• Title/Summary/Keyword: Hydroxyethyl cellulose

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Influence of Artificial Tear Containing Carboxymethyl Cellulose Component on Physical Properties of Hydrogel Contact lens (카르복시메칠 셀룰로오스 성분이 포함된 인공누액이 하이드로젤 콘택트렌즈의 물성에 미치는 영향)

  • Cho, Seon-Ahr;Sung, A-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.4
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    • pp.457-463
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    • 2013
  • To determine the impact of artificial tears which include carboxymethyl cellulose on a hydrogel contact lenses. Methods: A contact lenses made of the cross-linking agent, EGDMA (ethylene glycol dimethacrylate) and HEMA (2-hydroxyethyl methacrylate) and with added NVP (n-vinyl-2-pyrrolidone) and MMA (methyl methacrylate) was evaluated for water content, refractive index, spectral transmittance and contact angle of produced contact lens. Results: The physical properties of the sampled copolymerized polymers showed that water content, refractive index, visible ray transmittance and contact angle were in the range of 26.61%~48.58%, 1.422~1.455, 80.8%~91.4% and $33.93^{\circ}{\sim}65.70^{\circ}$, respectively. In addition, after soaking with artificial tears, the water content, refractive index and contact angle were in the range of 24.46%~48.25%, 1.422~1.457, 77.0%~91.0% and $37.25^{\circ}{\sim}77.33^{\circ}$, respectively. The changes of the physical property depending on hydration time and showed an increase of refractive index and contact angle, decrease of water content and visible ray transmittance. Conclusions: Artificial tears which include carboxymethyl cellulose sodium which is used as a wetting agent influenced water content, refractive index, contact angle and spectral transmittance of a hydrogel contact lenses.

Identification of Pelleting Materials and Effect of Nutrient Addition on the Germination of Pelleted Lettuce Seeds (상추 펠렛종자의 피복물질 탐색과 영양물질 첨가가 발아력에 미치는 영향)

  • Kang, Jum-Soon
    • Journal of Bio-Environment Control
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    • v.13 no.1
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    • pp.8-15
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    • 2004
  • Seedling mechanization of lettuce is known to be difficult due to the small seed size and the irregular seed shape. The purpose of seed pelleting is to make seedling mechanization possible by enlarging the seed size. After that, it can reduce seedling and thinning labours and can also save seeds. According to the results, there were significant differences on the percent germination and day to 50% final germination in accordance with the pelleting polymer. Among the pelleting polymer, gemination of seeds using polynimyl alcohol (PVA) was generally smooth, and followed by polyvinyl pyrrolidone (PVP), hydroxyethyl cellulose (HEC), methyl cellulose (MC), and wteen 80. The germination rate was also different according to the pelleting particulate matters. Generally, percent germination and speed of seed using the mixture of diatomaceous earth, talc and calcium carbonate were higher and faster than using other polleting materials, respectively. Thus, it should be suitable pelleting particulate matter for the pelleting of lettuce seeds. On the other hands germination of seeds using limestone, calcium oxide and benonite were low. The seed size of lettuce after pelleting was 33 times as large as the raw seed size. During the process of seed pelleting, netrient addition induced the decrement on the germination and the delay of germination speed. Also, there was differences in the germinability of pelleted seeds in accordance with the addition of nutrient sources. MS medium was generally lower than monosodium phosphate in inhibition of seed germination. Germination of pelleted seeds after priming was higher than the seeds without the treatment, and also showed the trend of early germination.

A Second Thioltransferase of Schizosaccharomyces pombe Contains Glutathione S-transferase Activity

  • Kim, Hong-Gyum;Park, Eun-Hee;Lim, Chang-Jin
    • BMB Reports
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    • v.32 no.6
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    • pp.535-540
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    • 1999
  • Two types of the thioltransferase (also called glutaredoxin) have been previously detected in the cytosolic extract of Schizosaccharomyces pombe, a fission yeast. Previously, the one with a smaller molecular mass (14kDa) was purified and characterized. In the present study, the second thioltransferase was purified. The purification procedure included ammonium sulfate fractionation (40-80%), Sephadex G-200 gel filtration, DEAE-cellulose ion-exchange chromatography, Sephadex G-50 gel filtration, and glutathione-agarose affinity chromatography. The purified enzyme showed a single band on SDS-PAGE, and its molecular mass was determined to be 23 kDa. It utilizes various compounds as substrates, including 2-hydroxyethyl disulfide. Interestingly, we found that the purified thioltransferase also contains significant glutathione S-transferase activity.

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Performance of Latex Modified Cementitious Repair material for Concrete Structures (콘크리트 보수용 라텍스 개질 시멘트계 보수 재료의 특성)

  • Lee, Sang-Woo;Park, Sung-Ki;Sung, Sang-Kyoung;Lee, Jae-Young;Kim, Wan-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.289-292
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    • 2006
  • The purpose of this study was to evaluate a performance of latex-modified repair material applied to the substrate concrete. The experimental variables were latex-cement ratios (5, 10, 15%), polymer(0.5%, 1%) and admixtures. The flow, air content, compressive strength, flexural strength were tested. Test results showed that compressive and flexural strength decreased by adding hydroxyethyl cellulose and increasing water-binder ratio. The compressive and flexural strength were increased when addition of defoamer.

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Fabrication of Gel-type Electrolyte for the Development of Reference Electrode for Sea Water and Application to Measuring Equipment for Total Residual Oxidants (해수용 기준전극 개발을 위한 겔 타입 내부전해질 제조 및 잔류염소 측정장치에의 적용)

  • Kim, Yu-Jin;Lee, Hae-Don;Kim, Dae-Won
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.153-157
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    • 2017
  • Gel type internal electrolytes were synthesized by varying hydroxyethyl-cellulose (HEC) amounts and their durability and conductivity were measured. The ionic conductivity decreased as the content of HEC increased thus the internal electrolyte containing more than 12% of HEC could not be used as a reference electrode. Based on durability test results, as the HEC amount decreased carrier density resulting in increasing of the amount of KCl coming out of the porous membrane. Therefore in order to use long time at ballast water treatment systems, we selected 10% HEC for gel type internal electrolyte. The resolution test for total residual oxidants (TRO) was carried out using the TRO sensor and the gel type reference electrode made of 10% HEC. A 50 mV potential was applied to the TRO sensor for 30 sec and changes in the current were measured. It was confirmed that the TRO concentrations ranging from 0 to 15 mg/L could be separated at salinity conditions of 0.2~30 PSU. The results indicated that the TRO concentration at sea water and at fresh water was successfully measured by the TRO sensor constructed with the reference electrode using gel-type internal electrolyte of HEC.

Shear-induced structure and dynamics of hydrophobically modified hydroxy ethyl cellulose (hmHEC) in the presence of SDS

  • Tirtaatmadija, Viyada;Cooper-white, Justin J.;Gason, Samuel J.
    • Korea-Australia Rheology Journal
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    • v.14 no.4
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    • pp.189-201
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    • 2002
  • The interaction between hydrophobically modified hydroxyethyl cellulose (hmHEC), containing approximately 1 wt% side-alkyl chains of $C_{16}$, and an anionic sodium dodecyl sulphate (SDS) surfactant was investigated. For a semi-dilute solution of 0.5 wt% hmHEC, the previously observed behaviour of a maximum in solution viscosity at intermediate SDS concentrations, followed by a drop at higher SDS concentrations, until above the cmc of surfactant when the solution resembles that of the unsubstituted polymer, was confirmed. Additionally, a two-phase region containing a hydrogel phase and a water-like supernatant was found at low SDS concentrations up to 0.2 wt%, a concentration which is akin to the critical association concentration, cac, of SDS in the presence of hmHEC. Above this concentration, SDS molecules bind strongly to form mixed micellar aggregates with the polymer alkyl side-chains, thus strengthening the network junctions, resulting in the observed increase in viscosity and elastic modulus of the solution. The shear behaviour of this polymer-surfactant complex during steady and step stress experiments was examined In great detail. Between SDS concentrations of 0.2 and 0.25 wt%, the shear viscosity of the hmHEC-polymer complex network undergoes shear-induced thickening, followed by a two-stage shear-induced fracture or break-up of the network. The thickening is thought to be due to structural rearrangement, causing the network of flexible polymers to expand, enabling some polymer hydrophobic groups to be converted from intra- to inter-chain associations. At higher applied stress, a partial local break-up of the network occurs, while at even higher stress, above the critical or network yield stress, a complete fracture of the network into small microgel-like units, Is believed to occur. This second network rupture is progressive with time of shear and no steady state in viscosity was observed even after 300 s. The structure which was reformed after the cessation of shear is found to be significantly different from the original state.

Enzymatic Characteristics of a Highly Thermostable β-(1-4)-Glucanase from Fervidobacterium islandicum AW-1 (KCTC 4680)

  • Jeong, Woo Soo;Seo, Dong Ho;Jung, Jong Hyun;Jung, Dong Hyun;Lee, Dong-Woo;Park, Young-Seo;Park, Cheon-Seok
    • Journal of Microbiology and Biotechnology
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    • v.27 no.2
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    • pp.271-276
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    • 2017
  • A highly thermostable ${\beta}-(1-4)-glucanase$ (NA23_08975) gene (fig) from Fervidobacterium islandicum AW-1, a native-feather degrading thermophilic eubacterium, was cloned and expressed in Escherichia coli. The recombinant FiG (rFiG) protein showed strong activity toward ${\beta}-{\small{D}}-glucan$ from barley (367.0 IU/mg), galactomannan (174.0 IU/mg), and 4-nitrophenyl-cellobioside (66.1 IU/mg), but relatively weak activity was observed with hydroxyethyl cellulose (5.3 IU/mg), carboxymethyl cellulose (2.4 IU/mg), and xylan from oat spelt (1.4 IU/mg). rFiG exhibited optimal activity at $90^{\circ}C$ and pH 5.0. In addition, this enzyme was extremely thermostable, showing a half-life of 113 h at $85^{\circ}C$. These results indicate that rFiG could be used for hydrolysis of cellulosic and hemicellulosic biomass substrates for biofuel production.

Manufacture and Characteristics of Peel-off Pack for Natural Cosmetics Using Pullulan and Polysaccharides (Pullulan과 Polysaccharides를 이용한 천연화장품용 필 오프 팩의 제조 및 특성)

  • Jun Soo Kwak;So Young Jung;So Min Lee;Seok-Ju Lee;Sofia Brito;Byungsun Cha;Hyojin Heo;Lei Lei;Sang Hun Lee;Ha-Hyeon Jo;You-Yeon Chun;Ye Ji Kim;Hyung Mook Kim;Mi-Gi Lee;Byeong-Mun Kwak;Bum-Ho Bin
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.1
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    • pp.67-74
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    • 2023
  • In this study, for a natural cosmetics market, we sought to explore alternatives that can replace polyvinyl alcohol (PVA) of peel-off packs. A peel-off type pack was prepared by combining pullulan, a water-soluble polysaccharide, and other polysaccharides (sodium hyaluronate, cellulose gum, hydroxyethyl cellulose, sodium alginate, corn starch), and the pH, viscosity, and stability against temperature of each peel-off type pack were confirmed. The thickness and tensile strength of the manufactured film were measured for comparison with the PVA peel-off type pack, and applicability, drying speed, and removal degree were measured. Among them, the pullulan-sodium hyaluronate peel-off type pack showed excellent film formation ability to replace the peel-off type pack containing PVA with 5.12% thin film thickness and 4.23% high film tensile strength. When applied to actual skin, the degree of spread of the pack, the usability that can be uniformly applied, and the formation and removal strength of the film when removed after drying were also similar to the peel-off type pack containing PVA. Therefore, it was confirmed that the film formed of pullulan-sodium hyaluronate showed enough physical properties to replace the PVA of the peel-off type pack as a natural peel-off type pack.

An L-Type Thioltransferase from Arabidopsis thaliana Leaves

  • Kim, Tae-Soo;Cho, Young-Wook;Kim, Joon-Chul;Jin, Chang-Duck;Han, Tae-Jin;Park, Soo-Sun;Lim, Chang-Jin
    • BMB Reports
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    • v.32 no.6
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    • pp.605-609
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    • 1999
  • Thioltransferase, also called glutaredoxin, is a general GSH-disulfide reductase of importance for redox regulation. Previously, the protein thioltransferase, now called S-type thioltransferase, was purified and characterized from Arabidopsis thaliana seed. In the present study, a second thioltransferase, called L-type thioltransferase, was purified to homogeneity from Arabidopsis thaliana leaves. The purification procedures included DEAE-cellulose ion-exchange chromatography, Sephadex G-50 gel filtration, and glutathione-agarose affinity chromatography. The purified enzyme was confirmed to show a unique band on SDS-PAGE and its molecular weight was estimated to be 26.6 kDa, which appeared to be atypical compared with those of most other thioltransferase. It could utilize 2-hydroxyethyl disulfide, S-sulfocysteine, and insulin as substrates, and also contained dehydroascorbate reductase activity. Its optimum pH was 8.5 and its activity was greatly activated by L-cysteine. When it was kept for 30 min, it appeared to be very stable up to $70^{\circ}C$. It was activated by $MgCl_2$ and, on the contrary, inhibited by $ZnCl_2$, $MnCl_2$, and $AlCl_3$.

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Fiber-optic humidity sensor system for the monitoring and detection of coolant leakage in nuclear power plants

  • Kim, Hye Jin;Shin, Hyun Young;Pyeon, Cheol Ho;Kim, Sin;Lee, Bongsoo
    • Nuclear Engineering and Technology
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    • v.52 no.8
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    • pp.1689-1696
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    • 2020
  • In this study, we developed a fiber-optic humidity sensor (FOHS) system for the monitoring and detection of coolant leakage in nuclear power plants. The FOHS system includes an FOHS, a spectrometer, a halogen white-light source, and a Y-coupler. The FOHS is composed of a humidity-sensing material, a metal tube, a multi-mode plastic optical fiber, and a subminiature version A (SMA) fiber-optic connector. The humidity-sensing material is synthesized from a mixture of polyvinylidene fluoride (PVDF) in dimethyl sulfoxide (DMSO) and hydroxyethyl cellulose (HEC) in distilled water. We measured the optical intensity of the light signals reflected from the FOHS placed inside the humidity chamber with relative humidity (RH) variation from 40 to 95%. We found that the optical intensity of the sensing probe increased linearly with the RH. The reversibility and reproducibility of the FOHS were also evaluated.