• 멤브레인
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• 제33권1호
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• pp.46-51
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• 2023

본 연구의 목적은 스마트시티 구축의 핵심인 수소연료전지의 활용형태를 분석하고 해결방안을 제시하는 것이다. 수소연료전지를 활용하는 발전소의 경우 간헐성 문제가 없다는 장점 때문에 향후 가장 유망한 사용 형태로 분석됐다. 다만 많은 장점에도 불구하고 폭발 우려와 특정 수소 생산방식의 경우 이산화탄소 발생 문제 등으로 지역주민들의 반발이 지속적으로 나타나고 있어 이를 해결하는 것이 스마트시티 구축의 주요 관건이 될 것으로 분석된다. 마지막으로 현재의 수소 생산방식을 분석하고 이에 따른 문제점을 파악하여 스마트시티의 완전한 구축을 위한 해결책을 제시하였다.

• 한국미생물·생명공학회지
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• 제27권1호
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• pp.46-53
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• 1999

The purpose of this study was to optimize the conditions of continuous mixed culture of C.butyricum and R. spaeroides K-7, which were able to produce hydrogen using biomass-dreived substrate. To investigate the possibility of continuous culture, semi-continuous culture was carried out for 20 days. In semi-continuous culture using the reactor system, the replacement rate of fresh medium was 30% of total medium volume for the highest hydrogen evolution. In continuous culture, the optimum dilution rate was determined to be 0.05$h^{-1}$. The continuous culture produced 3.1 times as compared with the hydrogen on batch culture. On the other hand, the continuous mixed culture produced 1.3~2.1 times as much as hydrogen of the continuous monoculture of C. butyricum. When 10g of glucose in the media (1l) was supplied as a carbon source on continuous culture, mixed culture of C. butyricum and R. sphaeroides K-7 increased hydrogen evolution rate. Because considerable amount of glutamate was contained in waste water of glutamate fermentation, utilization of glutamate was examined in mixed culture. As a result of examination, production of hydorgen was slightly inhibited by high concentration of glutamate, more than 20mM, on continuous monoculture of R. sphaeroides K-7. On the other hand, both on continuous monoculture of C. butyricum and on mixed culture of C. butyricum and R. sphaeroides K-7, production of hydrogen was not inhibited by high concentration of glutamate such as 100mM. Hence this suggests that high concentration of waste water can be used as good substrate for hydrogen production on monoculture of C. butyricum and mixed culture of C. butyricum and R. sphaeroides K-7.

• 한국미생물·생명공학회지
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• 제19권2호
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• pp.179-185
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• 1991

We examined optimum culture conditions of Rhodopseudomonas sphaeroides B5 for effective utilization of substrate and sunlight for hydrogen production. The optimum concentration range of DL-lactate as electron donor for hydrogen production by resting cells was from 5 to 50mM, and optimun CN ratio (lactate/glutamat) for maintenence of hydrogen production activity by growing cultures was from 5 to 6. Hydrogen production by the cultures of low cell density (0.36mg/ml dry cells) was saturated with 10 Klux light intensity. Under constant illumination of 50Klux which was set up as the average medium value of annual variation of sunlight intensity, hydrogen production with various cell densities in the culture resulted in highest production rate (132${\mu}$l/hr/mg dry cells) up to 0.64mg/ml dry cells. However, the amount of total hydrogen production was saturated with cell density of 2.1mg/ml dry cells. In addition to these, the optimum inner thickness pervious to light of the culture vessel for hydrogen production which was measured under sunlight was 5 cm.

• 한국수소및신에너지학회논문집
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• 제31권2호
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• pp.169-176
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• 2020

There is a growing interest in hydrogen energy utilization since an alternative energy development has been demanded due to the depletion of fossil fuels. Hydrogen is produced by the reforming reaction of natural gas and biogas, and the electrolysis of water. An solid oxide electrolyte cell (SOEC) is reversible system that generates hydrogen by electrolyzing the superheated steam or producing the electricity from a fuel cell by hydrogen. If the water can be converted into steam by waste heat from other processes it is more efficient for high-temperature electrolysis to convert steam directly. The reasons are based upon the more favorable thermodynamic and electrochemical kinetic conditions for the reaction. In the present study, steam at over 180℃ and 3.4 bars generated from a boiler were converted into superheated steam at over 700℃ and 3 bars using a cylindrical steam superheater as well as the waste heat of the exhaust gas at 900℃ from a solid refuse fuel combustor. Superheated steam at over 700℃ was then supplied to a high-temperature SOEC to increase the hydrogen production efficiency of water electrolysis. Computational fluid dynamics (CFD) analysis was conducted on the effects of the number of 90° elbow connector for piping, insulation types and insulation layers of pipe on the exit temperature using a commercial Fluent simulator. For two pre-heater injection method of steam inlet and ceramic wool insulation of 100 mm thickness, the highest inlet temperature of SOEC was 744℃ at 5.9 bar.

• 한국콘텐츠학회논문지
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• 제21권6호
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• pp.306-317
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• 2021

미국, 유럽, 중국, 일본 등 주요 선진국은 탄소 경제에서 수소 경제로의 전환을 위해 다양한 수소 경제 정책을 발표하며 연구역량을 집중하고 있다. 우리나라도 이러한 추세에 발맞추어 2019년 초 수소 경제 활성화 로드맵을 발표한 이래로 수소 경제 관련 법안을 마련하고 지원책을 실시하고 있다. 본 연구에서는 국가과학기술지식정보서비스(NTIS)의 국가R&D과제정보 최근 10년치 데이터를 활용해 수소 경제, 그중에서도 전·후방 파급효과가 크다고 할 수 있는 연료전지전기차 관련 R&D 현황과 지식구조를 파악하고자 한다. 연료전지전기차 관련 국가R&D과제(2020년 1월 기준) 1,479개의 원시 데이터를 바탕으로 네트워크 분석 및 텍스트 마이닝을 실시한 결과, 연료전지전기차 분야에서는 수소의 생산, 운반, 저장, 활용의 전 프로세스에 걸친 기술 및 시스템의 연구개발이 활발하게 이루어지고 있는 것으로 나타났다. 본 논문은 해당 연구결과를 통해 현재 연료전지전기차 산업을 선도하고 있는 한국의 수소 경제 관련 정책 수립과 연구개발, 시장 전략에 대해 시사점을 제시한다.

• 한국가스학회지
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• 제25권6호
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• pp.98-105
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• 2021

현재 정부의 「한국판 뉴딜 종합계획」발표('20.7.14, 관계부처 합동)에 따른 수소 생산 및 충전시설 보급 확대에 따라 주요 기업에서 액화수소 제조설비 건설계획 발표에 액화수소 플랜트, 충전소 등 관련시설 구축이 속도감 있게 진행되고 있다. 그러나 국내 액화수소 밸류체인에 따른 생산·저장시설·운송·활용 등에 대한 안전기준이 미흡한 실정이며, 액화수소 전주기에 걸친 안전 기술 및 안전기준 마련이 시급하다. 이에 한국가스안전공사는 액화수소 플랜트를 비롯한 전주기에 걸친 안전기준을 제·개정하고, 이를 통해 국내 안전한 수소 경제를 실현시키고자 한다.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.845-855
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• 2022

In response to climate change, the world is continuing efforts to reduce fossil fuels, expand renewable energy, and improve energy efficiency with the goal of achieving carbon neutrality. In particular, R&D is being made on the value chain covering the entire cycle of hydrogen production, storage, transportation, and utilization in order to shift the energy supply system to focus on hydrogen energy. Hydrogen-based energy sources can produce heat and electricity at the same time, so it is possible to utilize heat energy, which can increase overall efficiency. In this study, calculation of the optimal scale for hydrogen-based cogeneration and the composition of heat sources were reviewed. It refers to a method of the optimal heat source size according to the external heat supply and heat storage to be considered. The results of this study can be used as basic data for establishing a hydrogen-based energy supply model in the future.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.641-649
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• 2023

This study analyzes the cool-down process of liquid hydrogen storage tanks, which have advantages in terms of large-capacity transfer, storage, and utilization as hydrogen demand increases. A hydrogen liquefaction plant is selected for analysis and an efficient tank cooling method is sought by comparing the time required for the cool-down process with the gas consumption in connection with the gassing-up process required for the operation of the liquid hydrogen storage tank. The results of this study can be referred to in the operation process after the initial start-up and maintenance of the hydrogen liquefaction plant.

• 한국수소및신에너지학회논문집
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• 제25권3호
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• pp.240-246
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• 2014

In order to develop a universal cryogenic piston pump of small size for increasing utilization of liquid hydrogen, dynamic compression performance of piston pump were evaluated and improvements were also discussed for piston rod and piston tip. The cryogenic piston pump has crosshead structure and inclined cup shape piston tip. As the results, it was found that i) insulation of heat flow from piston-rod part is required for stable operation ii) improving the self-clearance adjustment effect of piston tip and reducing piston eccentricity were desirable to promote pumping pressure and operating range.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 춘계학술대회
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• pp.223-226
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• 2005

For $CO_2-free$ hydrogen production and better utilization of the produced carbon, catalytic decomposition of methane over rubber-grade carbon blacks manufactured from coal tar was carried out. The catalytic activities of several domestic carbon blacks were compared. A pelletized carbon black exhibited considerably lower activity and activation energy than the fluffy( loose) carbon black of the same grade. This difference is considered due to the binder that was added during pelletization. For pelletized carbon blacks, a tendency was observed that the activity per unit mass of catalyst increased with the specific surface area of the carbon black. Another tendency was also observed that the activation energy increased with the primary particle size or decrease of the specific surface area.