• Title/Summary/Keyword: Improved materials

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Densification of matrix graphite for spherical fuel elements used in molten salt reactor via addition of green pitch coke

  • He, Zhao;Zhao, Hongchao;Song, Jinliang;Guo, Xiaohui;Liu, Zhanjun;Zhong, Yajuan;Marrow, T. James
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1161-1166
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    • 2022
  • Green pitch coke with an average particle size of 2 mm was adopted as densifier and added to the raw materials of conventional A3-3 matrix graphite (MG) to prepare modified A3-3 matrix graphite (MMG) by the quasi-isostatic molding method. The structure, mechanical and thermal properties were assessed. Compared with MG, MMG had a more compact structure, and exhibited improved properties of higher mechanical strength, higher thermal conductivity and better molten salt barrier performance. Notably, under the same infiltration pressure of 5 atm, the fluoride salt occupation of MMG was only 0.26 wt%, whereas it was 15.82 wt% for MG. The densification effect of green pitch coke endowed MMG with improved properties for potential use in the spherical fuel elements of molten salt reactor.

Effect of Multi-functional Group of Acrylate Crosslinker on Properties of Waterborne Polyurethane-acrylate

  • Moon, Seok Kyu;Kim, Eun-jin;Kwon, Yong Rok;Kim, Jung Soo;Kim, Hae Chan;Park, Han Soo;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.57 no.3
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    • pp.100-106
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    • 2022
  • Waterborne polyurethane-acrylate(WPUA) dispersions were prepared by surfactant-free emulsion polymerization in a two-step process. In the first step, polytetrahydrofuran, isophorone diisocyanate, dimethylol proponic acid, and 2-hydroxyethyl methacrylate were used to synthesize a vinyl-terminated polyurethane prepolymer. In the second step, styrene, methyl methacrylate, butyl acrylate, and different multi-functional crosslinkers were copolymerized. 1,6-hexanediol diacrylate, trimethylolpropane triacrylate, and pentaerythritol tetraacrylate were used as the crosslinkers, and their effect on the mechanical and thermal properties of WPUA was investigated. Overall, as the number of functional groups of the cross-linker increased, the gel fraction improved to 79.26%, the particle size increased from 75.9 nm to 148.7 nm, and the tensile strength was improved from 5.86 MPa to 12.40 MPa. In thermal properties, the glass transition temperature and decomposition temperature increased by 9.9℃ and 18℃, respectively. The chemical structures of the WPUA dispersions were characterized by Fourier-transform infrared spectroscopy. The synthesized WPUA has high potential for applications such as coatings, leather coatings, adhesives, and wood finishing.

Factors Affecting the Design of Brake Disc (제동 디스크 설계를 위한 고려 인자 고찰)

  • Kim, Jeong-Guk;Goo, Byeong-Choon;Kwon, Sung-Tae
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.798-803
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    • 2007
  • The brake system of railway plays an important role to enhance the speed of train, and the brake disc is one of major components relating to frictional braking. The performance enhancement of brake disc directly affects the braking performance of train. It is required to understand and investigate the factors need to be considered for the development of new brake disc with improved materials and performance. In this study, through the literature reviews of previous study, several factors including thermal crack phenomena, friction coefficient, materials and durability of disc, temperature characteristics, etc., were introduced for the design of improved brake disc. Moreover, based on the review results, the design direction of new brake disc was suggested. Eventually, a new brake disc with improved performance would be developed based on this investigation.

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Design of a Broad-band Electromagnetic Absorber Using the Improved Partial Initialization Genetic Algorithm (개선된 부분 초기화 유전자 앨거리즘을 이용한 광대역 전파 흡수체 최적 설계)

  • 이동근;남기진;이상설
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.11 no.2
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    • pp.177-185
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    • 2000
  • The broadband EM absorbers composed of dielectrics and magnetic materials are designed. The performance of the partial initialization genetic algorithm(PIGA) is improved with three factors such as partial initialization ratios, initialization starting points and scale factors. At the frequency range over 3∼10 GHz, the optimized electromagnetic absorbers designed by using the improved PIGA. The design results obtained by enhanced PIGA's are superior to that of the using GA presented by E. Michielssen with regard to the total depth of composite materials, the depth of magnetics and maximum reflection coefficients.

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Mechanical Characteristic Evaluation of Proper Material for Ultra-fine Dies (초소형 금형소재의 기계적 특성평가)

  • KANG Jae-hoon;LEE Hyun-yong;LEE Nak-kyu
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.473-476
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    • 2005
  • Today's manufacturing industry is facing challenges from advanced difficult-to-machine materials (WC-Co alloys, ceramics, and composites), stringent design requirements (high precision, complex shapes, and high surface quality), and machining costs. Advanced materials play an increasingly important role in modem manufacturing industries, especially, in aircraft, automobile, tool, die and mold making industries. The greatly-improved thermal, chemical, and mechanical properties of the material (such as improved strength, heat resistance, wear resistance, and corrosion resistance), while having yielded enormous economic benefits to manufacturing industries through improved product performance and product design, are making traditional machining processes unable to machine them or unable to machine them economically. In this paper, mechanical characteristic evaluation test of fine powder type WC-Co alloy was accomplished to obtain clear data for miniaturized special die parts machining with high reliability and high quality.

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Synthesis and Characterization of Graphene Based Unsaturated Polyester Resin Composites

  • Swain, Sarojini
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.2
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    • pp.53-58
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    • 2013
  • Graphene-based polymer nanocomposites are very promising candidates for new high-performance materials that offer improved mechanical, barrier, thermal and electrical properties. Herein, an approach is presented to improve the mechanical, thermal and electrical properties of unsaturated polyester resin (UPR) by using graphene nano sheets (GNS). The extent of dispersion of GNS into the polymer matrix was also observed by using the scanning electron microscopy (SEM) which indicated homogeneous dispersion of GNS through the UPR matrix and strong interfacial adhesion between the GNS and UPR matrix were achieved in the UPR composite, which enhanced the mechanical properties. The tensile strength of the nanocomposites improved at a tune of 52% at a GNS concentration of 0.05%. Again the flexural strength also increased around 92% at a GNS concentration of 0.05%. Similarly the thermal properties and the electrical properties for the nanocomposites were also improved as evidenced from the differential scanning caloriemetry (DSC) and dielectric strength measurement.

An Experimental Study on the Neutralization of High-Flowable Concrete (고유동콘크리트의 중성화에 관한 실험적 연구)

  • Jeon, Hyun-Kyu;Lim, Jin-Kyu;Seo, Chee-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.3 no.3
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    • pp.177-185
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    • 1999
  • In this study, study about fly ash and blast-furnace slag used as substitutive materials for cement, and the influence on the neutralization of high flow concrete durability with these substitutive materials was performed and analyzed. The results are as follows 1) Aggregate segregation was partially improved with the progress of the admixture input at the mix proportion above slump flow 65 cm 2) Compressive strength with the progress of the increasement of fly ash input was decreased in early age, but decrease range was improved in long term age. Also, in case of blast-furnace, similar or improved compressive strength was appeared. 3) The neutralization depth with fly ash input was noticeably increased. But blast-furnace slag was effective to prevent. 4) In this experiment, high powder content was advantageously affected on preventive effect of the neutralization, and the relationship between the compressive strength and the neutralization depth was inversely proportional.

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Improvement in LED structure for enhanced light-emission

  • Park, Seong-Ju
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.21-21
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    • 2003
  • To increase the light-emission efficiency of LED, we increased the internal and external quantum efficiency by suppressing the defect formation in the quantum well and by increasing the light extraction efficiency in LED, respectively. First, the internal quantum efficiency was improved by investigating the effect of a low temperature (LT) grown p-GaN layer on the In$\sub$0.25/GaN/GaN MQW in green LED. The properties of p-GaN was optimized at a low growth temperature of 900oC. A green LED using the optimized LT p-type GaN clearly showed the elimination of blue-shift which is originated by the MQW damage due to the high temperature growth process. This result was attributed to the suppression of indium inter-diffusion in MQW layer as evidenced by XRD and HR-TEM analysis. Secondly, we improved the light-extraction efficiency of LED. In spite of high internal quantum efficiency of GaN-based LED, the external quantum efficiency is still low due to the total internal reflection of the light at the semiconductor-air interface. To improve the probability of escaping the photons outside from the LED structure, we fabricated nano-sized cavities on a p-GaN surface utilizing Pt self-assembled metal clusters as an etch mask. Electroluminescence measurement showed that the relative optical output power was increased up to 80% compared to that of LED without nano-sized cavities. I-V measurement also showed that the electrical performance was improved. The enhanced LED performance was attributed to the enhancement of light escaping probability and the decrease of resistance due to the increase in contact area.

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Enhancement of Dielectric Properties of Polyamide Enamel Insulation in High Voltage Apparatuses Used in Medical Electronics by Adding Nano Composites of SiO2 and Al2O3 Fillers

  • Biju, A.C.;Victoire, T. Aruldoss Albert;Selvaraj, D. Edison
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1712-1719
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    • 2015
  • In recent days, there was a significant development on the electrical, thermal, mechanical, physical, chemical, magnetic and optical properties of the polyamide enamel, varnish and other insulating materials by the addition of nano fillers to it. Enamel was used in High Voltage Apparatuses used in Medical Electronics as insulation. Insulating materials determine the life time of the electrical apparatuses. The life time of the insulating materials was improved by the addition of nano fillers to it. Hence the life time of the electrical apparatuses was improved by the mixing of nano fillers to the enamel. In this research, the basic dielectric properties of the enamel and enamel mixed with nano composites of silica and alumina were analyzed and compared with each other. The addition of nano fillers has improved the quality factor and capacitance of the enamel. It was also observed that the addition of nano fillers has reduced the dissipation factor and dielectric losses of the enamel. Heat produced by the dielectric losses was also reduced by adding nano fillers to it.