• Journal of the Mineralogical Society of Korea
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• v.9 no.1
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• pp.43-53
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• 1996

The detailed crystal chemistry of ilmenite from the Hadong massif was studied by the EPMA, M ssbauer spectroscopy, and Rietveld structural refinement using X-ray powder diffraction data. The ilmenite-bearing anorthosite shows complicated mineral assemblage which consists of plagioclase, clinopyroxene, hornblende, biotite, chlorite, apatite, allanite, and zircon. Anorthite is andesine in composition (Ab 28-57), and clinopyroxene drops in ferro-hypersthene (Fs 62-70). Ilmenite is trigonal symmetry with R space group, whose structure shows the alternation of Fe2+ (M1 site) octahedral layer and Ti (M2 site) layer along c axis. M ssbauer spectroscopy indicates that there are three doubles which assigned to couple of Fe2+($\delta$=0.812, 0.890mm/sec) and one Fe3+($\delta$=0.303mm/sec) in octahedral sites. Their Fe3+/$\Sigma$Fe is 0.065 and chemical formula is established as Fe2+0.94Fe3+0.07Ti0.97O3 using both EPMA and M ssbauer analysis. Rietveld structural refinement reveals that site occupancies of Fe in M1 and Ti in M2 are 91.2% and 89.4%, respectively. This implies that Ti and Fe2+ are alternatively occupy M1 and M2 sites. In addition, smaller M2 site is more preferable to Fe3+ occupancy over M1.

• Resources Recycling
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• v.25 no.3
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• pp.74-81
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• 2016

Study on chlorination of ilmenite ore were carried out by using PVC(polyvinyl chloride) as the chlorinating agent in a static bed reactor for selective removal of iron. The effect of amount of PVC and reaction temperature were investigated. It was found that the removal ratio of iron increased with amount of PVC and temperature. After reaction with HCl gas generated from PVC, porous surface of the specimens were observed. As a result, HCl gas could react with iron in the central portion of ilmenite particle through these pores. Examination of data using kinetic model suggest that the selective chlorination rate is controlled by chemical reaction at the interface of particles. The activation energy for the selective chlorination of ilmenite using PVC was calculated as 20.47 kJ/mol.

• Resources Recycling
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• v.25 no.5
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• pp.64-74
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• 2016

Titanium and iron are closely related in nature, although titanium is the ninth most abundant element in the Earth's crust. Iron in titanium ores must be removed for use as feedstocks in the manufacture of titanium dioxide pigments and pure $TiCl_4$ for metal titanium. In this study, various beneficiation processes of ilmenite for production of $TiO_2$ have been reviewed and compared. Most of these processes involve a combination of pyrometallurgy and hydrometallurgy. These beneficiation processes of ilmenite generate considerable quantities of wastes primarily in the form of iron salt, iron oxide and acidic effluents. Therefore, it is important that recovery of acid value from waste and conversion of iron bearing waste to useful materials for development of new beneficiation processes of ilmenite.

• Korean Journal of Materials Research
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• v.29 no.7
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• pp.412-424
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• 2019

Global fitting functions for Fe-selective chlorination in ilmenite($FeTiO_2$) and successive chlorination of beneficiated $TiO_2$ are proposed and validated based on a comparison with experimental data collected from the literature. The Fe-selective chlorination reaction is expressed by the unreacted shrinking core model, which covers the diffusion-controlling step of chlorinated Fe gas that escapes through porous materials of beneficiated $TiO_2$ formed by Fe-selective chlorination, and the chemical reaction-controlling step of the surface reaction of unreacted solid ilmenite. The fitting function is applied for both chemical controlling steps of the unreacted shrinking core model. The validation shows that our fitting function is quite effective to fit with experimental data by minimum and maximum values of determination coefficients of $R^2$ as low as 0.9698 and 0.9988, respectively, for operating parameters such as temperature, $Cl_2$ pressure, carbon ratio and particle size that change comprehensively. The global fitting functions proposed in this study are expressed simply as exponential functions of chlorination rate(X) vs. time(t), and each of them are validated by a single equation for various reaction conditions. There is therefore a certain practical merit for the optimal process design and performance analysis for field engineers of chlorination reactions of ilmenite and $TiO_2$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.234-234
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• 2003

MgTiO$_3$와 ZnTiO$_3$ 같은 ilmenite형 세라믹스는 유용한 유전특성 때문에 MLCC와 RF/microwave 장치와 같은 유전체 세라믹 부품에 사용될 수 있다. 그러나, 이 두 ilmenite형 세라믹스는 저온에서 hexagonal 구조를 띄는 ilmenite 합성에서의 난점들 때문에 LTCC에 사용되기 어려운데, 본 연구에서는 ilmenite형 세라믹스의 합성을 개선시키는데 Mechanically Activated Syntheses법(이하 MAS법)을 이용했다. MAS법으로 합성온도를 낮출 수 있었고 원치 않는 2차상의 형성을 방지할 수 있었으며, LTCC에 이용될 수 있는 분말들의 소결온도를 95$0^{\circ}C$ 이하로 내릴 수 있었다. 또한, MAS법을 이용했을 때와 기존의 방법을 이용했을 때의 여러 특성들을 비교 분석했다.

• Solar Energy
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• v.8 no.1
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• pp.49-56
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• 1988

Thermally treated Korean ilmenite was characterized and used for water splitting to obtain hydrogen by photo-catalytic reaction. Experiments on specific surface area, X-ray diffraction and EDS showed that the formation of FeO, $Fe_2O_3$ and $TiO_2$ ilmenite crystal surface increased the specific surface area with maximum value, phase change of $TiO_2$ at $600^{\circ}C$ and hetrogeneity. The hydrogen evolved in caustic soda solution on these ilmenites indicated that there was a maximum yield point at about $600^{\circ}C$. This point was explained with the change of the surface area due to sintering of newly formed FeO, $Fe_2O_3$ and $TiO_2$, as well as crystal phase change of anatase to rutile at $600^{\circ}C$. Produced hydrogen increased also as the concentration of caustic soda, but become constant at the near 1N solution.

• The Journal of the Petrological Society of Korea
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• v.3 no.1
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• pp.1-19
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• 1994

We present petrography, mode and chemistry data for Fe-Ti oxide minerals from the Mesozoic granitoids in South Korea. Magnetites from the Daebo Uurassic) granites are nearly pure $Fe_3O_4$, while those from the Bulgugsa (Cretaceous) granites contain considerable amounts of Mn and Ti. This is probably related to rapid cooling of the Bulgugsa granites compared with slow cooling of Daebo granites, which is supported by geologic relations and hornblende geobarometry results of Cho and Kwon (1994) on the emplacement depth for these granites. The composition of ilmenite does not shew appreciable difference between the Daebo and Bulgugsa granites. However, $Fe_2O_3$ contents are higher for the ilmenites coexisting with magnetite than for those without magnetite. In the temperature vs. oxygen fugacity diagram, the Bulgugsa granites plot near Ni-NiO and QFM buffer curves, although only two samples show greater than the granite solidus temperature. The mode data suggest that both magnetite- and ilmenite-series exist in Daebo and Bulgusa granites from the Kyonggi massif, Ogcheon belt and Youngnam massif, while only magnetite-series exists in Bulgugsa granites from the Kyongsang basin. Many ilmenite-series granites occur in the Ogcheon belt, which might be related to assimilation of carboniferous sediments in the belt. The proportion (44 : 56) between ilmenite- and magnetite-series for the Daebo granites is significantly different from that of Ishihara et al. (1981) who showed, using magnetic susceptibility data, predominance of ilmenite-series (more than 70%) for the Daebo granites, which can be mainly attributed to preference in sampling and to wrong assignment of age for some plutons. We also found magnetite in weakly-magnetized Kanghwa granite which was formerly classified as ilmenite-series by Ishihara et al. (1981). The proportion of ilmenite-series increases in the order of hornblende biotite granite, biotite granite and two mica granite. We conclude from these observations that the ilmeniteseries granites might have originated from contamination of carboniferous crustal material and/or such source material.

• Journal of the Korean Magnetics Society
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• v.21 no.1
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• pp.37-41
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• 2011

Fe compounds of scoria samples distributed in Songdang-ri positioning north-eastern area of Jeju island were investigated by means of X-ray diffractometry (XRD) and $^{57}Fe$ M$\ddot{o}$ssbauer spectroscopy. The samples were prepared from six parasite. We found that the samples were composed of a typical olivine, pyroxene, ilmenite, $SiO_2$, anorite and anorthoclase, M$\ddot{o}$ssbauer spectrum of the most scoria samples are shown doublets and sextets of olivine, doublets of pyroxene, ilmenite and silicate minerals. And the valence states of Fe ion of the scoria samples in this area are chiefly 3+ charge state and a little 2+ charge state.

• Journal of the Korean Magnetics Society
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• v.17 no.5
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• pp.205-209
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• 2007

It have been investigated the measured results of the XRF, the X-ray diffractometry and $^{57}Fe\;M{\ddot{o}}ssbauer$ spectrum for scoria samples which are distributed throughout different areas in Mid-mountain Area of Jeju island. We consider that the scoria samples are chiefly made of silicate minerals, like $SiO_2$, others silicate minerals and iron oxides minerals. We study that it's materiel is consisted of olivine, pyroxene, ilmenite, hematite and magnetite. Iron compounds in that are $Fe^{2+}$ of olivine, pyroxene, ilmenite and $Fe^{3+}$ of hematite, magnetite et al. The major Fe fractions of the scoria samples are 51.77 wt%, so Fe fractions of the scoria samples are almost 3+ charge state with a little of the 2+ charge state.

• The Journal of the Petrological Society of Korea
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• v.3 no.3
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• pp.220-233
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• 1994

The granitic rocks in the Poeun - Sogrisan area are composed of the Jurassic Poeun granodiorite and the Cretaceous Sogrisan granites. The latter can be divided into three rock types : coarse-grained biotite granite, porphritic biotite granite and granite porphyry. Petrographical observations, especially focusing on the quartz-feldspar intergrowth texture, suggest that the Sogrisan granites has emplaced at shallower level and crystallized more rapidly than the Poeun granodiorite. The F, Cl contents and the Fe/(Fe+Mg) ratio of biotite and muscovite in the Sogrisan granites are higher than those in the Poeun granodiorite. The anor-thite contents of plagioclase in the Poeun granodiorite are higher then in the Sogrisan granites. Ilmenite in the Sogrisan granites is more enriched in Mn and depleted in Fe than that in the Poeun granodiorite. The whole-rock magnetic susceptibility values (in $10^{-6}$ emu/g unit) are higher in the Sogrisan granites (33~144) than the Poeun granodiorite (9~12), indicating that the former generally belongs to magnetite-series granitoid and the latter to ilmenite-series one. The Sogrisan granites has solidified under more oxidizing environment than the Poeun gra-nodiorite, judging from the whole-rock magnetic susceptibility measurements as well as the chemical compositions of biotite and ilmenite.