• Title/Summary/Keyword: Improved PD

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Effect of Ultrasonic Agitation on Pd Catalyst Treatment (파라듐 촉매화 처리에 미치는 초음파 교반의 영향)

  • 김동규;이홍로;추현식
    • Journal of the Korean institute of surface engineering
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    • v.34 no.6
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    • pp.545-552
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    • 2001
  • Effect of ultrasonic agitation on Pd catalyst treatment was studied in metallization of ceramic boards by Cu electroless plating method.96% $Al_{2}$$O_{3}$ ceramic boards were used as substrate. In this study, the ultrasonic frequency of 28kHz was applied. In Pd catalyst, high density Pd nuclei of small size were formed during ultrasonic agitation. Density of Pd was more improved when using of ultrasonic then no stirring. In electroless plating, plating rate was in the range of 0.6~1.8$\mu\textrm{m}$/hr, which value increased with Rochelle Salts addition. Adhesion strength between ceramic boards and Cu layer was improved of 20% when using ultrasonic agitation at $30^{\circ}C$ ,5min.

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A Study of Partial Oxidation of Methane by Pd Catalyst - Effects of Reaction Temperature - (팔라듐 촉매의 메탄 부분산화에 관한 연구 - 반응온도에 따른 효과 -)

  • Lee, Taek-Hong;Mun, Yeong-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.3
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    • pp.244-249
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    • 2004
  • Pd catalyst have been used in hydrogenation, oxidation, and low temperature combustion reaction. Recently, it has been candidated as a possible reagents in the partial oxidation of methanol reformers of the fuel cell. Pd catalysts, even though it is very precious and expensive, catalytic functioning is good, but it still need to be improved in the matter of durability and low catalytic activity after calcination. In this study, we synthesize the improved Pd catalyst and study their chemical functioning.

Effect on the Sensitivity of a Hydrogen Sensor by Pd Electrode Patterns at High Temperature (고온에서 Pd 전극의 형태가 수소 센서의 감도에 미치는 영향)

  • Kim, Seong-Jeen
    • Journal of IKEEE
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    • v.22 no.2
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    • pp.356-361
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    • 2018
  • We investigated a hydrogen gas sensor which is available in a high temperature atmosphere. The hydrogen sensors were fabricated into a metal-oxide-semiconductor (MOS) structure made of $Pd/Ta_2O_5/SiC$, and the thin tantalum oxide ($Ta_2O_5$) layer was fabricated by rapid thermal oxidation (RTO). In the experiment, we made three types of sensors with different palladium (Pd) patterns to evaluate the effect of Pd electrode on response characteristics. As the result, the response characteristics in capacitance were improved further when the filled area of the Pd electrode became larger.

Corrosion Behavior of Ti-Pd System Alloys by Microstructural changes (Ti-Pd계 합금의 미세조직변화에 따른 부식거동)

  • Cha, Sung-Soo;Kwak, Dong-Ju;Nam, Sang-Yong
    • Journal of Technologic Dentistry
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    • v.30 no.2
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    • pp.9-16
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    • 2008
  • The surface microstructural changes, mechanical properties and corrosion resistance of Ti-Pd alloys for dental biomaterials have been investigated. Ti, Ti-Pd alloys were melted in arc furnace and the corrosion resistance of Ti-Pd alloys was evaluated by anodic polarization test. The surface microstructural changes and mechanical properties of Ti-Pd alloys were analysed by scanning electron microscope and Vickers micro-hardness tester. The vickers hardnees of pure Ti improved by addition of Pd but Ti-25Pd alloy showed decreasing compared with Ti-15Pd. And anodic polarization and potentiostatic test were conducted in 5% HCl to quantify the resistance to corrosion with the addition of Pd, There was no significant difference in corrosion resistance between pure Ti, Ti-5Pd and Ti-15Pd alloy. However, Ti-25Pd alloy showed decreasing compared with pure Ti in corrosion resistance. From these results, it was concluded that newly formulated Ti-15Pd experimental alloy have adequate hardness and high corrosion resistance, and this alloy is promising candidate for a successful dental casting alloy.

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Improved single crystal growth methods for oxide materials by MBE, LPE and $\mu$ - PD techniques (MBE, LPE와 $\mu$ - PD 기술에 의한 산화물재료의 개선된 단결정 성장방법)

  • ;Masahito Yoshizawa
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.4
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    • pp.378-385
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    • 1995
  • The growth processes of improved methods for MBE, LPE and $\mu$ - PD methods are discussed taking the oxide materials, especially those of Bi - Sr - Ca - Cu family $LiNbO_3$ and $K_3Li_2Nb_5O_{15}$ family as examples. It is suggested that the crystal growth far from equilibr iu m including composition homogeneity has been achieved to satisfy in understanding and controlling the atomic interfaces.

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A Study of Combustion Reaction of Methane by Pd Catalyst - Effects of Support Size & Calcination Temperature - (팔라듐 촉매의 메탄의 연소반응에 관한 연구 -담체의 크기와 소성온도에 따른 효과-)

  • Lee Taeck Hong
    • Journal of the Korean Institute of Gas
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    • v.8 no.3 s.24
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    • pp.52-56
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    • 2004
  • Pd catalyst have been used in hydrogenation, oxidation, and low temperature combustion reaction. Recently, it is candidated as a possible reagents in the partial oxidation of methanol reformers of the fuel cell. Pd catalysts, even though it is very precious and expensive, catalytic functioning is good, but it still need to be improved in the matter of durability and low catalytic activity after calcination. In this study, we synthesize the improved Pd catalyst and study their chemical functioning.

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Implementation of Balancing Control System for Two Wheeled Inverted Pendulum Robot (이륜 역진자 로봇의 밸런싱 제어시스템 구현)

  • An, Tae-Hee;Park, Jin-Hyun;Choi, Young-Kiu
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.16 no.3
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    • pp.432-439
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    • 2012
  • In this paper, instead of the conventional PD controller for balancing control of two wheeled inverted pendulum robots, an improved PD controller using the neural network is proposed and implemented for performance verification. First, a two wheeled inverted pendulum robot system is constructed for experiment. Next proper gains of the conventional PD controller according to users' weights are obtained for balancing the robot by use of the trial and error method. The PD gains based on the trial and error method are generalized through the neural network. Experiment results show that the PD controller based on the neural network has better performance than the conventional PD controller.

An Optimal Tuning of PI-PD Controller Via LQR (LQR을 사용한 최적 PI-PD제어기 동조)

  • Kang, Keun-Hyoung;Suh, Byung-Suhl
    • Proceedings of the KIEE Conference
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    • 2005.05a
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    • pp.109-112
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    • 2005
  • This paper presents an optimal and robust PI-PD controller design method for the second-order systems both with dead time and without dead time to satisfy the design specifications in the time domain via LQR design technique. The optimal tuning method of PI-PD controller are also developed by setpoint weighting and neural networks. It is shown that the simulation results show significantly improved performance by proposed method.

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Competitive Enzyme-Linked Immunosorbent Assay for Glucose-6-Phosphate Dehydrogenase

  • Kim, Moon-Hee
    • BMB Reports
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    • v.30 no.5
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    • pp.326-331
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    • 1997
  • To construct a competitive ELISA standard curve for the detection of glucose-6-phosphate debydrogenase (G6PD), we used highly purified native G6PD (nG6PD) as both immobilized and soluble antigens and anti-G6PD serum raised against nG6PD as antibody. The polystyrene cuvettes coated with nG6PD were challenged with a mixture of a limiting amount of anti-G6PD serum and various doses of nG6PD as competitors followed by incubation with alkaline phosphatase-anti-IgG conjugate. The competitive ELISA did not exhibit the typical sigmoidal dose-response curve characteristic of competition immunoassays under the optimal concentrations of antigen and antibody. The soluble nG6PD used as competitor failed to effectively inhibit the binding of antibodies to the immobilized nG6PD. The addition of NADP, a cofactor of G6PD enzyme, to coating buffer used for immobilizing nG6PD to the cuvettes and PBS-Tween-BSA buffer for diluting competitors did not improve the inhibition of antibody binding to immobilized nG6PD by soluble n/G6PD. The addition of BSA to coating buffer did not increase inhibition, either. Surprisingly, when partially active G6PD (paG6PD), obtained by repeated freeze-thawing, was used as competitor, the antibody binding to either immobilized nG6PD or immobilized paG6PD was inhibited 49-58%. We conclude that an effective competitive ELISA system with nG6PD enzyme and anti-G6PD serum for the detection of G6PD may not be established due to the poor inhibition of antibody binding to immobilized nG6PD by soluble nG6PD under the present assay conditions and that the inhibition may be improved by using an inactivated enzyme as competitor regardless of the type of immobilized antigen used. These results imply that the immobilized nG6PD may undergo denaturation upon binding to the polystyrene cuvettes and that our anti-G6PD serum may recognize denatured enzyme better than active enzyme.

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A Study on Control Characteristics of Translation System Using PD Control and LQR (PD제어와 LQR을 이용한 병진 시스템의 제어특성 연구)

  • 김택현;정상화;이동하
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.10 no.5
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    • pp.78-84
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    • 2001
  • The translation system is made up of springs, masses and a dashpot. This precise piece of equipment is controlled electro-mechanically by a motor and operating program. The control strategy of the system can be changed by spring stiffness, change of mass, and the damping coefficient of the dashpot. This system proves the necessity and effect of a closed loop control. In this paper, PD control experiments were implemented for the translation system. When the north falter was added on the PD controller, we compared the response characteristics of the two systems. The state feedback controller minimized scalar control gains and the resulting response characteristics of the system were studied using the LQR design. Finally, we improved the response characteristics of the translation system which are rising time, settling time, steady state error, and overshoot LQR was better as compared with PD control.

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