• Title/Summary/Keyword: In$(OTf)_{3}$

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Numerical calculation of contrast transfer function for periodic line-space patterns (주기적인 선물체에 대한 Contrast Transfer Function의 수치계산)

  • 김형수;전영세;이종웅;김성호
    • Korean Journal of Optics and Photonics
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    • v.9 no.6
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    • pp.396-402
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    • 1998
  • The measurement of OTF(optical transfer function) is used for evalution of imaging performance of optical system as a standard method. In the mass-production, the contrast measurement of projected patterns is also popular because of its simplicity. In this study, a computer program which evaluates the CTF(contrast transfer function) of optical system for periodic line-space patterns is developed by using the diffraction imaging theory. The MTF(modulation transfer function) and CTF of an aberrated system are evaluated and analyzed for the third order aberrations expressed by the C-coefficients and the Zemike polynomials.

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Improved Synthesis of the Tetrasaccharide Repeat Unit of the O-Antigen Polysaccharide from Escherichia coli O77

  • Lee, Bo-Young;Baek, Ju-Yuel;Jeon, Heung-Bae;Kim, Kwan-Soo
    • Bulletin of the Korean Chemical Society
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    • v.28 no.2
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    • pp.257-262
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    • 2007
  • The efficient synthesis of a tetrasaccharide, the suitably protected form of the repeat unit, →2)-α-D-Manp-(1→2)-β-D-Manp-(1→3)-α-D-GlcpNAc-(1→6)-α-D-Manp-(1→, of the O-antigen polysaccharide of the lipopolysaccharide from E. coli O77 has been accomplished. Glycosylation reactions for the coupling of four monosaccharide building blocks of the tetrasaccharide were carried out employing the CB glycoside method, the mannosyl 4-pentenoate/PhSeOTf method, and the glycosyl trichloroacetimidate method with complete stereoselectivities in excellent yields.

Efficient Implementation of Simeck Family Block Cipher on 8-Bit Processor

  • Park, Taehwan;Seo, Hwajeong;Bae, Bongjin;Kim, Howon
    • Journal of information and communication convergence engineering
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    • v.14 no.3
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    • pp.177-183
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    • 2016
  • A lot of Internet of Things devices has resource-restricted environment, so it is difficult to implement the existing block ciphers such as AES, PRESENT. By this reason, there are lightweight block ciphers, such as SIMON, SPECK, and Simeck, support various block/key sizes. These lightweight block ciphers can support the security on the IoT devices. In this paper, we propose efficient implementation methods and performance results for the Simeck family block cipher proposed in CHES 2015 on an 8-bit ATmega128-based STK600 board. The proposed methods can be adapted in the 8-bit microprocessor environment such as Arduino series which are one of famous devices for IoT application. The optimized on-the-fly (OTF) speed is on average 14.42 times faster and the optimized OTF memory is 1.53 times smaller than those obtained in the previous research. The speed-optimized encryption and the memory-optimized encryption are on average 12.98 times faster and 1.3 times smaller than those obtained in the previous studies, respectively.

Development of Interferometer for Performance Assessment of IR Optical System (적외선 광학계통 성능평가를 위한 간섭계 개발)

  • 홍경희;고재준;이성태;장세안;오명호
    • Korean Journal of Optics and Photonics
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    • v.2 no.4
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    • pp.179-185
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    • 1991
  • Twyman-Green interferometer is developed for assessment of IR optical system performance. Light source is $CO_2$ gas laser which has 10.6$\mu \textrm m$ wavelength. The light beam is expanded to 2.5 cm dia by Ge lens and splitted by ZnSe parallel plane plate. One of the beams is reflected by refernce mirror which is operated PZT. The fringe will be detected by a pyro-electric vidicon camera and displayed by a CRT monitor. Here, the IR firinge is recorded on the thermal paper. In visible region, the light source is He-Ne laser. The fringe is detected by a CCD camera and displayed by the CRT monitor. The intensity of the fringe is digitized by a image card and processed by a PC. The wavefront aberration function, PSF and OTF are calculated. The results are displayed in 3-D graphs on the monitor or printed out by a line printer.

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A Study on the Coast Topography using Real-Time Kinematics GPS and Echo Sounder

  • PARK WOON-YONG;KIM JIN-SOO;KIM CHEON-YEONG
    • Journal of Ocean Engineering and Technology
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    • v.17 no.3 s.52
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    • pp.13-20
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    • 2003
  • This research aims at investigation of accuracy potential of RTK(Real-Time Kinematic) GPS in combination with Echo Sounder(E/S) for the coastal mapping. Apart from this purpose, the accuracy of ambiguity resolution with the OTF(On The Fly) method was tested with respect to the initialization time. The result shows that the accuracy is better than 1cm with 5-minute initialization in the distance of 10km baseline. The seaside topography was measured by the RTK GPS only, on the other hand the seafloor topography was surveyed in combination of RTK GPS and E/S. Comparing to the volume of seaside measured by RTK GPS and digital topographical map, the difference of only $2\%$ was achieved. This indicates that the coastal mapping. As a result, it has been revealed that every possible noise in surveying could be corrected and the accuracy could be improved. The accuracy of GPS data acquired in real time was as good as that acquired by post processing. It is expected that it will be useful for the analysis of coastal geographic characteristics because DTM(Digital Terrain Model) can be also constructed for the harbor reclamation, the dredging, and the variation of soil movement in a river.

Efficient One-Pot Synthesis of Acridinediones by Indium(III) Triflate-Catalyzed Reactions of β-Enaminones, Aldehydes, and Cyclic 1,3-Dicarbonyls

  • To, Quang Huy;Lee, Yong-Rok;Kim, Sung-Hong
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1170-1176
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    • 2012
  • An efficient one-pot synthesis of acridinediones by $In(OTf)_3$-catalyzed reactions was developed starting from ${\beta}$-enaminones, aldehydes, and cyclic 1,3-diketones. The key strategies of these reactions involve domino Knoevenagel condensation/Michael addition/cyclodehydration reaction.

Esterification of Free Fatty Acids by Strong Acidic Ionic Liquids (강산성 이온성 액체에 의한 유리지방산의 에스테르화 연구)

  • Kim, Young-Joo;Lee, Jin-Suk;Kim, Deog-Keun;Rhee, Young-Woo;Han, Jeong-Sik
    • Korean Chemical Engineering Research
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    • v.45 no.3
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    • pp.286-290
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    • 2007
  • The esterification efficiency of several ionic liquids has been investigated to determine the feasibility for the conversion of free fatty acids to alkylester. Five ionic liquid catalysts having strong acidity, BPC[$AlCl_3$], BMIM[$Bf_4$], BMIM[$Pf_6$], EMIM[$Ntf_2$], BMIM[Otf], have been employed in this work. BPC[$AlCl_3$] has the highest esterification efficiency among the ionic liquid catalysts. Over 90% conversion efficiency has been achieved in the esterification of the simulated used cooking oil by BPC[$AlCl_3$] with two hours reaction time. Since BPC[$AlCl_3$] has several advantages such as high esterification activity, ease of separation from reaction mixture and reusability after treatment procedure, it will be a promising catalyst for the conversion of free fatty acids to esters in waste fats.

Synthesis of 2,5-Disubstituted Pyrrolidines from N-Alkenyl and Alkynyl N-Benzoyloxysulfonamides Catalyzed by (CuOTf)2・C6H6

  • Liu, Wei-Min;Liu, Zhen-Hong;Cheong, Wei-Wen;Priscilla, Lu-Yi Teo;Li, Yongxin;Narasaka, Koichi
    • Bulletin of the Korean Chemical Society
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    • v.31 no.3
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    • pp.563-569
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    • 2010
  • A new synthetic method of 2,5-disubstituted pyrrolidines is developed by the cyclization of unsaturated N-benzoyloxysulfonamides by $(CuOTf)_2{\cdot}C_6H_6$ in refluxing dichloroethane. Various N-4- and N-5-alkenyl and alkynyl N-benzoyloxysulfonamides are cyclized to give pyrrolidines. The cyclization proceeds via addition of sulfonamidoyl radicals to intramolecular unsaturated bonds or allylic hydrogen abstraction with the radical intermediates.

Preparation and Polymerization of Alkenylsilanes (Alkenylsilane의 제조와 고분자화반응)

  • Kim, Chung Kyun;Choi, Soon Kyu;Park, Eun Mi;Jung, In Kyung
    • Journal of the Korean Chemical Society
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    • v.41 no.2
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    • pp.88-97
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    • 1997
  • The silyltriflates$(Ph_{3-n}SiH(OTf)_n)$have been produced by the reaction of triphenylsilane and triflic acid$(CF_3SO_3H)$at low temperature. These highly reactive compounds are a valuable reagent for the synthesis of numerous new functional substituted silane derivatives. The reaction of silyltriflates with alkenyl- and alkynylmagnesium bromide as well as organolithium compounds gave new silanes$Ph_2SiHR(R=\;C(CPh,\;CH=CH_2,\;CH_2CH=CH_2,\; (CH_2)_2CH=CH_2,\;(CH_2)_3CH=CH_2)$in high yields. The hydrosilation of prepared alkenyl- and alkynylsilanesPh_2SiHR$in the presence of a platinum catalyst(Pt/C) at high temperature$(200{\circ}C)$gave carbosilane polymers$((Ph_2SiCH=CPh)_n$and$(Ph_2Si(CH_2)m)n;\;m=2∼4, n{\ge}10)$along with five- and six-membered silaalkane ring compounds derived from intramolecular hydrosilation reactions. All of the prepared compounds are confirmed by NMR, UV, IR and mass spectroscopy as well as elemental analysis.

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Characteristics of Ring-Opening Isomerization Polymerization of [4.3.0] Cyclic Pseudoureas ([4.3.0] 환상 유사 우레아의 이성화 개환중합과 특성평가)

  • Lee, Chan-Woo;Chung, Jin-Do
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.308-313
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    • 2011
  • The ring-opening isomerization polymerization behavior of 2,5,6,7-tetrahydro-3H-imidazo[2,1-b] [1,3] oxazine(TII) has been studied under various conditions. The present study aimed at improving the low polymerizability of the above monomer (six-membered ring) up to a level comparable to that of 2,5,6-tetrahydroimidazo[2,1-b] [l,3] oxazole(TIO) (five-membered ring). The optimum result could be observed when methyl trifluoromethanesulfonate(MeOTf) and nitrobenzene were used as an initiator and a solvent in the polymerization at $60^{\circ}C$ for 24 h. Polymers were confirmed by$^1H$ NMR과$^{13}C$ NMR, and m measurements. The molecular weight obtained by gel permeation chromatography (GPC) corresponded to the molecular weight theoretically calculated from the feed ratio. The melting temperature ($T_m$) of TII was conspicuously different from that of TIO, because of the difference in the alkyl group.