• 한국수소및신에너지학회논문집
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• 제25권1호
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• pp.19-27
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• 2014

Mg hydride has a high hydrogen capacity (7.6%), at high temperature, and is a lightweight and low cost material, thus it a promising hydrogen storage material. However, its high operation temperature and very slow reaction kinetics are obstacles to practical application. In order to overcome these disadvantages of Mg hydride, graphene powder was added to it. The addition of graphene has been shown to reduce the operating temperature of dehydrogenation. Moreover, in this report the environmental aspects of $MgH_x$-Graphene composites are investigated by means of the environmental life cycle assessment (LCA) method. $MgH_x$-Graphene mixture was prepared by hydrogen induced mechanical alloy (HIMA). The synthesized powder was characterized by XRD(X-ray Diffraction). The hydrogenation behaviors were evaluated by using a Sievert's type automatic PCT apparatus. Such evaluation of Materials also conducted in the LCA. From the result of P-C-T(Pressure-Composition-Temperature) curves, the $MgH_x$-3wt.% graphene composite was evaluated as having a 5.86wt.% maximum hydrogen storage capacity, at 523K. From absorption kinetic testing, the $MgH_x$-7wt.% graphene composite was evaluated as having a maximum 6.94wt.%/ms hydrogen absorption rate, at 573K. Environment evaluation results for the $MgH_x$-graphene composites and other materials indicated environmental impact from the electric power used and from the materials themselves.

• 한국인터넷방송통신학회논문지
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• 제18권2호
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• pp.217-226
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• 2018

차량의 측면은 전면이나 후면과 다르게 비대칭으로 설계되어있기 때문에 측면충돌이 일어나는 경우 충돌부위에 따라 차체의 변형정도가 크게 달라진다. 충돌로 인하여 차체에 탄성 및 소성 변형이 일어날 때 운동에너지가 차체로 흡수되어 운동량이 감소하게 된다. 일반적으로 교통사고분석은 충돌 후 차량의 거동을 운동량 보존법칙으로 분석하며 차체의 변형에 따른 에너지 흡수량은 반발계수를 적용해 그 오차를 보정한다. 본 연구에서는 차체의 구조와 각 부품의 재료특성을 적용한 유한요소 차량모델을 LS-DYNA로 해석하였으며, 그 결과를 분석하여 SUV와 승용차의 측면충돌에서 차량의 접촉부위에 따른 반발계수와 충돌감지시간을 도출하였다. 최종적으로 산출된 반발계수와 충돌감지시간을 실제 교통사고 사례에 적용하였을 때 결과오차의 개선효과를 얻었다. 유한요소해석 모델을 이용하여 도출한 초기 입력값을 적용했을 때 기존의 분석기법보다 해석의 신뢰도가 높다는 결과를 얻게 되었다.

• 한국구조물진단유지관리공학회 논문집
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• 제22권3호
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• pp.31-37
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• 2018

이 논문은 압축강도 수준(100, 140, 180 MPa급)에 따른 HPFRCC의 동적충격 인장강도를 평가하였다. 먼저 100, 140, 180 MPa급 HPFRCC의 압축응력-변형률 관계를 분석한 결과 압축강도는 각각 112, 150, 202 MPa로 나타났으며, 압축강도가 높아짐에 따라 탄성계수도 증가하는 경향을 나타내었다. 100, 140, 180 MPa급 HPFRCC의 정적 인장강도는 각각 10.7, 11.5, 16.5 MPa로 나타났으며, 압축강도가 높아질수록 인장강도도 증가하는 경향을 나타내었다. 반면 100 및 140 MPa급 HPFRCC에서의 인장강도 및 에너지 흡수능력은 압축강도 수준에 따라 큰 차이를 보이지 않았다. 이는 시험체의 규격 및 강섬유의 배열에 영향을 받은 것으로 판단된다. HPFRCC의 동적충격 인장강도를 평가한 결과, 변형률 속도가 10-1/s에서 150/s로 증가할수록 모든 HPFRCC의 인장강도와 동적증가계수는 증가하는 경향을 보였다. 한편 동일한 범위의 변형률 속도에서 HPFRCC의 압축강도가 낮을수록 인장강도에 대한 DIF가 높게 측정되어 효율적인 측면에서는 100 MPa급 HPFRCC가 가장 우수한 것으로 나타났다. 따라서 높은 수준의 인장성능이 요구되는 경우 높은 압축강도를 가지는 HPFRCC를 사용하는 것이 유리하며, 폭발과 같은 고속변형률 속도에서 보다 효율적인 접근을 위해서는 목표 압축강도에 근접한 HPFRCC를 사용하는 것이 바람직한 것으로 판단된다.

• Structural Engineering and Mechanics
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• 제67권4호
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• pp.347-358
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• 2018

The main aim of this research was to investigate the shear strength of non-prismatic steel fiber reinforced concrete beams under monotonic loading considering different parameters. Experimental program included tests on fifteen non-prismatic reinforced concrete beams divided into three groups. For the first and the second groups, different parameters were taken into consideration which are: steel fibers content, shear span to minimum depth ratio ($a/d_{min}$) and tapering angle (${\alpha}$). The third group was designed mainly to optimize the geometry of the non-prismatic concrete beams with the same concrete volume while the steel fiber ratio and the shear span were left constant in this group. The presence of steel fibers in concrete led to an increase in the load-carrying capacity in a range of 10.25%-103%. Also, the energy absorption capacity was increased due to the addition of steel fibers in a range of 18.17%-993.18% and the failure mode was changed from brittle to ductile. Tapering angle had a clear effect on the shear strength of test specimens. The increase in tapering angle from ($7^{\circ}$) to ($12^{\circ}$) caused an increase in the ultimate shear capacity for the test specimens. The maximum increase in ultimate load was 45.49%. The addition of steel fibers had a significant impact on the post-cracking behavior of the test specimens. Empirical equation for shear strength prediction at cracking limit state was proposed. The predicted cracking shear strength was in good agreement with the experimental findings.

• Structural Engineering and Mechanics
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• 제57권3호
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• pp.507-528
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• 2016

Reduced beam section (RBS) moment resisting connections are among the most economical and practical rigid steel connections developed in the aftermath of the 1994 Northridge and the 1995 Kobe earthquakes. Although the performance of RBS connection has been widely studied, this connection has not been subject to in the skewed conditions. In this study, the seismic performance of dogbone connection was investigated at different angles. The Commercial ABAQUS software was used to simulate the samples. The numerical results are first compared with experimental results to verify the accuracy. Nonlinear static analysis with von Mises yield criterion materials and the finite elements method were used to analyze the behavior of the samples The selected Hardening Strain of materials at cyclic loading and monotonic loading were kinematics and isotropic respectively The results show that in addition to reverse twisting of columns, change in beam angle relative to the central axis of the column has little impact on hysteresis response of samples. Any increase in the angle, leads to increased non-elastic resistance. As for Weak panel zone, with increase of the angle between the beam and the column, the initial submission will take place at a later time and at a larger rotation angle in the panel zone and this represents reduced amount of perpendicular force exerted on the column flange. In balanced and strong panel zones, with increase in the angle between the beam and the central axis of the column, the reduced beam section (RBS), reaches the failure limit faster and at a lower rotation angle. In connection of skewed beam, balanced panel zone, due to its good performance in disposition of plasticity process away from connection points and high energy absorption, is the best choice for panel zone. The ratio of maximum moment developed on the column was found to be within 0.84 to 1 plastic anchor point, which shows prevention of brittle fracture in connections.

• 한국대기환경학회지
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• 제25권4호
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• pp.325-338
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• 2009

National parks provide recreation, health, and science to human being. The provision of beautiful landscape view of the national park improves an economic and social phase of a nation. However, visibility impairment frequently occurred in the national park area of Gyeongju. The purpose of this study is to investigate the physical and the chemical characteristics of visibility reduction observed at the national park area of Gyeongju. Optical, chemical, meteorological characteristics and scenic monitoring were performed at the visibility monitoring station of Gyeongju University located at the Seoak section of Gyeongju national park from April 28 to May 9, 2008. Light extinction, light scattering, and light absorption coefficients were continuously measured using a transmissometer, a nephelometer, and an aethalometer, respectively. In order to investigate the impact of aerosol chemistry on visibility impairment, size-resolved aerosols were collected at intervals of 2-hour (from 8 A.M. to 6 P.M.) and 14-hour (from 6 P.M. to 8 A.M.) interval each sampling day. The average light extinction coefficient and the average visual range were measured to be $270{\pm}135\;Mm^{-1}$ and $14.5{\pm}6.3\;km$ during the intensive monitoring period, respectively. It was revealed that sulfate particle was the largest contributor to the light extinction under hazy condition. Organic mass accounted for about 26% of the average light extinction. The mass extinction efficiencies for $PM_{1.0}$, $PM_{2.5}$, and $PM_{10}$ were estimated to be 9.0, 4.7, and $2.7\;m^2\;g^{-1}$ under the consideration of water growth function of hygroscopic aerosols, respectively.

• 보존과학회지
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• 제26권2호
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• pp.133-142
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• 2010

태안 마도 출토 도자기를 대상으로 도자기 탈염에 일반적으로 사용되는 물 세척법에 추가조건(탈염수 양, 교반 및 온도)을 적용하여 탈염효율을 비교 연구하였다. 탈염수 양에 따른 효율실험결과 질량비 20배가 질량비 10배보다 효율은 높았지만, 그 정도가 2배에 미치지 못하여 경제적 측면에서 질량비 10배가 보다 효율적이었다. 또한 탈염처리 중 교반 및 가온에 따라 20~30%의 효율증대는 확인되었지만, 추가기법적용을 위한 에너지사용과 물리화학적 충격에 의한 유물손상의 위해성을 종합적으로 고려한다면 교반 및 가온에 따른 효율증대는 크지 않은 것으로 판단된다.

• 대한토목학회논문집
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• 제31권6A호
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• pp.425-433
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• 2011

본 연구에서는 파랑하중에 의해 부유구조체 하면에서 발생하는 파압 현상을 규명하기 위한 실험적 연구를 수행하였다. 서로 다른 측면 형상과 하면 형상을 갖는 4개의 폰툰형 시험체를 제작하여 5 종류 파랑하중에 대한 수리모형실험을 실시하였다. 시험체의 하면에는 6개의 파압센서를 설치하였으며, 수리모형실험 동안 시험체 하면에 작용하는 파압을 측정하였다. 측정된 파압을 분석한 결과, 와플형의 하면 형상은 부유구조체 하면에 작용하는 파압에 거의 영향을 미치지 않으며, 하이브리드형의 측면 형상은 파압에 상당한 영향을 미치는 것으로 나타났다. 이것은 하이브리드형의 측면에 형성된 에어갭(Airgap)이 부유구조체에 작용하는 파랑의 충격 에너지를 일부 흡수하여 파압을 저감시키는데 기여하는 것으로 판단된다. 기존의 상자형 폰툰과 비교하였을 때 하이브리드형의 파압은 선수부에서 약 83%, 중간부에서 약 74% 및 선미부에서 약 53% 수준인 것으로 나타났다.

• Journal of Pharmaceutical Investigation
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• 제34권6호
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• pp.443-452
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• 2004

Habit is the description of the outer appearance of a crystal. If the environment of a growing crystal affects its external shape without changing its internal structure, a different habit results. Crystal habit and the internal structure of a drug can affect bulk and physicochemical properties, which range from flowability to chemical stability. A polymorph is a solid crystalline phase of a given compound resulting from the possibility of at least two different arrangements of the molecules of that compound in the solid state. Chemical stability and solubility changes due to polymorphism can have an impact on a drug's bioavailability and its development program. During crystallization from a solution, crystals separating may consist of a pure component or be a molecular compound. Solvates are molecular complexes that have incorporated the crystallizing solvent molecule in their lattice. When the solvent incorporated in the solvate is water, it is called a hydrate. To distinguish solvates from polymorphs, which are not molecular compounds, the term pseudopolymorph is used. Identification of possible hydrate compounds is important since their aqueous solubilities can be significantly less than their anhydrous forms. Conversion of an anhydrous compound to a hydrate within the dosage form may reduce the dissolution rate and extent of drug absorption. An amorphous solid may be treated as a supercooled liquid in which the arrangement of molecules is random. Amorphous solids lack the three-dimensional long-range order found in crystalline solids. Since amorphous forms are usually of higher thermodynamic energy than corresponding crystalline forms, solubilities as well as dissolution rates are generally greater. A study on crystal form includes characterization of (l)crystal habit, (2)polymorphism, (3)pseudopolymorphism, (4)amorphous solid.

• 대한기계학회논문집A
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• 제35권9호
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• pp.991-997
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• 2011

본 논문은 EPP 비드폼에 대한 증기실 조형공정의 기본 원리들과 과정들에 대해 다루고 있습니다. 증기실 조형은 EPP 기술을 위한 필수적인 공정입니다. 그러나 증기실 조형의 공정조건에 대해 연구가 거의 이루어져 있지 않습니다. EPP 폼의 특징들은 에너지흡수, 다양한 충격보호, 가벼운 무게, 구조상의 견고성과 내구성 등이다. 본 연구에서는 증기실 조형에서 증기압을 변화시켜 EPP 폼 제작을 위한 최적조건을 찾고자 노력하였으며, 무엇보다 증기조형 제품의 수축을 방지하기 위하여 EPP 폼 조형후 노내 가열을 수행하였다. 다른 노내 가열 온도들에서 시간에 따라 무게가 바뀌는 것을 관찰함으로써 폼수축의 메커니즘을 확인하는 것이 가능하였다. 인장시험과 SEM 해석을 수행하여 이들 실험결과들을 뒷받침할 수 있었고, 다른 증기압들에서 조형된 제품들에 대해 치수안정성을 조사하였다.