• 대한화학회지
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• 제6권1호
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• pp.88-93
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• 1962

The telomerization of vinyl acetate with carbon tetrachloride, chloroform and monochlorobenzene were investigated with respect to the synthesis of those telomers, properties and molecular weights of the formed telomers, and reaction mechanisms. Vinyl acetate reacted with carbon tetrachloride and chloroform to form telomers at 70-90$^{\circ}C$ and 60-70$^{\circ}C$, respectively and it formed polymer with monochlorobenzene. As a chain transfer agent, carbon tetrachloride was more effective than chloroform. In the telomerization of vinyl acetate and carbon tetrachloride: 1) The average molecular weight of the telomer decreased as the mole ratio of carbon tetrachloride to vinyl acetate increased. The optimum conditions for the highest yield of the telomer were as follows: Mole ratio of carbon tetrachloride to vinyl acetate : 2.5 Reaction time : 20 hours. 2) As the reaction proceeded, the refractive index and average molecular weight of the telomer increased rapidly in the first 10 hours but the increase was slow through the next 10 hours, so that, the average recurring number(n) of taxogen in the final product reached an almost definite value, i.e., 3. The telomer formed in the telomerization of vinyl acetate with carbon tetrachloride and chloroform turned to brown color in the air due to decomposition or polymerization. The suggested telomerization mechanism was supported by the hexachloroethane detected in the course of reaction.

• 한국자기학회지
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• 제8권2호
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• pp.79-85
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• 1998

e-beam evaporator로 [Ni80Fe20/Cu/Co/Cu] 다층박막을 증착하여 자성층 사이의 교환 결합 상태에 따라 Co를 Ni80Fe20/Cu 계면에 삽입, 자기 저항비와 자기 저항비와 자화 곡선의 변화를 연구하였다. 강자성 결합 및 비 결합에서는, 계면에 Co를 삽입하게 되면, 자기 저한 값이 증가하지만 반강자성 결합에서는 자기 저항 값이 감소하는 경향이 보였다. 이러한 원인은 계면에 삽입되는 Co가 계면 산란을 증가시키는 것 뿐만 아니라 자성층 간의 교환 결합상태를 변화 시키기 때문에 것으로 판단된다. 아울러 계면에 삽입된 Co는 박막의 다층 구조를 30$0^{\circ}C$ 이상까지 유지시키며 이는 Cork 효과적인 확산 장애물(diffusion barrier)역할을 하기 때문으로 판단된다.

• 한국식품과학회지
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• 제10권4호
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• pp.371-375
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• 1978

쌀 다수확 장려품종의 단백질의 양적 및 질적 평가를 위해 기존장려품종 1종(Jinheung)과 장려품종 5종(Tongil, Suwon 264, Ishin, Iri 326, Milyang 23)의 아미노산 조성을 분석하였다. 진흥, 통일, 수원, 유신, 이리, 밀양 등의 단백질 함량은 각각 8.16%, 8.77%, 9.36%, 9.43%, 9.63%이고 E/T ratio는 각각 1.83, 2.10, 2.04, 2.01, 2.11, 1.93이였으며 A/E비 화학가는 각각 94.9, 84.8, 83.2, 80.8, 78.4, 89.5이였으며 제 1제한아미노산은 진흥은 isoleucine이였고 그의 모두는 lysine이였다.

• 한국해양공학회지
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• 제13권4호통권35호
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• pp.151-158
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• 1999

A model harbour with Plan scale of $1.08{\times}1.08m$ is built on a tidal tank using a Froude relationship from a real harbour($432{\times}432m$). Velocity components are measured by a ultrasonic velocity meter and flow structure is then predicted using a 2-D depth integrated hydrodynamic model. In the finite difference model implemented in this study, various wall boundary conditions, i.e. no-slip, free-slip, partial-slip and semi-slip are used to represent turbulent diffusion terms, e.g. ${\partial}^2U_{ij}/{\partial}x^2\;or\;{\partial}^2U_{ij}/{\partial}y^2$. These conditions are focused to investigate their influence on the flow structure along the wall and basin of the harbour with aspect ratio of unity, i.e. Length/Breadth. Numerical experiments are compared with the measurements and used to analyse flow patterns in the basin during tidal cycles. It is shown from the results that no-slip closed boundary condition is the most appropriate method with respect to the location of the eddy centre, although the condition underestimates velocity components along the wall.

• The Journal of the Acoustical Society of Korea
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• 제29권3E호
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• pp.131-139
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• 2010

This paper proposes a novel spectral hole substitution technique for low bit-rate audio coding. The spectral holes frequently occurring in relatively weak energy bands due to zero bit quantization result in severe quality degradation, especially for harmonic signals such as speech vowels. The enhanced aacPlus (EAAC) audio codec artificially adjusts the minimum signal-to-mask ratio (SMR) to reduce the number of spectral holes, but it still produces noisy sound. The proposed method selectively predicts the spectral shapes of hole bands using either intra-band correlation, i.e. harmonically related coefficients nearby or inter-band correlation, i.e. previous frames. For the bands that have low prediction gain, only the energy term is quantized and spectral shapes are replaced by pseudo random values in the decoding stage. To minimize perceptual distortion caused by spectral mismatching, the criterion of the just noticeable level difference (JNLD) and spectral similarity between original and predicted shapes are adopted for quantizing the energy term. Simulation results show that the proposed method implemented into the EAAC baseline coder significantly improves speech quality at low bit-rates while keeping equivalent quality for mixed and music contents.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2020년도 학술발표회
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• pp.4-4
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• 2020

Three wildfires severely damaged local towns and forests in Gangwon-do, South Korea in 2019 April 4-5. Local hydrological regime could be greatly altered by the wildfires, therefore it is important to assess its damage (e.g. area and severity) and also resultant changes in hydrological fluxes. We retrieved the Normalized-Burned Ratio (NBR) index using remote-sensing data (Moderate Resolution Imaging Spectroradiometer (MODIS) 500-m 8-day surface reflectance data), and delineated the damaged-area based on the difference in the NBR (dNBR) before and after the wildfires. We then estimated changes in the annual evapotranspiration (AET) in 2019 using the MODIS evapotranspiration data (500-m 8-day). It was found that the damaged-area of the three wildfires was 29.50 km^2 in total, which take up 1.00-6.19% area of five catchments. It was estimated that the AET would be decreased as 0.05-1.56% over those five catchments, as compared to the pre-fire AET (2004-2018). The impact of the wildfires on the catchment AET was less severe than expected (i.e. up to 1.56%) mostly because two big wildfires were distributed across two catchments respectively (i.e. four catchments for the two wildfires) and the other wildfire was small and not severe. This study highlights the importance of assessing the area and severity of a wildfire when estimating its impact on the local hydrological cycle.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2006년도 춘계학술대회 논문집
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• pp.239-242
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• 2006

LCD-BLU (Liquid Crystal Display - Back Light Unit) is one of kernel parts of LCD unit and it consists of several optical sheets(such as prism, diffuser and protector sheets), LGP (Light Guiding Plate), light source (CCFL or LED) and mold frame. The LGP of LCD-BLU is usually manufactured by forming numerous dots with $50{\sim}200$ um in diameter on it by etching process. But the surface of the etched dots of LGP is very rough due to the characteristics of the etching process during the mold fabrication, so that its light loss is high along with the dispersion of light into the surface. Accordingly, there is a limit in raising the luminance of LCD-BLU. In order to overcome the limit of current etched dot patterned LGP, optical pattern design with 50um micro-lens was applied in the present study. The micro-lens pattern fabricated by modified LiGA with thermal reflow process was applied to the optical design of LGP. The attention was paid to the effects of different aspect ratio (i.e. $0.2{\sim}0.5$) of optical pattern conditions to the brightness distribution of BLU with micro-lens patterned LGP. Finally, high aspect ratio micro-lens patterned LGP showed superior results to the one made by low aspect ratio in average luminance.

• 한국분무공학회지
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• 제28권4호
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• pp.176-183
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• 2023

Many countries are striving to reduce carbon emissions with the goal of net zero by 2050. Accordingly, vehicles are rapidly being electrified to reduce greenhouse gases in the transportation sector. However, many organizations predict that internal combustion engines of LDV (light-duty vehicle) will exist even in 2050, and it is difficult to electrify aircraft and large ships in a short time. Therefore, synthetic fuel (i.e., e-Fuel) that can reduce carbon emissions and replace existing fossil fuels is in the spotlight. The e-Fuel refers to a fuel synthesized by using carbon obtained through various carbon capture technologies and green hydrogen produced by eco-friendly renewable energy. The purpose of this study is to compare and analyze the injection and spray characteristics of the simulated e-Gasoline. We mixed the hydrocarbon fuel components according to the composition ratio of the synthetic fuel produced based on the FT(Fischer-Tropsch) process. As a result of injection rate measurement, simulated e-Gasoline showed no significant difference in injection delay and injection period compared to standard gasoline. However, due to the low vapor pressure of the simulated e-Gasoline, the spray tip penetration (STP) was lower, and the size of spray droplets was larger than that of traditional gasoline.

• Earthquakes and Structures
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• 제24권6호
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• pp.455-475
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• 2023

The present study investigates the non-linear soil-pile interaction using three-dimensional (3D) non-linear finite element models. The numerical models were validated by using the results of extensive pile load and shaking table tests. The pile performance in liquefiable and non-liquefiable soil has been studied by analyzing the liquefaction ratio, pile lateral displacement (LD), pile bending moment (BM), and frictional resistance (FR) results. The pile models have been developed for the different ground conditions. The study reveals that the results obtained during the pile load test and shaking cycles have good agreement with the predicted pile and soil response. The soil density, peak ground acceleration (PGA), slenderness ratio (L/D), and soil condition (i.e., dry and saturated) are considered during modeling. Four ground motions are used for the non-linear time history analyses. Consequently, design charts are proposed depended on the analysis results to be used for design practice. Eleven models have been used to validate the capability of these charts to capture the soil-pile response under different seismic intensities. The results of the present study demonstrate that L/D ratio slightly affects the lateral displacement when compared with other parameters. Also, it has been observed that the increasing in PGA and decreasing L/D decreases the excess pore water pressure ratio; i.e., increasing PGA from 0.1 g to 0.82 g of loose sand model, decrease the liquefaction ratio by about 50%, and increasing L/D from 15 to 75 of the similar models (under Kobe earthquake), increase this ratio by about 30%. This study reveals that the lateral displacement increases nonlinearly under both dry and saturated conditions as the PGA increases. Similarly, it is observed that the BM increases under both dry and saturated states as the L/D ratio increases. Regarding the acceleration histories, the pile BM was reduced by reducing the acceleration intensity. Hence, the pile BM decreased to about 31% when the applied ground motion switched from Kobe (PGA=0.82 g) to Ali Algharbi (PGA=0.10 g). This study reveals that the soil conditions affect the relationship pattern between the FR and the PGA. Also, this research could be helpful in understanding the threat of earthquakes in different ground characteristics.

• 대한한의학회지
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• 제23권1호
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• pp.37-49
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• 2002

Objectives: Maekmoondong-tang and Jeongcheonhwadamgangki-tang are herbal decoctions which have been used as traditional therapeutic agents for asthma. This study was performed to investigate the effects of Maekmoondong-tang and Jeongcheonhwadamgangki-tang on immune Cell & serum OA-specific 19B in broncho-alveolar lavage fluid (BALF) in rat asthma model. Methods: Rats were sensitized with ovalbumin (OA); at day I the sensitized group and Maekmoondong-tang and Jeongcheonhwadamgangki-tang groups were systemically immunized by subcutaneous injection of 1mg OA and 300mg of $Al(OH)_3$ in a total volume of 2ml. At the same time, 1ml of 0.9% saline containing $6{\times}10^9$ B. pertussis bacilli was injected by i.p. for 14 days. After systemic immunization, the rats received local immunization by inhaling 0.9% saline aerosol containing 2% (wt/vol) OA. A day after local immunization, BAL fluid was collected from the rats. A day after local immunization, rats were orally administered with each of Maekmoondong-tang and Jeongcheonhwadamgangki-tang extract for 14 days. Lymphocyte, CD4+T-cell CD8+ T-cell counts, CD4+/CD8+ ratio in BALF, change of serum OA-specific IgE level, and CD4+T-cell CD8+T-cell percentage in the peripheral blood were measured and evaluated. Results: Maekmoondong-tang and Jeongcheonhwadamgangki-tang showed a suppressive effect on the rat asthma model. Maekmoondong-tang decreased total cell, lymphocyte, CD4+T-cell, CD8+T-cell in BALF, and serum OA specific 19B level as compared with the control group, whereas Maekmoondong-tang decreased CD4+/CD8+ ratio in BALF with statistical nonsignificance as compared with the control group. 1 decreased total cell, CD4+T-cell, CD4+/CD8+ ratio in BALF, and serum OA specific IgE level, whereas Jeongcheonhwadamgangki-tang decreased ymphocyte, and CD8+T-cell in BALF with statistical nonsignificance as compared with the control group. CD4+T-cell and CD8+ T-cell percentage in peripheral blood were not changed significantly in all the experimental groups. Conclusions: This study shows that Maekmoondong-tang and Jeongcheonhwadamgangki-tang have a suppressive effect on asthma. Maekmooruiong-tang and Jeongcheonhwadamgangki-tang would be useful asthma treatment agents.