• Title/Summary/Keyword: IEM

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MXene Based Composite Membrane for Water Purification and Power Generation: A Review (정수 및 발전을 위한 맥신(MXene) 복합막에 관한 고찰)

  • Seohyun Kim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.181-190
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    • 2023
  • Wastewater purification is one of the most important techniques for controlling environmental pollution and fulfilling the demand for freshwater supply. Various technologies, such as different types of distillations and reverse osmosis processes, need higher energy input. Capacitive deionization (CDI) is an alternative method in which power consumption is deficient and works on the supercapacitor principle. Research is going on to improve the electrode materials to improve the efficiency of the process. A reverse electrodialysis (RED) is the most commonly used desalination technology and osmotic power generator. Among many studies conducted to enhance the efficiency of RED, MXene, as an ion exchange membrane (IEM) and 2D nanofluidic channels in IEM, is rising as a promising way to improve the physical and electrochemical properties of RED. It is used alone and other polymeric materials are mixed with MXene to enhance the performance of the membrane further. The maximum desalination performances of MXene with preconditioning, Ti3C2Tx, Nafion, and hetero-structures were respectively measured, proving the potential of MXene for a promising material in the desalination industry. In terms of osmotic power generating via RED, adopting MXene as asymmetric nanofluidic ion channels in IEM significantly improved the maximum osmotic output power density, most of them surpassing the commercialization benchmark, 5 Wm-2. By connecting the number of unit cells, the output voltage reaches the point where it can directly power the electronic devices without any intermediate aid. The studies around MXene have significantly increased in recent years, yet there is more to be revealed about the application of MXene in the membrane and osmotic power-generating industry. This review discusses the electrodialysis process based on MXene composite membrane.

Numerical Investigations of Turbulent Piloted Non-Premixed Flames (난류 Pilot 비예혼합 화염장의 상세구조 해석)

  • Lee, Jeonwon;Jeon, Sangtae;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.185-186
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    • 2014
  • The multi-environment probability density function model has been applied to simulate the turbulent stratified premixed flames. The direct quadrature method of moments (DQMOM) has been adopted to solve the transport PDF equation due to its computational efficiency and robustness. The IEM mixing model is employed to represent the mixing process and the chemical mechanism is based on Gri 3.0 mechanism. Numerical results obtained in this study are precisely compared with experimental data in terms of unconditional and conditional means for scalar fields and velocity fields.

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Comparison of the Numerical, Theoretical, and Empirical Scattering Models for Randomly Rough Surfaces

  • Hong Jin-Young;Oh Yisok
    • Proceedings of the KSRS Conference
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    • 2005.10a
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    • pp.725-728
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    • 2005
  • The scattering problem of the randomly rough surface is examined by the method of moments(MoM), small perturbation method (SPM), integral equation method (IEM) and the semi-empirical polarimetic model. To apply the numerical technique of the MoM to microwave scattering from a rough surface, at first, many independent randomly rough surfaces with a rms height and a correlation length are generated with Gaussian random deviate. Then, an efficient Monte Carlo simulation technique is applied to estimate the scattering coefficients of the surfaces.

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Electrophysiological Characterization of AMPA and NMDA Receptors in Rat Dorsal Striatum

  • Jeun, Seung-Hyun;Cho, Hyeong-Seok;Kim, Ki-Jung;Li, Qing-Zhong;Sung, Ki-Wug
    • The Korean Journal of Physiology and Pharmacology
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    • v.13 no.3
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    • pp.209-214
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    • 2009
  • The striatum receives glutamatergic afferents from the cortex and thalamus, and these synaptic transmissions are mediated by ${\alpha}$-amino-3-hydroxy-5-methyl-4-isoxazolepropionate (AMPA) and N-methyl D-aspartate (NMDA) receptors. The purpose of this study was to characterize glutamate receptors by analyzing NMDA/AMPA ratio and rectification of AMPA and NMDA excitatory postsynaptic currents (EPSCs) using a whole-cell voltage-clamp method in the dorsal striatum. Receptor antagonists were used to isolate receptor or subunit specific EPSC, such as (DL)-2-amino-5-phosphonovaleric acid (APV), an NMDA receptor antagonist, ifenprodil, an NR2B antagonist, CNQX, an AMPA receptor antagonist and IEM-1460, a GluR2-lacking AMPA receptor blocker. AMPA and NMDA EPSCs were recorded at - 70 and + 40 mV, respectively. Rectification index was calculated by current ratio of EPSCs between + 50 and - 50 mV. NMDA/AMPA ratio was 0.20${\pm}$0.05, AMPA receptor ratio of GluR2-lacking/GluR2-containing subunit was 0.26${\pm}$0.05 and NMDA receptor ratio of NR2B/NR2A subunit was 0.32${\pm}$0.03. The rectification index (control 2.39${\pm}$0.27) was decreased in the presence of both APV and combination of APV and IEM-1460 (1.02${\pm}$0.11 and 0.93${\pm}$0.09, respectively). These results suggest that the major components of the striatal glutamate receptors are GluR2-containing AMPA receptors and NR2A-containing NMDA receptors. Our results may provide useful information for corticostriatal synaptic transmission and plasticity studies.

Control of Working Temperature of Isothermal Magnetic Entropy Change in La0.8Nd0.2(Fe0.88Si0.12)13 by Hydrogen Absorption for Magnetic Refrigerants

  • Fujieda, S.;Fujita, A.;Fukamichi, K.;Suzuki, S.
    • Journal of Magnetics
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    • v.18 no.2
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    • pp.150-154
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    • 2013
  • $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ and their hydrides were investigated to obtain large magnetocaloric effects (MCEs) in a wide temperature range, including room temperature, for applications in magnetic refrigents. Since the magnetization change due to the itinerant-electron metamagentic (IEM) transition for $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ becomes larger with increasing z, the isothermal magnetic entropy change ${\Delta}S_m$ and the relative cooling power (RCP) are enhanced. In addition, the Curie temperatrue $T_C$ of $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}$ is increased from 193 to 319 K by hydrogen absorption, with the IEM transition. The maximum value of $-{\Delta}S_m$, $-{\Delta}S{_m}^{max}$, in a magnetic field change of 2 T for $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}H_{1.1}$ is about 23 J/kg K at $T_C$ = 288 K, which is larger than that of 19 J/kg K at $T_C$ = 276 K for $La(Fe_{0.88}Si_{0.12})_{13}H_{1.0}$. The value of RCP = 179 J/kg of the former is also larger than 160 J/kg of the latter. It is concluded that the partial substitution of Nd improves MCEs in a wide temperautre range, including room temperature.

Proprioception and the Sense of Ownership (고유수용성 감각과 신체 소유감)

  • Sharon Yoon
    • Korean Journal of Cognitive Science
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    • v.34 no.3
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    • pp.243-257
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    • 2023
  • This paper aims to examine how proprioception provides a sense of ownership over one's body and physical actions. Proprioception is a sense that relies on somatic interoceptors rather than exteroceptors that receive external stimuli and has epistemic importance of knowing the presence, location, and movement of bodily parts. In this paper, I will argue that Shoemaker's principle, "Immunity to Error through Misidentification (IEM)" can be applied to proprioception by focusing on one of the intrinsic features of proprioception: First-Person Perspective. I will advocate the following two arguments by defeating each of Marcel's pathological counter-examples in turn. Proprioception is infallible in that it provides a sense of ownership over one's body and physical actions. Second, proprioception is indispensable for the sense of ownership of one's body and physical actions.

Performance Enhancement of Ion-Exchange Membranes Using Nanomaterials (나노물질을 이용한 이온교환막의 성능 향상)

  • Moon-Sung Kang
    • Membrane Journal
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    • v.33 no.6
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    • pp.315-324
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    • 2023
  • Ion-exchange membrane (IEM), is a key component that determines the performance of the electro-membrane processes. In this review, the latest research trends in improving the performance of IEMs used in various electro-membrane processes through modification using carbon-based and metal-based nanomaterials are investigated. The nanomaterials can be introduced into IEMs through various methods. In particular, carbon-based nanomaterials can strengthen their interaction with polymer chains by introducing additional functional groups through chemical modification. Through this, not only can the ion conductivity of IEM be improved, but also the permselectivity can be improved through the sieving effect through the layered structure. Meanwhile, metal-based nanomaterials can improve permselectivity through sieving properties using the difference in hydration radius between target ions and excluded ions within a membrane by using the property of having a layered or porous structure. In addition, depending on the characteristics of the binder used, ion conductivity can be improved through interaction between nanomaterials and binders. From this review, it can be seen that the properties of IEMs can be effectively controlled using carbon-based and metal-based nanomaterials and that research on this is important to greatly improve the performance of the electro-membrane process.

Reinforced Ion-exchange Membranes for Enhancing Membrane Capacitive Deionization (막 축전식 탈염 공정의 성능 향상을 위한 강화 이온교환막)

  • Min-Kyu Shin;Hyeon-Bee Song;Moon-Sung Kang
    • Membrane Journal
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    • v.33 no.5
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    • pp.257-268
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    • 2023
  • Membrane capacitive deionization (MCDI) is a variation of the conventional CDI process that can improve desalination efficiency by employing an ion-exchange membrane (IEM) together with a porous carbon electrode. The IEM is a key component that greatly affects the performance of MCDI. In this study, we attempted to derive the optimal fabricating factors for IEMs that can significantly improve the desalination efficiency of MCDI. For this purpose, pore-filled IEMs (PFIEMs) were then fabricated by filling the pores of the PE porous support film with monomers and carrying out in-situ photopolymerization. As a result of the experiment, the prepared PFIEMs showed excellent electrochemical properties that can be applied to various desalination and energy conversion processes. In addition, through the correlation analysis between MCDI performance and membrane characteristic parameters, it was found that controlling the degree of crosslinking of the membranes and maximizing permselectivity within a sufficiently low level of membrane electrical resistance are the most desirable membrane fabricating condition for improving MCDI performance.

Translucency of ceramic veneers on glazing effect (세라믹 비니어의 글레이징에 따른 반투명도 변화)

  • Kim, Sung-Joon;Kahm, Se Hoon
    • The Journal of Korean Academy of Prosthodontics
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    • v.53 no.2
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    • pp.138-143
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    • 2015
  • Purpose: The aim of this study was to compare the translucency of two different laminate ceramic veneers with and without glazing. Materials and methods: Ten millimeter side square-shaped specimens in 0.3 mm and 0.6 mm thick were fabricated for the following materials with and without glazing (n=80): A1 shade IPS e.maxPress (IEM) and Styleveneers (STV). The color coordinates (CIE $L^*a^*b^*$) of the specimens were measured with a colorimeter. The Translucency parameter (TP) was calculated from the color difference of the material on a black versus a white background. For comparisons between materials and between the 'not glazed' and 'glazed' groups, unpaired t-test was used to analyze the data (P=.05). Results: The TP ($Mean{\pm}SD$) of 'not-glazed' and 'glazed' group of IEM specimens at 0.3 mm thickness were $45.99{\pm}3.00$ and $49.53{\pm}2.28$ and the TP at 0.6 mm thickness were $32.82{\pm}2.59$ and $43.02{\pm}0.98$, respectively. Likewise, the TP of 'not-glazed' and 'glazed' group of STV specimens at 0.3 mm thickness were $47.03{\pm}3.65$ and $50.95{\pm}3.05$ and the TP at 0.6 mm thickness group were $34.48{\pm}1.28$ and $43.39{\pm}1.20$, respectively. As the glazing of ceramic veneer differed, the TP of each ceramic veneer showed statistically significant difference. But, the result between the products was not statistically different. Conclusion: Within the limitations of this study, we are concluded that the glazing process changed translucency of laminate ceramic veneers and the TP would not be affected by products.

A New Hydrodynamic Simulation Using Unstructured Moving Meshes

  • Yun, Kiyun;Yoon, Suk-Jin;Kim, Juhan;Kim, Sungsoo
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.1
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    • pp.50.1-50.1
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    • 2015
  • We present a new hydrodynamic simulation based on the unstructured moving mesh scheme. The simulation utilizes the Voronoi tessellation technique that produces polygonal cells composed of, on average, 13 surfaces each in 3D. We devise the incremental expanding method (IEM) and hybrid-neighbor searching algorithm and achieve the CPU time just proportional to the number of particles, i.e., O(N). We show the results of requisite tests for hydrodynamic simulations and demonstrate superiority of our code over the conventional codes using the stationary meshes. The applications in the context of cosmological and galactic simulations are also discussed.

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