• Title/Summary/Keyword: Hydrogen-peroxide

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Effect on Bleaching Efficiency by Chelating Treatment in Sugarcane Bagasse DEDP Bleaching Process (사탕수수 부산물 펄프의 DEDP 표백 시 킬레이트 전처리가 표백 효율에 미치는 영향)

  • Lee, Jai-Sung;Song, Woo-Yong;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.81-87
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    • 2015
  • Soda-AQ pulp made from sugarcane bagasse (SCB) were bleached in element chlorine free (ECF) sequence. To reduce chlorine dioxide use, final peroxide bleaching was introduced. Prior to peroxide bleaching, different chelating chemicals were applied for comparative analysis in ISO brightness and viscosity. When using equal total chlorine dioxide usage (4.5%), bleached SCB pulp using chelate and hydrogen peroxide (DEDQP) was reached 86.8% (DTPA), 86.4% (EDTA) ISO brightness, whereas bleached pulp using only hydrogen peroxide (DEDP) reached at 81.2% ISO brightness. Viscosity of DEDQP bleached pulp was 25.6 cPs (DTPA), 25.2 cPs (EDTA), And DEDP bleached pulp was shown 18.0 cPs viscosity. Decreasing of transition metal by chelate process led to improvements in final brightness along with higher viscosity. Due to EDTA is 5-7 times cheaper than DTPA, EDTA is recommended as chelating chemical prior to peroxide bleaching.

Measurement of hydrogen peroxide and methyl hydroperoxide in Yanbian, China (연변시 hydrogen peroxide와 methyl hydroperoxide 측정)

  • 지병수;김영미;이미혜
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.237-238
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    • 2003
  • 과산화수소와 organic peroxide는 대류권내 광화학반응에서 생성되는 중요 부산물이다. 이들은 대류권내의 OH와 HO$_2$ 라디칼의 농도를 지시하여 대기의 산화도를 나타내는 지시자가 된다. 이 라디칼들은 $O_3$를 생성하는데 필수적인 성분이므로, 대류권내 광화학 반응을 이해하기 위해서는 과산화수소의 농도와 분포를 이해하는 것이 필수적이다. 대기중의 hydroperoxide는 유리코일 내에서 포집 용액에 의해 포집된 후 HPLC 시스템의 postcolumn reactor에서 효소와 반응하여 형광을 띠게 되고, 형광검출기에서 검출된다. 이 모든 과정은 자동화되어 과산화수소의 실시간 관측 및 연속관측이 가능하게 되었다. (중략)

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Study of Alkaline Peroxide Mechanical Pulp Made from Pinus densiflora (국내산 소나무로 제조된 APMP 특성 연구)

  • Lee, Ji-Young;Nam, Hyegeong;Kim, Chul-Hwan;Kwon, Sol;Park, Dong-Hun;Joo, Su-Yeon;Lee, Min-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.100-110
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    • 2016
  • Alkaline Peroxide Mechanical Pulping (APMP) of Pinus densiflora harvested from domestic mountains was explored. APMP contributes to various advantages including pulp quality, elimination of the need for a bleaching process, and energy savings. Sequential treatment of impregnation of bleaching chemicals and refining not only overcome the concern of alkaline darkening of wood chips during chemical impregnation, but it also brightens the chips to the desired brightness levels suitable for writing and printing papers. APMP pulping from Pinus densiflora was greatly influenced by the dosage levels of hydrogen peroxide and sodium hydroxide. Alkaline peroxide treatment was carried out by applying one of three levels of hydrogen peroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips) and one of three levels of sodium hydroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips). Other chemicals including a peroxide stabilizers and metal chelation were constantly added for all treatments. Chemical treatment with a liquor-to-wood ration of 9:1 was carried out in a laboratory digestor. Compared to BTMP, APMP pulping displayed outstanding characteristics including the less requirement of refining energy, the better improvement of tensile strength, the more reduction of shives, and the greater increase of pulp brightness. In particular, when 4.5% of hydrogen peroxide with impregnation during 90 minutes was used, the brightness of APMP reached 64.9% ISO. Even though bulk of APMP was decreased with the increase of sodium hydroxide, a better and improved balance could be achieved between optical and strength properties. The spent liquor obtained from the discharge of the impregnation process at the dosage level of 4.5% hydrogen peroxide exhibited an equal level of residual peroxide with BTMP. In conclusion, APMP pulping showed successful results with Pinus densiflora due to its better response to the development of optical and physical properties compared to TMP pulping.

Effects of hydrogen peroxide pretreatment and heat activation of silane on the shear bond strength of fiber-reinforced composite posts to resin cement

  • Pyun, Jung-Hoon;Shin, Tae-Bong;Lee, Joo-Hee;Ahn, Kang-Min;Kim, Tae-Hyung;Cha, Hyun-Suk
    • The Journal of Advanced Prosthodontics
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    • v.8 no.2
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    • pp.94-100
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    • 2016
  • PURPOSE. To evaluate the effects of hydrogen peroxide pretreatment and heat activation of silane on the shear bond strength of fiber-reinforced composite posts to resin cement. MATERIALS AND METHODS. The specimens were prepared to evaluate the bond strength of epoxy resin-based fiber posts (D.T. Light-Post) to dual-curing resin cement (RelyX U200). The specimens were divided into four groups (n=18) according to different surface treatments: group 1, no treatment; group 2, silanization; group 3, silanization after hydrogen peroxide etching; group 4, silanization with warm drying at $80^{\circ}C$ after hydrogen peroxide etching. After storage of the specimens in distilled water at $37^{\circ}C$ for 24 hours, the shear bond strength (in MPa) between the fiber post and resin cement was measured using a universal testing machine. The fractured surface of the fiber post was examined using scanning electron microscopy. Data were analyzed using one-way ANOVA and post-hoc analysis with Tukey's HSD test (${\alpha}=0.05$). RESULTS. Silanization of the fiber post (Group 2) significantly increased the bond strength in comparison with the non treated control (Group 1) (P<.05). Heat drying after silanization also significantly increased the bond strength (Group 3 and 4) (P<.05). However, no effect was determined for hydrogen peroxide etching before applying silane agent (Group 2 and 3) (P>.05). CONCLUSION. Fiber post silanization and subsequent heat treatment ($80^{\circ}C$) with warm air blower can be beneficial in clinical post cementation. However, hydrogen peroxide etching prior to silanization was not effective in this study.

Effects of Red Ginseng Extracts on Hydrogen Peroxide Production of Murine Prtitoneal Macrophages (홍삼추출물이 마우스 복강 대식세포 Hydrogen Peroxide 생산에 미치는 영향)

  • 박란숙
    • The Korean Journal of Food And Nutrition
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    • v.11 no.1
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    • pp.107-113
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    • 1998
  • This experiment has conducted to evaluate whether single injection of red ginseng extract including 50% ethanol extract, crude saponin, and lipid soluble fraction can induce oxidative burst of mouse peritoneal macrophages with use of fluorescence spectrophotometer. To optimize conditions of fluorescent spectrophotometry, concentrations of DCFH-DA(2', 7' -dichlorofluorescin diacetate) was 1.6 ${\mu}{\textrm}{m}$ and control oxidative burst by Zymosan A and PMA(phorbol myristate acetate) were 100$\mu\textrm{g}$, 250ng, respectively. Though in vitro macrophages failed to induce increment of H2O2 production, but 50% ethanol extract group induced significant enhancement of H2O2 production when zymosan A triggered oxidative burst. On the other hand, lipid soluble fraction enhanced significantly H2O2 production than that of control group. These findings consisted with the other reports which showed ginsenosides inhibited nitric oxide production and lipid soluble fraction activated colony stimulating factor(granulocyte - monocyte) activity in bone marrow stem cells. As is well known, lipid soluble fraction contains phenol compound, polyacetylene compound and alkaloids. Further study would unravel which component of it can induce H2O2 production of macrophages. Key words : Red ginseng(Panax ginseng), H2O2 production, macrophages.

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