of data resampling function of conventional OTFTOOL, we added a new SELF referencing mode and data pre-reduction function. Since OTF observation data have a large redundancy, we can choose and use only good quality samples excluding bad samples. Sorting out the bad samples is based on the floating level, rms level, antenna trajectory, elevation, $T_{sys}$, and number of samples. And, spikes are also removed. Referencing method can be chosen between CLASSICAL mode in which the references are taken from the OFFs observation and ELLIPSOIDAL mode in which the references are taken from the inner source free region (this is named as SELF reference). Baseline is subtracted with the source free channel windows and the baseline order chosen by the user. Passing through these procedures, the raw OTF data will be an FITS datacube. The revised-OTFTOOL maximizes the advantages of OTF observation by sorting out the bad samples in the earliest stage. And the new self-referencing method, the ELLIPSOIDAL mode, is very powerful to reduce the data. Moreover since it is possible to see the datacube at once without moving them into other data reduction programs, it is very useful and convenient to check whether the data resampling works well or not. We expect that the revised-OTFTOOL can be applied to the facilities of the OTF observation like SRAO, NRAO, and FCRAO.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.117-117
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• 2015

Availability of X-ray photoelectron spectroscopy (XPS) for the identification of ionic liquids (ILs) was tested. Commercially available ionic liquids (1-butyl-3-methyl imidazolium tetrafluoroborate ([BMIM] $BF_4$), (1-butyl-3-methyl imidazolium trifluoromethanesulfonate ([BMIM] OTf), (1-butyl-3-methyl imidazolium hexafluorophosphate ([BMIM] $PF_6$), 1-hexyl-3-imidazolium hexafluorophosphate ([HMIM] $PF_6$), and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM] $Tf_2N$) were qualitatively and semi-quantitatively analyzed with XPS. In order to confirm whether the results of XPS were correct, conventional method such as a nuclear magnetic resonance (NMR) was performed. After the XPS results were convinced by NMR, we synthesized ILs (1-(4-sulfonic acid) butyl-3-butylimidazolium trifluoromethanesulfonate ([SBBIM] OTf), 1-(4-sulfonic acid) propyl-3-methylimidazolium trifluoromethanesulfonate ([SPMIM] OTf), and 1-(4-sulfonic acid) propyl-3-butylimidazolium trifluoromethanesulfonate ([SPBIM] OTf) and analyzed it with XPS and NMR as well. It was successful the usage of XPS to analyze ILs without any purification processes.

• 한국측량학회지
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• 제18권3호
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• pp.271-278
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• 2000

최근 대형구조물의 거동 측정에 GPS를 활용하려는 시도가 부분적으로 이루어지고 있으나 초보적인 단계이며 체계적인 연구가 이루어지지 못하고 있는 실정이다. 본 연구에서는 GPS의 OTF(Kinematic On The Fly) 기법을 이용하여 교량의 거동을 측정하는데 그 목적이 있다. GPS의 실시간 동적 측위기법에 의하여 마포대교를 관측한 결과 수 센티미터 정도 발생하는 구조물의 거동을 3차원적으로 쉽고 편리하게 정밀 관측할 수 있으며 실시간으로 모니터링 할 수 있음을 알 수 있었다. 또한 본 연구에서는 OTF 측위기법을 적용, 초기화가 동적인 상태에서도 가능하도록 함으로써 신호의 단절시에도 연속적으로 교량의 거동을 관측할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제22권7호
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• pp.739-742
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• 2001

Reactions of [Cp*Ir(η3-CH2CHCHPh)(NCMe)]OTf (1) with HC≡CR (R = H, CH2OH) in the presence of bases, B (B=NEt3, PPh3, AsPh3) produce stable Cp*Ir-η3-allyl-alkenyl compounds [Cp*Ir(η3-CH2CHCHPh)(-CH=CH-+B)]OTf (2) and [Cp*Ir(η3-CH2CHCHPh)(-C(CH2OH)=CH- +PPh3)]OTf (3), respectively in high yields. Cp*Ir-η3-allyl-alkynyl compounds Cp*Ir(η3-CH2CHCHPh(-C≡C-R') (4) and Cp*(η3-CH2CHCHPh)Ir-C≡C-p-C6H4-C≡C-Ir(η3-CH2CHCHPh)Cp* (5) have been prepared from reactions of 1 with HC≡CR'(R' = C6H5, p-C6H4CH3, C3H5, C6H9) and HC≡C-p-C6H4-C≡CH in the presence of NEt3.

• Bulletin of the Korean Chemical Society
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• 제30권9호
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• pp.1989-1995
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• 2009

Efficient one-pot synthesis of arylmethylene bis(3-hydroxy-2-cyclohexene-1-ones) and xanthenediones by EDDA and In($OTf)_3$-catalyzed reactions was developed starting from dimedone and aryl aldehydes. The key strategies of these reactions involve domino Knoevenagel/Michael reaction or Koevenagel/Michael/Cyclodehydration reactions. The scope and limitation of the two catalysts under various reaction conditions were investigated and described.

• 천문학논총
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• 제20권1호
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• pp.73-83
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• 2005

On-The-Fly (OTF) observation method is developed for the efficient use of 6 M radio telescope at Seoul Radio Astronomy Observatory (SRAO). This technique, in which data and information of antenna position are recorded synchronously while driving a telescope regularly and rapidly across a field, provides more efficient use of telescope time and better calibration of the acquired data than the traditional point-to-point observation method does. For the realization of the method, we (1) added RT-Linux modules to the existing operating system, (2) replaced digital voltmeter with voltage-to-frequency converter, and (3) modified many SRAO observation programs. By observing Moon and G78.2+2.7 using this method and comparing them with previous observations, we verify the successful operation and efficiency of the OTF observation mode.