• Title/Summary/Keyword: Hydrophilic surface

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${\mu}-PIV$ Visualization of Flow in Hydrophilic and Hydrophobic Micro-nozzle (친수성 및 소수성 마이크로 노즐 내 유동 ${\mu}-PIV$ 연구)

  • Byun, Do-Young;Kim, Ji-Hoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.15-18
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    • 2006
  • Recently, experimental visualization of microscale fluid transport has attacted considerable attention in designing microelectromechanical systems. Fluid-surface interactions on hydrophobic and hydrophilic surfaces can play a key role in passively controlling microfluidics. Here we investigate the slip boundary condition depending on the surface characteristics; hydrophilic, hydrophobic wettabilities. Using the micro-PIV, velocity profiles are measured in the glass (hydrophilic), PDMS (hydrophobic) microchannels.

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The Analysis of Surface Characteristics of the Hydrophilic Chemicals Treated PET Fibers using Tensiometric Methods (Tensiometric법을 이용한 친수하 PET 섬유의 표면특성 분석)

  • Chung Hae Won;Obendorf S. Kay
    • Journal of the Korean Society of Clothing and Textiles
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    • v.15 no.4 s.40
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    • pp.431-435
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    • 1991
  • The dispersion and Poiar force components of the surface free energy of PET fibers untreated and treated with hydrophilic chemicals, such as nonionic-soil release polymer (SRP), anionic, nonionic and hydrophilic silicone, were determined using harmonic-mean and geometric-mean methods. Contact angles of water and methylene iodide on the fibers were determined from the adhesion tensions using tensiometric method. Fibers treated with hydrophilic chemicals have the increased polar force component and the decreased dispersion force component. The adhesion tensions of triolein for the hydrophilic treated fibers were smaller than that for untreated fiber.

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Hydrophilic/Hydrophobic Dual Surface Coatings for Membrane Distillation Desalination (막증류 담수화를 위한 친수성/소수성 이중 표면 코팅)

  • Kim, Hye-Won;Lee, Seungheon;Jeong, Seongpil;Byun, Jeehye
    • Journal of Korean Society on Water Environment
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    • v.38 no.3
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    • pp.143-149
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    • 2022
  • Membrane distillation (MD) has emerged as a sustainable desalination technology to solve the water and energy problems faced by the modern society. In particular, the surface wetting properties of the membrane have been recognized as a key parameter to determine the performance of the MD system. In this study, a novel surface modification technique was developed to induce a Janus-type hydrophilic/hydrophobic layer on the membrane surface. The hydrophilic layer was created on a porous PVDF membrane by vapor phase polymerization of the pyrrole monomer, forming a thin coating of polypyrrole on the membrane walls. A rigid polymeric coating layer was created without compromising the membrane porosity. The hydrophilic coating was then followed by the in-situ growth of siloxane nanoparticles, where the condensation of organosilane provided quick loading of hydrophobic layers on the membrane surface. The composite layers of dual coatings allowed systematic control of the surface wettability of porous membranes. By the virtue of the photothermal property of the hydrophilic polypyrrole layer, the desalination performance of the coated membrane was tested in a solar MD system. The wetting properties of the dual-layer were further evaluated in a direct-contact MD module, exploring the potential of the Janus membrane structure for effective and low-energy desalination.

Wetting Characteristic of Single Droplet Impinging on Hole-Patterned Texture Surfaces (홀 패턴 텍스쳐 표면에서 충돌하는 단일 액적의 젖음 특성)

  • Moon, Joo Hyun;Lee, Sangmin;Jung, Jung-Yeul;Lee, Seong Hyuk
    • Journal of ILASS-Korea
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    • v.20 no.3
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    • pp.181-186
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    • 2015
  • This study presents the dynamic wetting characteristics of an impact droplet on hole-patterned textured surfaces. The flat surfaces were manufactured by a drilling machine to generate the micro-order holes, leading to make the surface hydrophobic. Other flat surfaces were fabricated by the anodizing technique to make hydrophilic texture surfaces with a nanometer order. For hydrophilic and hydrophobic textured surfaces with similar texture area fractions, the impinging droplet experiments were conducted and compared with flat surface cases. As results, an anodized textured surface decreases apparent equilibrium contact angle and increases contact diameters, because of increase in contact area and surface energy. This is attributed to more penetration inside holes from larger capillary pressure on nanometer-order holes. On the other hand, temporal evolution of the contact diameter is smaller for the hydrophobic textured surface from less penetration on the micro-order holes.

Ultrafiltration of Oily Wastewater with Surface Pretreated Membranes

  • Kim, Kyu-Jin;Fane, Antony G.
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.43-49
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    • 1999
  • Separation of soluble oil was investigated during filtration of cutting oil emulsion using various commercial ultrafiltration membranes. The surface properties of membranes used were hydrophilic hydrophobic and modified surfaces by various surfactant pretreatments. Conditions varied include stirring speed transmeembrane pressure membrane type and surfactant type for pretreatment. The results give some indication of mechanisms occurring at the membrane surface. Surfactant pretreatments significantly improved water flux and UF flux of hydrophilic regenerated cellulose(up to 2.4x for YM100) and hydrophobic polysulfone (up to 2.2x for PTHK) membranes depending on surfactant type and operating conditions. The UF flux enhancement was attributed to membrane swelling and reduction of interfacial surface tension between oil droplets and membrane surface. unexpectedly the hydrophilic membranes revealed greater flux enhancement than the hydrophobic membranes. The results also showed a greater improvement in UF flux at lower operating pressure.

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Hydrophilic/Hydrophobic Conversion of $TiO_2$ Films by Reactive Magnetron Sputtering (Reactive Magnetron Sputtering법으로 제조된 $TiO_2$의 친수성/소수성 변환 특성)

  • 이영철;박용환;안재환;고경현
    • Journal of the Korean Ceramic Society
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    • v.36 no.11
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    • pp.1211-1216
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    • 1999
  • TiO2 thin films were prepared by reactive magnetron sputtering on glass substrate and subjected into investigation about their hydrophilic properties. Varing Ar/O2 ration and post annealing at 50$0^{\circ}C$ for 12h anatase and rutile phases of TiO2 films were obtained. Hydrophilic properties were evaluated by determination of contact angle of water droplet on TiO2 surface. On as-annealed TiO2 films water droplet spreaded widely with ~0$^{\circ}$contact angle. Sonication(60 Hz, 28kHz 40kHz) and following dark room treatments turned these hydrophilic TiO2 films into hydrophobic state. All of hydrophobic films were converted recersibly into their original state after UV illumination. Hydrophobic states of anatase films were saturated after sonication and remain same during dark room treatment. But it was found that the conversion into hydrophobic state of rutile films progressed. further after sonication. Therefore it was concluded that Ti3+/Ti+4 ratio is the key to determine hydrophilicity of TiO2 surface so that different surface structure of polymorphs could lead to unique characteristics.

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Experimental Study on Liquid Desiccant Distribution Characteristics at a Dehumidifier with Extended Surface (확장표면을 적용한 액체식 제습기에서 제습액 분배 특성에 관한 실험적 연구)

  • Lee, Min-Su;Chang, Young-Soo;Lee, Dae-Young
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.645-649
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    • 2009
  • Liquid desiccant cooling technology can supply cooling by using waste heat and solar heat which are hard to use effectively. For compact and efficient design of a dehumidifier, it is important to sustain sufficient heat and mass transfer surface area for water vapor diffusion from air to liquid desiccant on heat exchanger. In this study, the plate type heat exchanger is adopted which has extended surface, and hydrophilic coating and porous layer coating are adopted to enhance surface wettedness. PP(polypropylene) plate is coated by porous layer and PET(polyethylene terephthalate) non-woven fabric is coated by hydrophilic polymer. These coated surfaces have porous structure, so that falling liquid film spreads widely on the coated surface foaming thin liquid film by capillary force. The temperature of liquid desiccant increases during dehumidification process by latent heat absorption, which leads to loss of dehumidification capacity. Liquid desiccant is cooled by cooling water flowing in plate heat exchanger. On the plate side, the liquid desiccant can be cooled by internal cooling. However the liquid desiccant on extended surface should be moved and cooled at heat exchanger surface. Optimal mixing and distribution of liquid desiccant between extended surface and plate heat exchanger surface is essential design parameter. The experiment has been conducted to verify effective surface treatment and distribution characteristics by measuring wall side flow rate and visualization test. It is observed that hydrophilic and porous layer coating have excellent wettedness, and the distribution can be regulated by adopting holes on extended surface.

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Surface Modification of Silica Aerogels (실리카 에어로겔의 표면 개질)

  • 현상훈;이찬호;김동준
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1319-1324
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    • 1996
  • Silica aerogels were synthesis by the sol-gel-supercritical drying process using isopropanol as a solvent. Effets of the heat-treatment and the surface modification through propoxylation on the structural reinforcement as well as the surface hydrophobic/hydrophilic characteristics of aerogels were investigated. Silica aerogels synthesized by supercritical drying were hydrophobic but aerogels heat-treated above 20$0^{\circ}C$ were transformed to be hydrophilic. In particular it was found that the skeletal structure of aerogels heat-treated at 50$0^{\circ}C$ was strong enough not to crack after adsorbing a large amount of water vapor. Hydrophilic aerogels modified by propoxylation at 28$0^{\circ}C$ for 20 h were reversed to the hydrophobic form. Transition between hydrophobicity and hydrophilicity was reversible. The hydrophobicvity and the hydrophilicity of silica aerogels were attributed to the Si-Oh bond and the nonpolar C-H bond groups of orgainc species respectively.

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Experimental study of spreading phenomena on hydrophilic micro-textured surfaces depending on surface geometrical features (친수성 마이크로 기둥 구조 표면에서의 표면 지형적 특성에 따른 퍼짐성 현상에 대한 실험적 연구)

  • Jang, Munyoung;Park, Sehyeon;Yu, Dong In
    • Journal of the Korean Society of Visualization
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    • v.16 no.3
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    • pp.35-39
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    • 2018
  • In multiphase systems, surface wettability is one of dominant design parameters to enhance system performance. Since surface wettability can be maximized and minimized with micro-textured surfaces, therefore micro-textured surfaces are widely countered in various research and engineering fields. In this study, for better understanding of micrometer scaled surface wettability, spreading phenomena is experimentally investigated on the hydrophilic micro-textured surfaces. By photolithography and conventional dry etching method, there are prepared the surfaces with uniformly arrayed micro-pillars. The interfacial motions of a water droplet on the test sections are visualized by high speed camera in top view. On the basis of visualization data, it is analyzed the relation between dynamic coefficient and geometrical features on micro-textured surfaces.

Surface static properties in polymer hybrid material after plasma treatment (플라즈마 처리한 고분자 복합재료의 표면특성변화)

  • Park, Jong-Kwan
    • 전자공학회논문지 IE
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    • v.44 no.3
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    • pp.6-11
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    • 2007
  • In this study, which was performed to identify a degradation mechanism in macromolecular insulating material, the contact angle, surface potential decay, surface resistance rate and XPS analysis were compared after exposure of fibre-glass-reinforced polymer laminate to plasma discharge. In the case of chemical changes arising from plasma treatment, carboxyl radicals were generated mainly in the plasma-treated surface, which was rapidly changed to a hydrophilic surface. In the corona potential decay study to determine the electrical changes, leading to a negative surface for the untreated specimen. However, in the case of the hydrophilic surface, a lot of carboxy radicals(-COO) acting as positive polarity were generated, resulting in a positive surface. Owing to such a positive surface, the charges of applied negative polarity were decreased rapidly.