• 한국가스학회지
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• 제18권3호
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• pp.31-37
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• 2014

본 연구에서는 자료 제공을 목적으로 국내 분진폭발사고에서와 동일한 고밀도 폴리에틸렌(high-density polyethylene, HDPE ) 분진을 사용하여 열분해성과 착화에너지를 실험적으로 조사하였다. 폭발 민감도를 측정하기 위하여 시차주사열량계(differential scanning calorimeter, DSC), 열중량분석기(thermo-gravimetric analysis, TGA) 및 최소착화에너지(minimum ignition energy, MIE) 측정장치를 사용하였다. HDPE의 체적기준 평균입경은 $61.6{\mu}m$가 얻어졌으나, 입자 크기에 따른 입자 수밀도(particle number density) 분석에서는 $0.4{\sim}4{\mu}m$의 미세 입자가 98% 이상의 비율을 갖는 것으로 나타났다. TGA 및 DSC 측정결과로부터 HDPE는 $380{\sim}490^{\circ}C$의 온도 구간에서 발화가 일어날 수 있음을 알 수 있었고, MIE는 $1200{\sim}1800g/m^3$의 HDPE의 농도 범위에서 1 mJ 이하로 측정되었는데, 이는 입자 수밀도 기준에 따른 $0.4{\sim}4{\mu}m$의 미세 입자의 비율(98 %)이 매우 높았던 것이 원인으로 판단된다.

• 한국안전학회지
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• 제33권2호
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• pp.45-51
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• 2018

This study was conducted to assess the hazards of gasoline in relevance to the changes in octane numbers, and gasoline's spontaneous ignition temperature and instantaneous ignition temperature were measured. Spontaneous ignition temperature of regular gasoline was $301^{\circ}C$ for sample quantity of $100{\sim}125{\mu}{\ell}$. Spontaneous ignition temperature of middle gasoline was $380^{\circ}C$ for sample quantity of $125{\mu}{\ell}$ and that of premium gasoline was $400^{\circ}C$. As gasoline's octane numbers increased, their spontaneous ignition temperatures increased, and their instantaneous ignition temperature were almost identically $499^{\circ}C$ for sample quantity of $125{\mu}{\ell}$. In addition, activation energies of regular gasoline, middle gasoline, and premium gasoline were 10.48 Kcal/mol, 16.89 Kcal/mol, and 24.55 Kcal/mol respectively.

• 한국안전학회지
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• 제7권4호
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• pp.45-53
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• 1992

Sponataneous ignition characteristics for granulated activated carbon were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 5$^{\circ}C$, 1$0^{\circ}C$ and 15$^{\circ}C$ respectively, and the period in each amplitude was varied at an interval of 30minutes from zero to 3hours. As the results of experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample decreased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank-Kamenetskii's thermal Ignition theory was 38.82［kca1/mo1］ In case of varying the ambient temperature sinusoidally, the critical spontaneous ignition tempera-ture was lower than that at the constant ambient temperature, and the minimum critical spontaneous ignition temperature decreased with the amplitude of heating sinusoidal curve. At the same amplitude, the critical spontaneous ignition temperature decreased until it reached the minimum point and then in-creased as the period increased.

• 한국자동차공학회논문집
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• 제1권1호
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• pp.50-58
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• 1993

The ignition delay of diesel oil and fish oil blended with diesel oils was investigated at various pressure and temperature conditions in a constant volume combustion bomb. The evaporation and combustion duration of diesel oil and fish oil blended with diesel oils were respectively different in high and low temperature. The dependence of ignition delay on the temperature was different in high and low temperature ranges which were divided at the 773K. The dependence of ignition delay on the pressure was almost linear, regardless of the test fuels at the constant temperature(863K). The ignition delay became longer as the blending rate of fish oil increased at the constant temperature and pressure, but it was especially short with 20% fish oil blended with diesel oils.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1854-1856
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• 1996

This study describes the minimum ignition limit for LPG-Ai-r mixtures by switching sparks in radio-frequency limits using RF power supply and IEC type ignition spark apparatus. As a result, the minimum ignition limit voltage is increased in proportional to the rate of increasing of frequency in LPG-Air mixed gas. Especially, increment between 10[kHz] and 30[kHz] is typical. It is considered that ignition is caused by one discharge until 10 [kHz] and, beyond 10[kHz] ignition is caused by more than two discharges. The reason is analysed that energy loss is caused by existing pause interval between discharges.

• 한국안전학회지
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• 제6권4호
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• pp.66-72
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• 1991

Spontaneous ignition characteristics were observed by performing experiments for granulated activated carbon at constant ambient temperature in an oven. As the results of the experiments, the critical spontaneous ignition temperature of sample for large, intermediate and small vessels was 158.5$^{\circ}C$ , 165.5$^{\circ}C$ and 174.5$^{\circ}C$, respectively. It was found that the critical spontaneous ignition temperature decreased and the ignition induction time increased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank= kamenetskii's thermal ignition theory was 17.81＊10$^3$J/mol.

• 한국안전학회지
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• 제7권1호
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• pp.47-56
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• 1992

Spontaneous ignition charactenstics for fish meal were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. As the results of the experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample for large, intermediate and small vessels was 170.5$^{\circ}C$, 177.5$^{\circ}C$ and 188.5$^{\circ}C$, respectively. The critical spontaneous ignition temperature decreased as the sample vessel size increased. Apparent activation energy of used fish meal calculated from the Frank-Kamenetskii's thermal ignition theory was 37.60Kcal/mol. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 1$0^{\circ}C$, 2$0^{\circ}C$ and 3$0^{\circ}C$ respectively with the period in each amplitude 1hr, 2hrs and 3hrs. The results showed that the critical spontaneous ignition temperatures at the varied amplitudes of temperature were lower than that at the constant anbient temperature and increased as the amplitude increased. At the same amplitude, the critical spontaneous ignition temperature increased with the period.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제35회 추계학술대회논문집
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• pp.705-706
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• 2010

킥모터 점화기의 점화 초기 연소 특성에 대한 설계 해석 결과 초기 압력 조건에 따라 100~500 ms 범위의 점화지연이 생기는 것으로 나타났다. 개발 시험에서 점화기가 점화 초기 주 추진제를 점화시키는데 충분한 에너지를 공급할 수 있다는 것을 검증하였다.

• 대한기계학회논문집B
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• 제33권9호
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• pp.682-687
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• 2009

In order to investigate the effects of three different electrostatic discharge energies on gas explosions, a high-speed PIV system has been applied. The present study paid attention to the flame initiation by the gas explosions and its propagation at the existence of an obstacle within a chamber. Three different ignition energies such as 0.56 mJ, 52.87 mJ and 112.5 mJ were used. It is found that the ignition kernel is bent by the electrostatic discharge during the flame initiation. Tangential velocities of unburnt mixture ahead of initially propagating flame fronts are increased with increasing ignition energy, which makes the flame propagation faster before it reaches the obstacle. Although the flame speed was found to be less sensitive to the ignition energies, the flame developments were different. The effects of the energies on explosion pressures were also discussed.

• Korean Chemical Engineering Research
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• 제57권6호
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• pp.790-803
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• 2019

디옥틸테레프탈산(DOTP) 제조공정은 분말형태의 테레프탈산(PTA) 주원료와 옥탄올(Octanol)의 에스테르화 반응을 통해 플라스틱 가소제를 생산하는 공정이다. 본 연구에서는 이 공정의 반응기 내에 가연성 용제나 유증기가 존재하고 있는 상태에서 분말형태로 맨홀에 직접 투입하는 테레프탈산의 분진폭발 특성에 관하여 고찰하였다. 분진의 입경과 입도분포 분진특성 실험을 하였고, 화재 폭발특성과 발화온도를 추정하기 위한 분진의 열분해 특성을 조사하였다. 또한 폭발민감도를 평가하기 위한 최소점화에너지 실험을 실시하였다. 실험결과 테레프탈산의 분체 특성은 평균입경이 $143.433{\mu}m$으로 나타났다. 이러한 입경과 입도분포 조건에서 실시한 열분석으로부터 분진의 발화온도는 약 $253^{\circ}C$로 나타났다. 테레프탈산의 폭발민감도를 알기 위해 조사한 폭발하한 농도(LEL)는 $50g/m^3$으로 측정되었다. 폭발민감도를 나타내는 최소점화에너지(MIE)는 (10 < MIE < 300) mJ로 나타났으며, 점화 확률에 기반하여 추산한 최소점화에너지 추정값(Es)은 210 mJ로서 충분한 점화원이 있는 경우 폭발할 수 있음을 알 수 있었다. 또한 폭발피해 예측에 필요한 폭발강도 특성을 조사한 결과, 테레프탈산 분진의 최대폭발압력($P_{max}$), 최대폭발압력상승속도[$({\frac{dP}{dt}})_{max}$]는 각각 7.1 bar, 511 bar/s로 나타났다. 분진폭발지수(Kst)는 139 mbar/s로 분진폭발등급 St 1에 해당되는 것으로 나타났다.