• 한국도로학회논문집
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• 제17권5호
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• pp.1-10
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• 2015

PURPOSES : A finite difference model considering snow melting process on porous asphalt pavement was derived on the basis of heat transfer and mass transfer theories. The derived model can be applied to predict the region where black-ice develops, as well as to predict temperature profile of pavement systems where a de-icing system is installed. In addition, the model can be used to determined the minimum energy required to melt the ice formed on the pavement. METHODS : The snow on the porous asphalt pavement, whose porosity must be considered in thermal analysis, is divided into several layers such as dry snow layer, saturated snow layer, water+pavement surface, pavement surface, and sublayer. The mass balance and heat balance equations are derived to describe conductive, convective, radiative, and latent transfer of heat and mass in each layer. The finite differential method is used to implement the derived equations, boundary conditions, and the testing method to determine the thermal properties are suggested for each layer. RESULTS: The finite differential equations that describe the icing and deicing on pavements are derived, and we have presented them in our work. The framework to develop a temperature-forecasting model is successfully created. CONCLUSIONS : We conclude by successfully creating framework for the finite difference model based on the heat and mass transfer theories. To complete implementation, laboratory tests required to be performed.

• 설비공학논문집
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• 제9권2호
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• pp.104-111
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• 1997

The freezing phenomenon of saturated water with the supercooled region in a horizontal circular cylinder has been studied experimentally by using the holographic real time interferometry technique. From the experiments, it was found that there were three types of freezing patterns. The first is the annular ice layer growing from the cylinder surface at a high cooling rate; the next is the asymmetric ice layer at a moderate cooling rate; and the last is the instantaneous ice layer growth over the full region at lower cooling rate. As the water was coolde from room temperature to the subfreezing point passing through the density inversion point, the freezing pattern was largely affected by the inversion phenomenon, which had much effected the free convection and was susceptible to influences from the cooling rate. When the cooling rate is high, supercooling energy is released before the water is sufficientry mixed by free convection. On the other hand, when the cooling rate is low, there is much time for the water to be mixed by free convection. This seems to be the reason why the different ice layer growths occur.

• 콘크리트학회논문집
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• 제17권5호
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• pp.857-868
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• 2005

This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

• 한국분무공학회지
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• 제14권4호
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• pp.147-152
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• 2009

Since a liquid-phase LPG injection system allows accurate control of fuel injection and increase in volumetric efficiency, it has advantages in achieving higher engine power and lower emissions compared to the mixer type LPG supplying system. However, this system also leads to an unexpected event called icing phenomenon which occurs when moisture in the air near the injector freezes and becomes frost around the nozzle hole due to extraction of heat from surrounding caused by instant fuel vaporization. As a result, it becomes difficult to control air/fuel ratio in engine operation, inducing exacerbation of engine performance and HC emission. One effort to mitigate icing phenomenon is to attach anti-icing injection tip in the end of nozzle. Therefore, in this study, the effect of engine operation parameters as well as surrounding conditions on icing phenomenon was investigated in a bench test rig with commercially-used anti-icing injection tips. The test results show that considerable ice was deposited on the surface near the nozzle hole of the anti-icing tip in low rpm and low load operating conditions in ambient air condition. This is because acceleration of detachment of deposited ice from the tip surface was induced in high load, high rpm conditions, resulting in decrease in frost accumulation. The results of the bench testing also demonstrate that little or no ice was formed at surrounding temperature below a freezing point since the absolute amount of moisture contained in the intake air is too small in such a low temperature.

• 한국응용과학기술학회지
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• 제38권6호
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• pp.1355-1369
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• 2021

본 연구는 도로 노면결빙 판정 알고리즘에 대해 알고리즘을 개선하고 실제 현장 측정 자료와 알고리즘 예측값을 비교하였을 때 알고리즘에 대한 적중률을 분석하였다. 분석을 위하여 포천시 신북면 금동리의 도로 및 기상을 측정하였다. 알고리즘은 기존 도로 결빙 알고리즘을 선정하여 실제 결빙 조건 및 측정 수치에 맞춰 4차 알고리즘까지 개선하였다. 최종적으로 응결에 의한 결빙, 강수에 의한 결빙, 적설에 의한 결빙, 결빙상태의 지속, 풍속에 의한 결빙 5개의 알고리즘을 제작하였다. 포천 현장에서 알고리즘을 활용하여 예측할 경우 경우 결빙 적중률이 93.22%까지 개선되었다. 결빙 알고리즘에 대한 조합 비율에 대해 도출하였을 때 응결에 의한 결빙과 결빙상태의 지속에 대한 알고리즘이 96%를 차지하였다.

• 한국지열·수열에너지학회논문집
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• 제19권2호
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• pp.8-19
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• 2023

Hydronic heated road pavement (HHP) systems have well studied and documented by many researchers. However, most of the systems run on asphalt, only a few are tested with concrete, and there rarely is a comparison between those two common road materials in their heating and cooling performance. The aim of this study is to investigate the thermal performance of the HHP, such as heat dissipation performance in winter season while focusing on the surface temperature of the concrete and asphalt pavement. For preliminary study a small-scale experimental system was designed and installed to evaluate the heat transfer characteristics of the HHP in the test field. The system consists of concrete and asphalt slabs made of 1 m in width, 1 m in length, and 0.25 m in height. In two slabs, circulating water piping was embedded at a depth of 0.12 m at intervals of 0.16 m. Heating performance in winter season was tested with different inlet temperatures of 25℃, 30℃, 35℃ and 40℃ during the entire measurement period. The results indicated that concrete's heating performance is better than that of asphalt, showing higher surface temperatures for the whole experiment cases. However, the surface temperature of both concrete and asphalt pavement slabs remained above 0℃ for all experimental conditions. The heat dissipation performance of concrete and asphalt pavements was analyzed, and the heat dissipation of concrete pavement was greater than that of asphalt. In addition, the higher the set temperature of the circulating water, the higher the heat dissipation. On the other hand, the concrete pavement clearly showed a decrease in heat dissipation as the circulating water set temperature decreased, but the decrease was relatively small for the asphalt pavement. Based on this experiment, it is considered that a circulating water temperature of 20℃ or less is sufficient to prevent road ice. However, this needs to be verified by further experiments or computational fluid dynamic (CFD) analysis.

• 한국태양에너지학회 논문집
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• 제34권2호
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• pp.53-59
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• 2014

Ice Rink is energy intensive building type. Concern of energy saving from buildings is one of very important issues nowadays. New and renewable energy sources for buildings are especially important when we concern about energy supply for buildings. Among new and renewable energy sources, use of seawater for heating and cooling is an emerging issue for energy conscious building design. The options of energy use from sea water heat sources are using deep sea water for direct cooling with heat exchange facilities, and using surface layer water with heat pump systems. In this study, energy consumptions for an Ice Rink building are analyzed according to the heat sources of air-conditioning systems; existing system and sea water heat source system, in a coastal city, Kangnung. The location of the city Kangnung is good for using both deep sea water which is constant temperature throughout the year less than $2^{\circ}C$, and surface layer water which should be accompanied with heat pump systems. The result shows that using sea water from 200m and 30m under sea lever can save annual energy consumption about 33% of original system and about 10% of that using seawater from 0m depth. Annual energy consumption is similar between the systems with seawater from 200m and 30m. Although the amount of energy saving in summer of the system with 200m depth is higher than that with 30m depth, the requirement of energy in winter of the system with 200m depth is bigger than that with 30m depth.

• 대한화학회지
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• 제8권2호
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• pp.68-74
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• 1964

물은 용융점, 끓는점, 용융열 및 증발열등의 수소와 6족원소와의 화합물의 성질로부터 예측되는 값보다 훨씬 크고, ice-I녹을 때 부피의 감소가 일어나는 등 특이한 성질을 가지고 있다. 이와같은 성질들을 정량적으로 설명하려고 지금까지 많은 연구자들이 노력해왔다. 저자들은 물의 큰 표면자유에네르기와 용융시의 특수한 부피변화로 미루어 물의 구조모델을 다음과 같이 생각하였다. 즉, 얼음이 용융함에 따라 분자크기의 이동성 빈자리가 도입되면 물의 큰 표면에네르기 밀도로 말미암아 빈자리 주위의 물분자는 촘촘한 배열을 가지게 되면 빈자리에서 떨어져있는 분자는 ice-I의 구조를 가질것으로 생각된다. 빈자리 주위의 분자가 빈자리에 뛰어 들어갈 때는 이동자유도를 지니게 될 것이다. 저자들은 H. Eyring의 액체구조이론을 써서 물의 liquid partition function을 위에 말한 바와 같이 구조모델로부터 유도하고 물의 증기압, 용융 및 증발엔트로피 등 여러가지 열역학적 성질 및 몰부피를 계산하여 실측치와 좋은 일치를 얻었다.

• 한국응용과학기술학회지
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• 제37권6호
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• pp.1507-1516
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• 2020

본 연구는 도로 노면결빙 판정 알고리즘을 적용하여 도로결빙 구간에 대한 시나리오를 분석하였다. 도로결빙 알고리즘 적용을 위해서, 도로 결빙에 대한 영향인자를 검토하고, 분석을 위해서 목감IC, 정릉터널, 성산대교, 염창교 등 4지점의 관측자료를 활용하였다. 관측소는 모두 고속화도로에 설치되어 있으며, 도로 결빙 특성 분석을 위하여 분류하였다. 도로 결빙 판정 알고리즘의 노면온도-노점온도 차가 3℃ 이하일 때 도로결빙 발생 구간을 확인하고 결빙 구간의 노면상태와 수막두께 변화를 통해 도로 결빙 판정을 도출하였다.

• 공업화학
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• 제32권1호
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• pp.83-90
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• 2021

본 연구에서는 저온 열처리 탄소의 물리·화학적 특성이 이차전지 음극재로서의 전기화학적 거동에 미치는 영향에 대하여 고찰하였다. 석유계 핏치의 코크스화를 위하여 600 ℃ 열처리를 수행하였으며 제조된 코크스는 700~1500 ℃로 탄화 온도를 달리하여 저온 열처리 탄소 음극재로 제조되었다. 탄소 음극재의 물리 화학적 특성은 N2 흡·탈착 등온선, X-ray diffraction (XRD), 라만 분광(Raman spectroscopy), 원소 분석 등을 통하여 확인하였으며,저온 열처리 탄소의 음극 특성은 반쪽 전지를 통한 용량, 초기 쿨롱 효율(ICE, initial Coulomb efficiency), 율속, 수명 등의 전기화학적 특성을 통하여 고찰하였다. 저온 열처리 탄소의 결정 구조는 1500 ℃ 이하에서 결정자의 크기와 진밀도가 증가하였으며 비표면적은 감소하였다. 저온 열처리 탄소의 물리화학적 특성 변화에 따라 음극재의 전기화학 특성이 변화하였는데 수명 특성은 H/C 원소 비, 초기 쿨롱 효율은 비표면적, 율속 특성은 진밀도의 특성에 기인하는 것으로 판단되었다.