• Title/Summary/Keyword: Hydrothermal Pretreatment

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Adsorption Characteristics of Biochar from Wood Waste by KOH, NaOH, ZnCl2 Chemical Activation (폐목재를 이용한 KOH, NaOH, ZnCl2 화학적 활성화로 생성된 바이오차의 흡착특성에 관한 연구)

  • MinHee Won;WooRi Cho;Jin Man Chang;Jai-young Lee
    • Clean Technology
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    • v.29 no.4
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    • pp.272-278
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    • 2023
  • There is a lot of interest in methods for pollutants using adsorption, and recent research is being conducted to show that biochar can be used to remove organic and inorganic pollutants. In particular, wood waste as waste biomass requires a biomass recycling method, and a method to increase the adsorption capacity of biochar produced using wood waste is needed. Biochar is created by Hydrothermal carbonization (HTC) using, which uses low temperature and high pressure, has low energy consumption and does not require moisture removal pretreatment, and biochar is created through chemical activation using KOH, NaOH, and ZnCl2 chemicals. The adsorption characteristics of biochar were determined by analyzing iodine adsorptivity, specific surface area, pore diameter, pore volume, pore distribution, and SEM according to the activation. The results of analyzing the selecting biochar by activating the biochar produced at HTC 300℃, 4 hr by KOH, NaOH, and ZnCl2 chemicals, the specific surface area was 774~1.387 m2/g, showing a high specific surface area similar to activated carbon, and it was confirmed that micropores with an average pore diameter in the range of 21~24 Å were formed. As a result of SEM observation, the surface was uniform with a certain shape depending on activation. It was confirmed that one pore was developed and the number of pores increased.