• 제목/요약/키워드: Illite

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Major Industrial Minerals in Korea : Geological Occurrence and Current Status of Demand/Supply (국내 산업소재광물의 수급 및 부존 특성)

  • Lee, Dong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.7 no.1
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    • pp.1-13
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    • 1994
  • The industrial minerals play an important role in mining sector. More than 70 % of total mineral production come from industrial mineral sector. This paper reviews geological occurrence of kaolin, pyrophyllite and limestone, and current demand-supply status of major industrial minerals in the Republic of Korea. The kaolin is mainly distributed in the Kyeongsang province, formed by deep weathering of Precambrian anorthosite on mountainside of gentle slope. The pyrophyllite mainly occurs in the Kyeongsang and Chulla provinces, formed by hydrothermal alteration of late Cretaceous andesitic and rhyolitic rocks. Pyrophyllite comprises massive and lenticular bodies and contains minor amounts of kaolin, alunite and pyrite, in some places andalusite and illite. The limestone(Great Limestone Series of Cambrian age) is distributed widely in the Kwangwon and Chungcheong provinces. The limestone bodies are approzimately 70 km long and 3 km wide, elongated NE-ward, and show high grade of CaO content. In 1992, the self-sufficiency ratio of 44 nonfuel (metallic and non-metallic) minerals was no more than 30 percent. However, the ratio of 27 industrial minerals (non-metallic) represents high value of about 72 percent. The export/productjon ratio of the industrial minerals shows decreasing patterns from 12.2 % in 1983 to 4.2 % in 1992. Also the import/production ratio shows rapidly decreasing pattern from 84 % in 1983 to 38.2 % in 1992.

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Identification of two coliphages from Han-river and its adsorption-elution effect on soil materials (한강에서 분리한 이종 coliphage의 동정과 점토질에 대한 흡착 및 용출효과)

  • 홍순우;하영칠;안태석;이영숙
    • Korean Journal of Microbiology
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    • v.20 no.4
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    • pp.210-222
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    • 1982
  • Coliphages isolated from Han-River from September 1980 to August 1981 were classified by morphological and physiological characteristics. Effects of soil metrial on the fate of coliphage in nature were investigated. 1. The correlation coefficient between coliphage and E.coli which was host of coliphages in nature was 0.7173 (p=0.004). 2. Coliphage I isolated from Han-River of which DNA molecular weight was $27{\times}10^6$ daltons was identified as $T_1$ phage and coliphage II of which DNA molecular weight $72{\times}10^6$ daltons was classified as $T_5$ phage. 3. Soil material SW was composed of 63.65% silt and 21.92% clay. Clay was consisted of illite, kaolinite and chlorite evenly. Soil material J was composed of 68.92% silt and 11.67% clay. Clay consisted of smectite only. 4. Coliphage was absorbed to soil material J more than soil material SW, and $T_1$ coliphage was absorbed to soil material more than $T_5$ coliphage was. 5. The phage adsorption efficiency to soil material was enhanced at lower pH : the phage adsorption efficiency at pH 4 was 27 time higher than at pH 7. 6. Divalent $(Ca^{2+})\;and\;trivalention\;(Al^{3+})$ enhanced the phage adsorption efficiency to soil material from 4 to 39 and from 17 to 91 times higher than monovalent $ion(Na^+)$, respectively. 7. The concentration of organic compound was inversely related to the phage adsorption efficiency to soil. 8. Adsorption of phage onto soil material, and elution efficiency of elutants was in the order of D.D.W>tap water>river water>seawater. 9. The higher the concentration of organic compound was, the more were adsorbed phages to soil eluted. 10. Coliphages survived longer in sterile soil suspension than in nonsterile soil material suspension.

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The Measurement System and Physical Property of Unconsolidated Sample under Trinxial Pressure (삼축압력하에서의 미고결 시료의 물성측정을 위한 측정 장치와 물성 연구)

  • Bae, Wi-Sup;Chung, Tae-Moon;Kwon, Young-Ihn;Kim, Hyun-Tae
    • Journal of the Korean earth science society
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    • v.28 no.7
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    • pp.838-846
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    • 2007
  • A measurement system of tri-axial pressure was designed and constructed to measure permeability and resistivity under changing confining pressure. The system was designed to measure the permeability and resistivity of a core simultaneously, consisting of tri-axial supporting device and sets of dual-flow measurement. In this measurement system the permeability and resistivity of a sample can be directly measured and porosity can be obtained using Archie's laws. As for physical properties, artificial core samples are made from mixtures of standard commercial sand and mud of illite. In-situ sediment cores were sampled at the water-depth of 1,800m in the Ulleung Basin East Sea. In order to investigate the effects of confining pressure changes on physical properties, permeability and resistivity changes were monitored with increasing confining pressure. In this study, it was found that with the increase of confining pressure, permeability and porosity tend to decrease and resistivity tend to increase exponentially.

Mineralogy of Evaporation Residues and Geochemistry of Acid Mine Drainage in the Donghae Mine Area (동해탄광 일대 산성광산배수의 지화학적 특성 및 증발잔류물에 대한 광물학적 연구)

  • 김정진;김수진;김윤영
    • Economic and Environmental Geology
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    • v.36 no.2
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    • pp.103-109
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    • 2003
  • The mineralogy of material left after evaporation of acid mine drainage water is generally dependent on the chemical composition of the source water. The residues formed by the evaporation of acid mine water in the Dong-hae coal mine area consists mainly of gypsum (CaSO$_4${\circ}$2$H_2O$) with mine. amounts of alunogen (Al$_2$(SO$_4$)$_3$${\circ}$17$H_2O$) and hexahydrite (MgSO$_4$${\circ}$<.TEX>6$H_2O$). Gypsum was identified from both of the bottom precipitates and the evaporation residues of acid mine water. Alunogen, an aluminum sulfate hydrate, was also formed by evaporation and occurred as needle-like crystals. Aluminum is derived from chemical dissolution of alumine-silicate mineral such as pyre-phyllite, illite and chlorite in wasted rocks. Hexahydrite in evaporation residues occured as needle-like, fibrous, and acicular crystals and was associated with gypsum and alunogen.

Mineralogical and Geochemical Characteristics of PFA (Pulverised Fuel Ash) from Yongwol Power Plant (영월 화력발전소에서 배출된 석탄회의 광물학적, 지화학적 특성)

  • Lee, Gyoo Ho;Choi, Sun Kyung;Moon, Hi-Soo;Lee, Sang Hoon
    • Economic and Environmental Geology
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    • v.30 no.5
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    • pp.443-450
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    • 1997
  • The main purpose of this study is to investigate mineralogical and chemical changes during natural weathering, and assess the mobility of major and trace elements. Yongwol power plant utilize anthracite coal which is mainly composed of illite, kaolinite, pyrophyllite and quartz in mineralogy. Coal and coal-derived fly ash samples were sampled by the electrostatic precipitator in Yongwol coal-fired power plant in Korea. Short term weathered fly ash were also collected in ash disposal mound, and two profile soil samples were taken from an ash near the power plant. Amorphous materials are the main component of the fly ash, and mullite, quartz, magnetite and heamatite are present in all coal-derived fly ash. In chemistry, Si and Al are the most abundant elements of the total content. The ash samples were fractionated into upper $90{\mu}m$ and under $45{\mu}m$ size. Finer particles show higher concentrations in metal contents including Co, Cr, Cu, Ni, V, Zn and Pb. Concentration of Zn and Pb are nearly 4 times higher concentration in the finer particles. For the profile samples, the concentrations of $SiO_2$, $Na_2O$, MgO and $K_2O$ generally show increasing trends with depth, whereas those of $Fe_2O_3$ and $TiO_2$ appear to decrease with depth. Content of MnO does not show any specific depth trend. For the trace elements, Co, Cu, Ni and V show increasing concentrations with depth.

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The Characteristics of the White Clay Pigment Manufactured from the White Clay of Producing Area Recorded in Old Documents (고문헌 산출지 백토로 제조된 백토안료의 특성 연구)

  • Kang, Yeong Seok;Mun, Seong Woo;Jeong, Hye Young
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.497-506
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    • 2017
  • An investigation on the records of old document was conducted to identify the producing area of white clay and there were on-the-spot surveys to secure raw materials of white clay pigment. Based on the survey results, six raw materials were obtained from the region of Gangwon-do and Gyeongsang-do, South Korea and white clay pigment was subsequently manufactured by applying the hydraulic elutriation method. The results show that the major constituent minerals of YBW, HBW, and MCW were quartz and plagioclase, whereas SGW, HOW, and HGW were composed of clay minerals such as kaolinite and illite. HGW showed the highest $L^*$-value of 92.9. HOW and HGW showed an opacity of 94.1% and 89.6%, respectively, and they had excellent spreadability (270.3 mm and 223.3 mm, respectively). Therefore, HGW, HOW, and SGW have excellent characteristics in terms of color, opacity, and spreadability, and are considered to be highly applicable as white pigments for the Dancheong.

Applicability Assessment of Acid Treated Red Mud as Adsorbent Material for Removal of Six-valent Chromium from Seawater (해수에서 6가 크롬 제거를 위한 흡착제로서의 산처리 적니 적용성 검토)

  • Kang, Ku;Um, Byung-Hwan;Kim, Young-Kee;Park, Seong-Jik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.5
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    • pp.17-23
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    • 2013
  • Six-valent chromium ($Cr^{6+}$) is a highly toxic pollutant, supplied in a variety of industrial activities such as leather tanning, cooling tower blowdown, and plating. Herein, we investigated the removal of $Cr^{6+}$ from aqueous phase using low-cost adsorbents. Steel slag, montmorillonite, illite, kaolinite, red mud, and acid treated red mud with 0.5, 1.0, and 2.0 M HCl were used as adsorbent for the removal of $Cr^{6+}$ and the results showed that acid treated red mud with 2.0 M HCl (ATRM-2.0 M) had higher adsorption capacity of $Cr^{6+}$ than other adsorbents used. Accordingly, $Cr^{6+}$ removal by ATRM-2.0 M were studied in a batch system with respect to changes in initial concentration of $Cr^{6+}$, initial solution pH, adsorbent dose, adsorbent mixture, and seawater. Equilibrium sorption data were described well by Freundlich isotherm model. The influence of initial solution pH on $Cr^{6+}$ adsorption was insignificant. The use of the ATRM-2.0 M alone was more effective than mixing it with other adsorbents including red mud, zeolite, oyster shell, lime stone, and montmorillonite for the removal of $Cr^{6+}$. The $Cr^{6+}$ removal of the ATRM-2.0 M was slightly less in seawater than deionized water, resulting from the presence of anions in seawater competing for the favorable adsorption site on the surface of ATRM-2.0 M. It was concluded that the ATRM-2.0 M can be used as a potential adsorbent for the removal of $Cr^{6+}$ from the aqueous solutions.

The scientific analyses and classifications of potteries focused on the artifacts from Changdo (도.토기의 과학적 분석 및 분류-전남 완도군 장도 청해진 유적을 중심으로)

  • Hong, Jong-Ouk;Cho, Nam-Chu;Kang, Dai-Il;Lee, Myong-Hee
    • 보존과학연구
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    • s.21
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    • pp.233-271
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    • 2000
  • This study has proved if there are homogeneities in crystal structures, firing temperaures and element compositions of 69 specimens for potteries and soils from Changdo, Kangjin-gun, Jinjuk-Ri in Korea and Yaezhou inChina and obtained the following results.1. XRD analyses showed that soft potteries seemed to contain ($\alpha$)quartz, feldspar, while hard potteries seemed to contain ($\alpha$-)quartz, mullite, tridymite, feldspar. Jinjuk-Ri soils consisted of clays such as Kiolinite, Montmorillonite, Muscovite, Illite and, mica and feldspar etc.2. It was estimated that the firing temperatures which are determined by crystals using XRD, ranged from $550^{\circ}C$ to $870^{\circ}C$ for soft potteries and $870^{\circ}C$ to $975^{\circ}C$ for hard potteries.3. The firing temperatures for 4-pieces of Changdo pottery were measured by using TG-DTA, and it was found that specimen No. 10 was fired at temperatures below $600^{\circ}C$, while specimens No. 14, No. 23 and No. 29 were fired at temperatures above $1000^{\circ}C$.4. It was found that the specimems for potteries and porcelains from Changdo, Kangjin-gun, Jinjuk-Ri in Korea and Yaezhou in China were apparently classified into 4 clusters. This suggests that there are no correlations between the raw materials used in each 4 regions. Among the porcelains from Changdo, there were many typologically similar ones to those from Yaezhou in China in the 9th centry, but the analyses of porcelains only from Changdo, Kangjin in Korea and Yaezhouin China showed that they were classified into 3 clusters. This suggest that there are no correlations between the raw materials used for making porcelains in Changdo, Kangjin-gun, Jinjuk-Ri in Korea and Yaezhou in China.

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Studies on Variations of Turbidity with Strength of Rainfall and Mineralogy of turbidity-causing materials in Imha and Andon-Dam (강우 강도에 따른 임하댐 및 안동댐 유입하천의 탁도 변화와 탁도 유발물질의 광물학적 특성 연구)

  • Kim, Jeong-Jin;Jung, Yong-Sik;Kim, Jung-Gon;Lee, Sang-Wook;Kim, Young-Hun
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.3
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    • pp.213-222
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    • 2007
  • Changes of turbidity and suspended solid concentration of inflow tend to be very similar in Andong and Imha dam, and show significant effect on the amount of rainfall. Concentrations of suspended solid and turbidity in Imha are higher than these of Andogn dam, and Banbyon have higher values than that of Yongjeon stream in Imha dam. There is no difference in size distribution and mineral composition of the suspended particles in Andong and Imha dam. The turbidity-causing materials are composed of vermiculite. illite, kaolinite, quartz and albite. X-ray diffraction analysis shows that turbidity-causing materials are have similar mineralogy between Andong and Imha Dam, but they have different abundance.

Studies on Heavy Metal Dissolution Characteristics from Sediments of Andong Dam (안동댐 퇴적물의 중금속 용출 특성 연구)

  • Seo, Jeong Min;Kim, Young Hun;Kim, Jeong Jin
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.4
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    • pp.303-312
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    • 2019
  • In this study, X-ray diffraction, ICP analysis, and leaching experiments were performed to analyze the heavy metals and dissolution characteristics of Andong dam sediments. As a result of X-ray diffraction analysis, Andong dam sediment consists of quartz, plagioclase, chlorite and illite. ICP analysis of sediment showed very high concentrations of As and Cd. Leaching experiments were performed in aerobic and anaerobic condition in a disturbed state. The results of leaching experiment showed that more heavy metals were leached in aerobic than anaerobic conditions. Heavy metal that increased in concentration with time in aerobic conditions were Mn, Zn and Cd, and those in anaerobic conditions were Mn, Fe and As. The leaching ratio of heavy metal concentration in sediment was Mn > Cd > Zn > Ni > Cu > As > Pb ≒ Fe ≒ Cr and Mn > As > Cu > Ni > Zn > Pb ≒ Cd ≒ Fe ≒ Cr in aerobic and anaerobic conditions, respectively.