• Journal of The Korean Society of Agricultural Engineers
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• v.64 no.5
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• pp.1-8
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• 2022

Hydrogen can be produced by gasification of biomass and other combustible fuels. Depending on oxydant agents, syngas or producer gas compositions become quite different. Since biomass has limited amount of hydrogen including moisture in it, the hydrogen concentration in the syngas is about 15% when air is supplied for oxidant agent. Experiments were conducted to investigate the channges in hydrogen concentrations in syngas with different oxidant agent conditions, fuel conditions, and external heat supply. Allothermal reaction resulted in higher concentrations of hydrogen with the supply of steam over air, reaching over 60%. Hydrogen is produced by water-gas and water-gas shift reactions. These reactions are endothermic and require enough heat. Autothermal reaction occurred in the downdraft gasifier used in the experiment did not provide enough heat in the reactions for hydrogen production. Steam seems a more desirable oxidant agent in producing the syngas with higher concentrations of hydrogen from biomass gasifications since nitrogen is included in syngas when air is used.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.19 no.4
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• pp.363-369
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• 2009

The total number of confined space accident cases from 1999 to 2007 in Korea were 220, causing 353 injuries and 212 casualties. Out of 220 cases, 44(20.0%) occurred in sewage treatment facilities and 40(18.2%) occurred in both manholes and containers. When the main causes of confined space accidents were classified, oxygen deficiency accounted for 69 cases(31.4%), carbon monoxide, 48(21.8%), hydrogen sulfide, 40(18.2%), and organic solvent, 32(14.5%). Improvement of occupational accident statistics is necessary in order to report accurate and precise data for confined space accidents. The structure of confined space must be considered when selecting gas to be measured.

• Journal of Hydrogen and New Energy
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• v.34 no.2
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• pp.205-211
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• 2023

Hydrogen gas is light and diffuses very quickly. Therefore, when a leakage accident occurs, the damage is great, so a technology that can quickly measure the leakage in the air at a long distance is needed. In order to develop hydrogen gas leaked in the atmosphere in a non-contact manner, an experiment was performed to measure hydrogen gas using a lidar technology using the Raman effect. Hydrogen Raman signals were detected using a UV LED light source, which is a Raman light source, and a spectrometer in the ultraviolet region including an optical filter in the 400-430 nm band. To develop this, a Raman lidar optical structure was designed to measure the hydrogen Raman signal at a certain distance, and the hydrogen Raman spectrum was confirmed using a standard gas to evaluate the performance of this optical structure. The linearity was found to be 0.99 using hydrogen standard gas (10, 50, 100, 500, 1,000 ppm). Accordingly, a Raman lidar capable of measuring hydrogen gas rapidly diffusing in the air in an open state was developed to improve the limitations of existing hydrogen sensors.

• Proceedings of the Korean Nuclear Society Conference
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• 2005.10a
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• pp.685-686
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• 2005

• Journal of the Korean Institute of Gas
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• v.16 no.1
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• pp.8-14
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• 2012

Hydrogen is considered to be the most important future energy carrier in many applications reducing significantly greenhouse gas emissions, but the explosion safety issues associated with hydrogen applications need to be investigated and fully understood to be applicable as the carrier. The risk associated with a explosion depends on an understanding of the impacts of the explosion, particularly the pressure-time history during the explosion. This work provides the effects of explosion parameters, such as specific heat ratio of burned and unburned gas, equilibrium maximum explosion pressure, and burning velocity, on the pressure-time history with flame growth model. The pressure-time history is dominantly depending on the burning velocity and equilibrium maximum explosion pressure of hydrogen-air mixture. The pressure rise rate increase with the burning velocity and equilibrium maximum explosion pressure. The specific heat ratio of unburned gas has more effect on the final explosion pressure increase rate than initial explosion pressure increase rate. However, the specific heat ratio of burned gas has more influence on initial explosion pressure increase rate. The flame speeds are obtained by fitting the experimental data sets. The flame speeds for hydrogen in air based on our experimental data is very low, making a transition from deflagration to detonation in a confined space unlikely under these conditions.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.81-89
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• 2019

This study deals with a process for recovering hydrogen isotopes from fusion exhaust gas. The goal of this process is to remove impurities, maximally recover only pure hydrogen isotopes. Experiments using hydrogen and deuterium were conducted to confirm the possibility of the recovery of hydrogen isotopes. In the exhaust gas containing H₂, impurities was removed in the membrane process, and only pure H₂ was recovered. And the H₂ in the exhaust gas of the He-GDC(Glow Discharge Cleaning) process was recovered using a cryogenic adsorption process. In addition, HAZOP analysis was performed for qualitative risk assessment. For scenario analysis, the damage prediction ALOHA program was used to calculate the range of influence. Finally measures were sought to improve safety.

• Journal of the Korean Professional Engineers Association
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• v.45 no.6
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• pp.20-27
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• 2012

World has become interested in the development of new dean energy because of oil prices rise and global warming due to carbon dioxide emissions. This study evaluated the safety of the refueling infrastructure for hydrogen, CNG and HCNG(hydrogen blended natural gas) which recently take center stage as a clean fuel. The risk of fuel was evaluated by 3D computational fluid dynamics program for gas dispersion and explosion. Hydrogen is higher than the CNG explosion overpressure and shows rapid spread. On the other hand, CNG and 30% HCNG showed quite similar characteristics. HCNG slightly rises in risk than the CNG, but HCNG is safe compared to hydrogen.

• Journal of Hydrogen and New Energy
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• v.26 no.6
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• pp.541-546
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• 2015

Global energy shortage problem is expected to increase driven by strong energy demand growth from developing countries. Nuclear fusion power offers the prospect of an almost infinite source of energy for future generations. Hydrogen isotope storage and delivery system is a important subsystem of a nuclear fusion fuel cycle. Metal hydride is a method of the high-density storage of hydrogen isotope. For the safety storage of hydrogen isotope, depleted uranium (DU) has been widely proposed. But DU needs a safe test because It is a radioactive substance. The authors studied a small-scale DU bed and a medium-scale DU bed for the safety test. And then we made a large-scale DU bed and stored hydrogen isotopes in the bed. Before the hydriding/dehydriding, we tested it's heating and cooling properties and carried out an activation procedure. As a result, Reaction rate of DU-$H_2$ is more rapid than the other metal hydride ZrCo. Through the successful storage result of our large bed, the development possibility of the hydrogen isotope storage technology seems promising.

• Nuclear Engineering and Technology
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• v.47 no.1
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• pp.11-25
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• 2015

The accident at Japan's Fukushima Daiichi nuclear power plant in March 2011, caused by an earthquake and a subsequent tsunami, resulted in a failure of the power systems that are needed to cool the reactors at the plant. The accident progression in the absence of heat removal systems caused Units 1-3 to undergo fuel melting. Containment pressurization and hydrogen explosions ultimately resulted in the escape of radioactivity from reactor containments into the atmosphere and ocean. Problems in containment venting operation, leakage from primary containment boundary to the reactor building, improper functioning of standby gas treatment system (SGTS), unmitigated hydrogen accumulation in the reactor building were identified as some of the reasons those added-up in the severity of the accident. The Fukushima accident not only initiated worldwide demand for installation of adequate control and mitigation measures to minimize the potential source term to the environment but also advocated assessment of the existing mitigation systems performance behavior under a wide range of postulated accident scenarios. The uncertainty in estimating the released fraction of the radionuclides due to the Fukushima accident also underlined the need for comprehensive understanding of fission product behavior as a function of the thermal hydraulic conditions and the type of gaseous, aqueous, and solid materials available for interaction, e.g., gas components, decontamination paint, aerosols, and water pools. In the light of the Fukushima accident, additional experimental needs identified for hydrogen and fission product issues need to be investigated in an integrated and optimized way. Additionally, as more and more passive safety systems, such as passive autocatalytic recombiners and filtered containment venting systems are being retrofitted in current reactors and also planned for future reactors, identified hydrogen and fission product issues will need to be coupled with the operation of passive safety systems in phenomena oriented and coupled effects experiments. In the present paper, potential hydrogen and fission product issues raised by the Fukushima accident are discussed. The discussion focuses on hydrogen and fission product behavior inside nuclear power plant containments under severe accident conditions. The relevant experimental investigations conducted in the technical scale containment THAI (thermal hydraulics, hydrogen, aerosols, and iodine) test facility (9.2 m high, 3.2 m in diameter, and $60m^3$ volume) are discussed in the light of the Fukushima accident.

• Journal of Platform Technology
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• v.10 no.4
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• pp.3-10
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• 2022

In this study, damage resulting from internal flaws was investigated by finite element analysis for the safety evaluation of a non-destructive testing platform for hydrogen pressure vessels. A specimen was modeled and calculated using finite element analysis to determine material properties in accordance with the parameters of the composite material in order to assess the safety of the Type 4 hydrogen pressure vessel. Through this, flaws in the hydrogen pressure vessel were modeled, and test conditions were provided in accordance with rules to look into whether there was safety. Delamination, foreign object, and vertical cracks were modeled for internal flaws, and damage was examined in accordance with failure criteria. As the delamination defect approached the interior of the hydrogen pressure tank, it became more likely to cause damage. Additionally, as the crack depth grew in the case of vertical cracks, the likelihood of crack propagation rose. On the other hand, it was anticipated that the foreign item defect would suffer more damage from the outside in. A non-destructive testing platform will be used to assess the safety of fuel cell vehicles that are already in operation in future research.