• Journal of Korean Society for Atmospheric Environment
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• v.22 no.E1
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• pp.9-18
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• 2006

Aerosol hygroscopic properties were measured by a tandem differential mobility analyzer (TDMA) system during the Aerosol Characterization Experiment (ACE)-Asia campaign from 31 March to 1 May 2001. Two high flow differential mobility analyzers (DMAs) were used to maximize the count rate on board the Center for Interdisciplinary Remotely Piloted Aircraft (CIRPAS) Twin Otter aircraft. Hygroscopic growth factor distributions of particles having initial dry nanoparticle diameters of 0.040, 0.059, 0.086, 0.126, 0.186, 0.273, 0.400, and $0.586{\mu}m$ were measured during 19 research flights. Data collected during 12 of those flights were used to investigate aerosol mixing state and the influence of aerosol source region on size-resolved hygroscopicity. The uniformity in size-resolved hygroscopicity was quantified to facilitate comparison between measurements made in different air masses. Hygroscopic growth factors are strongly dependent on source region and sizes. Mean hygroscopic growth factors were observed to be greatest when the air mass origin was from the south. The mean growth factors for continental sources decreased with initial size from 1.47 to 1.27 for $0.040{\mu}m\;and\;0.586{\mu}m$, but increased with initial size from 1.44 to 1.8 for $0.040{\mu}m\;and\;0.400{\mu}m$ dry diameters for marine sources.

• Journal of ILASS-Korea
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• v.3 no.3
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• pp.14-22
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• 1998

The growth by steam condensation of an hygroscopic aerosol is investigated using the condensation rate model which has been derived from the mass and heat transfer equations. The present model accounts for both the solute and Kelvin effects. When the hygroscopicity is considered, condensation can occur on hygroscopic seed particles even under subsaturated steam conditions. This study focuses on the effect of hygroscopicity on the evolution of the particle size distribution and decay of the total aerosol concentration. It is found that hygroscopicity causes the particle size distribution to rapidly move upward even in a very short time, resulting in substantially higher decay of the total aerosol concentration than the case without considering hygroscopicity.

• Journal of ILASS-Korea
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• v.3 no.4
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• pp.25-34
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• 1998

Hygroscopic aerosols can rapidly grow in size by steam condensation even under subsaturated steam conditions. Much efforts have been made to handle this process, but there have been computational difficulties in handling the condensational growth of hygroscopic aerosols by contentional methods. A recently released computer code, CONTAIN 2.0, employs a new technique called Moving Sectional Method(MSM) to handle the growth of hygroscopic aerosols. As a part of the model verification efforts, we have used the code to simulate the VANAM M3U hygroscopic aerosol experiment. We assess the accuracies of the new MSM and the conventional Fixed Sectional Method(ESM) based on the simulation results. Also presented are discussions about the robustness of the MSM.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2006.04a
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• pp.55-56
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• 2006

This thesis describes the use of measured aerosol size distributions and size-resolved hygroscopic growth to examine the physical and chemical properties of several particle classes. The primary objective of this work was to investigate the optical and cloud forming properties of a range of ambient aerosol types measured in a number of different locations. The tool used for most of these analyses is a differential mobility analyzer / tandem differential mobility analyzer (DMA / TDMA) system developed in our research group. To collect the data described in two of the chapters of this thesis, an aircraft-based version of the DMA / TDMA was deployed to Japan and California. The data described in two other chapters were conveniently collected during a period when the aerosol of interest came to us. The unique aspect of this analysis is the use of these data to isolate the size distributions of distinct aerosol types in order to quantify their optical and cloud forming properties. I used collected data during the Asian Aerosol Characterization Experiment (ACE-Asia) to examine the composition and homogeneity of a complex aerosol generated in the deserts and urban regions of China and other Asian countries. An aircraft-based tandem differential mobility analyzer was used for the first time during this campaign to examine the size-resolved hygroscopic properties of particles having diameters between 40 and 586 nm. Asian Dust Above Monterey (ADAM-2003) study was designed both to evaluate the degree to which models can predict the long-range transport of Asian dust, and to examine the physical and optical properties of that aged dust upon reaching the California coast. Aerosol size distributions and hygroscopic growth are measured in College Station, TX to investigate the cloud nucleating and optical properties of a biomass burning aerosol generated from fires on the Yucatan Peninsula. Measured aerosol size distributions and size-resolved hygroscopicity and volatility were used to infer critical supersaturation distributions of the distinct particle types that were observed during this period. The predicted CCN concentrations were used in a cloud model to determine the impact of the different aerosol types on the expected cloud droplet concentration. RH-dependent aerosol extinction coefficients are calculated at a wavelength of 550 nm.

• Asian Journal of Atmospheric Environment
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• v.7 no.3
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• pp.129-138
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• 2013

The water uptake by fine aerosol in the atmosphere has been investigated at Gosan, Korea during ABC-EAREX 2005. The concentration of inorganic ion and carbon components, size distribution, and light scattering coefficients in normal and dry conditions were simultaneously measured for $PM_{2.5}$ by using a parallel integrated monitoring system. The result of this study shows that ambient fine particles collected at Gosan were dominated by water-soluble ionic species (35%) and carbonaceous materials (18%). In addition, it shows the large growth of aerosol in the droplet mode when RH is higher than 70%. Size distribution of the particulate surface area in a wider size range ($0.07-17{\mu}m$) shows that the elevation of RH make ambient aerosol grow to be the droplet mode one around $0.6{\mu}m$ or the coarse mode one, larger than $2.5{\mu}m$. Hygroscopic factor data calculated from the ratio of aerosol scattering coefficients at a given ambient RH and a reference RH (25%) show that water uptake began at the intermediate RH range, from 40% to 60%, with the average hygroscopic factor of 1.10 for 40% RH, 1.11 for 50% RH, and 1.17 for 60% RH, respectively. Finally, average chemical composition and the corresponding growth curves were analyzed in order to investigate the relationship between carbonaceous material fraction and hygroscopicity. As a result, the aerosol growth curve shows that inorganic salts such as sulphate and nitrate as well as carbonaceous materials including OC largely contribute to the aerosol water uptake.

• Journal of Environmental Science International
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• v.16 no.7
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• pp.793-798
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• 2007

During May of 2003, smoke from fires in the Yucatan Peninsula was transported across the Gulf of Mexico and into Texas where it caused significant enhancement in measured aerosol concentrations and reduced visibility. During this event, the formation and growth of aerosol particles has been observed by a differential mobility analyzer (DMA) / tandem differential mobility analyzer (TDMA) system to characterize the size distribution and size-resolved hygroscopicity of the aerosol. The most number concentration is by the particles smaller than 100 nm, but the integrated number concentrations for over 100 nm increased due to the aerosol growth. Hygroscopic growth factor increase from 1.2 to 1.4 for 25, 50, and 100 nm particles during the nucleating period. This distribution and the aerosol properties derived from the TDMA data were used to calculate the growth rate. Particle growth rates were in the range 1-12 nm/hr.

• Particle and aerosol research
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• v.5 no.2
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• pp.45-52
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• 2009

Black carbon, which is a by-product of combustion of fossil fuel and biomass burning, is the component that imposes the largest uncertainty on quantifying aerosol climate effect. The direct, indirect and semi-direct climate effects of black carbon depend on its state of the mixing with other water-soluble aerosol components. The process that transforms hydrophobic externally mixed black carbon particles into hygroscopic internally mixed ones is called "aging". In most climate models, simple parameterizations for the aging time scale are used instead of solving detailed dynamics equations on the aging process due to the computation cost. In this study, a new parameterization for the black carbon aging time scale due to condensation and coagulation is presented as a function of the concentration of hygroscopic atmospheric components and the black carbon particle size. It is shown that the black carbon aging time scale due to condensation of sulfuric acid vapors varies to a large extent depending on the sulfuric acid concentration and the black carbon particle size. This result indicates that the constant aging time scale values suggested in the literature cannot be directly applied to a global scale modeling. The aging time scale due to coagulation with internally mixed aerosol particles shows an even stronger dependency on particle size, which implies that the use of a particle-size-independent aging time scale may lead to a large error when the aging is dominated by coagulation.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2006.04a
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• pp.222-223
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• 2006

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2008.10a
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• pp.264-265
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• 2008

• Particle and aerosol research
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• v.6 no.4
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• pp.151-164
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• 2010

Inorganic ions and water are major components of ambient fine particles. Water content in fine particles is mainly determined by ambient meteorological conditions and the concentrations of hygroscopic species such as inorganic ions. Thus, to reduce fine particle mass concentration, it is important to accurately estimate the relationship between water content and the concentration of ions in fine particles. Water content in fine particles in Seoul are estimated by using a gas/particle equilibrium model to understand the characteristics of fine particle mass concentration. In addition, sensitivity of fine particle mass concentration to the changes of particulate ionic species (sulfate, nitrate, and ammonium) is estimated. It was found that water content in Seoul is mostly determined by the concentrations of the hygroscopic ionic species, especially, sulfate and ammonium, and ambient relative humidity.