• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.48-53
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• 2017

Since the number and the amount of toxic substances handled by domestic companies have been increased, the possibility of serious chemical accidents has become severe. According to Chemistry Safety Clearing-house (CSC), the number of chemical accidents for the last five years has been rapidly raised. A representative example which shows the serious impact of a chemical accident is HF (Hydrogen Fluoride) accident generated in Gumi in 2012. In order to make effective responses for mitigating losses of accidents, the most suitable consequence model has to be selected and implemented throughout the considerations of chemical properties and environments. Even if each consequence model has been verified by the results of experiments, it is necessary to analyze and compare the usability of them according to various scenarios. In this study, the Gumi HF accident is simulated by HGSYSTEM, which is the most specialized model for the release and dispersion of HF. It is found that the ending point of ERPG-2 is about 1 km from the accident point. In order to investigate the usability of the most representative consequence models (ALOHA and CARIS), the results of them are compared with one of HGSYSTEM.

• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.15-21
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• 2013

This study evaluated comparison of the risk according to the type of fuel by three-dimensional simulation tool(FLACS). The consequence analysis of fire explosion and jet-fire was carried out in the layout of a typical high-pressure gas filling stations using CNG, hydrogen and 30%HCNG. Under the same conditions, hydrogen had a 30kPa maximum overpressure, CNG had a 0.4kPa and HCNG had a 3.5kPa. HCNG overpressure was 7.75 times higher than the CNG measurement, but HCNG overpressure was only 11.7% compared to hydrogen. In case of flame propagation, hydrogen had a very fast propagation characteristics. On the other hand, CNG and HCNG flame propagation velocity and distance tended to be relatively safe in comparison to hydrogen. The estimated flame boundary distance by jet-fire of hydrogen was a 5.5m, CNG was a 3.4m and HCNG was a 3.9m.

• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.611-618
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• 2023

The purpose of the refueling protocol and the contents of SAE J2601, which is used as the basis for hydrogen vehicles refueling around the world, were investigated, and research contents related to domestic protocols were also investigated. In addition, the components of the hydrogen refueling performance evaluation device developed in Korea and the method for evaluating the performance and safety of hydrogen refueling stations were reviewed. And, the result were analyzed by applying it to the hydrogen refueling stations currently operating in Korea. In addition, an economic feasibility analysis was conducted using data collected from domestic hydrogen refueling stations. In order to secure the safety and economy of a hydrogen refueling station, the protocol must be satisfied, and in order to satisfy the protocol, it is necessary to evaluate whether the refueling temperature, refueling pressure, and refueling flow are controlled within a safe range.

• Journal of the Korean Institute of Gas
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• v.28 no.2
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• pp.17-23
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• 2024

As interest in sustainable and eco-friendly energy increases due to various problems in the carbon economy, a hydrogen economy that utilizes hydrogen as a main energy source is emerging. Among the methods of producing hydrogen, the water electrolysis method based on renewable energy produces environmentally friendly green hydrogen because it produces hydrogen from water. The water electrolysis facility currently under development produces hydrogen by receiving electricity directly from renewable energy and uses KOH(potassium hydroxide) as an electrolyte. In this study, HAZOP(Hazard and Operability Study), a qualitative risk assessment, was conducted on alkaline water electrolysis facilities to find problems and risk factors in the design and operation of water electrolysis facilities. Risks related to oxygen and KOH, an electrolyte, were identified as major risks, and it is believed that the safety of facilities and workers can be secured based on emergency action plans and safe operation procedures.

• Journal of the Korean Institute of Gas
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• v.16 no.2
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• pp.25-30
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• 2012

This paper presents a stress safety of a composite pressure cylinder in which is composed of an aluminum liner and composite layers with carbon fiber/epoxy and glass fiber/epoxy resigns. The composite pressure cylinder for a hydrogen gas vehicle contains 9.2 liter hydrogen gas, and hydrogen gases are compressed by a filling pressure of 35MPa. The FEM computed results are analyzed based on the US DOT-CFFC basic requirement for a hydrogen gas cylinder and KS B ISO specification. The FEM results indicate that the stress, 247MPa of an aluminum liner is sufficiently low compared with that of 272MPa, which is 95% level of a yield stress for aluminum. And, the carbon fiber composite layers in which are wound on the surface of an aluminum cylinder are safe because the maximum carbon fiber stresses from 29.43% to 28.87% in hoop and helical directions are below 30% for a given minimum required burst pressure level, respectively. The carbon fiber composite layers are also safe because the stress ratios from 3.40 to 3.46 in hoop and helical directions are above 2.4 for a minimum safety level, respectively.

• Journal of the Korean Institute of Gas
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• v.16 no.1
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• pp.46-50
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• 2012

The performance of the Type3 hydrogen composite cylinder whose pressure is 70 MPa using hydrostatic cycling test equipment was evaluted in this study. It also includes the finite element method analysis on the performance of the cylinder when the pressure is applied. As a result, cylinder body parts of the Type3 hydrogen composite cylinder, which draws attention with its safe status and the lightness, was ruptured first and the same result has been found out through the finite element method. The dome knuckle and the cylinder body were proved as the weakest parts since the cylinder body parts was expanded under the pressure.

• Advanced Composite Materials
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• v.18 no.3
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• pp.233-249
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• 2009

Safe installation and operation of high-pressure composite cylinders for hydrogen storage are of primary concern. It is unavoidable for the cylinders to experience temperature variation and significant thermal input during service. The maximum failure pressure that the cylinder can sustain is affected due to the dependence of composite material properties on temperature and complexity of cylinder design. Most of the analysis reported for high-pressure composite cylinders is based on simplifying assumptions and does not account for complexities like thermo-mechanical behavior and temperature dependent material properties. In the present work, a comprehensive finite element simulation tool for the design of hydrogen storage cylinder system is developed. The structural response of the cylinder is analyzed using laminated shell theory accounting for transverse shear deformation and geometric nonlinearity. A composite failure model is used to evaluate the failure pressure under various thermo-mechanical loadings. A back-propagation neural network (NNk) model is developed to predict the maximum failure pressure using the analysis results. The failure pressures predicted from NNk model are compared with those from test cases. The developed NNk model is capable of predicting the failure pressure for any given loading condition.

• Journal of Applied Biological Chemistry
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• v.54 no.3
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• pp.214-217
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• 2011

Fumigant, methyl bromide which is used in most countries for plant quarantine, has been designated and under control as ozone depleting substance. For developing alternative chemicals for methyl bromide, many countries have been intensifying their capacity. This study was carried out to investigate the residue patterns of hydrogen cyanide which is commonly used for plant quarantine. Hydrogen cyanide was treated onto the orange, banana, and pineapple at recommended and double doses and then sampling was done at 1 and 3 day after fumigation treatment. Residue of hydrogen cyanide was found safe because average residue levels on orange, banana, and pineapple after 3 days of fumigation treatment were $0.57{\pm}0.05$, $0.21{\pm}0.17$, and $0.41{\pm}0.08$ ppm, which were lower than the MRLs of Korea (5 ppm), Japan (5 ppm), USA (50 ppm), and Canada (25 ppm). Hydrogen cyanide are expected to be used as alternative chemicals for methyl bromide fumigant for orange, banana, and pineapple.

• Journal of the Korean Institute of Gas
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• v.16 no.1
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• pp.15-21
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• 2012

An analysis was completed of the hazards distance of hydrogen accidents such as jet release, jet fire, and vapor cloud explosion(VCE) of hydrogen gas, and simplified equations have been proposed to predict the hazard distances to set up safety distance by the gas dispersion, fire, and explosion following hydrogen gas release. For a small release rate of hydrogen gas, such as from a pine-hole, the hazard distance from jet dispersion is longer than that from jet fire. The hazard distance is directly proportional to the pressure raised to a half power and to the diameter of hole and up to several tens meters. For a large release rate, such as from full bore rupture of a pipeline or a large hole of storage vessel, the hazard distance from a large jet fire is longer than that from unconfined vapor cloud explosion. The hazard distance from the fire may be up to several hundred meters. Hydrogen filling station in urban area is difficult to compliance with the safety distance criterion, if the accident scenario of large hydrogen gas release is basis for setting up the safety distance, which is minimum separation distance between the station and building. Therefore, the accident of large hydrogen gas release must be prevented by using safety devices and the safety distance may be set based on the small release rate of hydrogen gas. But if there are any possibility of large release, populated building, such as school, hospital etc, should be separated several hundred meters.

• Journal of Auto-vehicle Safety Association
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• v.14 no.4
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• pp.43-52
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• 2022

Recently, the government has been expanding the supply of hydrogen vehicles according to the roadmap for vitalizing the hydrogen economy, but is developing safety assessment and inspection technology for the relevant vehicles. This study analyzed the prevention of hydrogen bus accidents' economic effect that arises from the application and development of large-capacity CHSS oil pressure repetition-test assessment technology, hydrogen bus internal chamber pressure transmission and emission volume inspection technology, among various technologies capable of assessing the safety of a hydrogen bus fuel system. To this end, the contingent valuation method (CVM), one of the value evaluation methods of non-market goods, was applied to investigate users' willingness to pay for each inspection technology. The survey for users' willingness to pay was conducted by attaching posters to promote surveys on the internet and within buses to the entire public. As a result of the analysis, the average WTP of the hydrogen bus internal chamber pressure transmission volume inspection technology was 25.3 KRW, the average WTP of the hydrogen bus internal chamber pressure emission volume inspection technology was 18.6 KRW, and the average WTP of the large-capacity CHSS oil pressure repetition-test assessment technology was measured at 16.7 KRW. In addition, the costs and benefits of the introduction of the relevant inspection technology were defined through the interviewing of experts at related research institutions and businesses. As a result of conducting an economic analysis (4.5% discount rate) according to the development of each inspection technology, economic feasibility was seen in all assessment and inspection technologies. As much as the technology is indispensable for the safe use of hydrogen buses, it shows that investment in related technology is very necessary in the future. However, because it was decided that the relevant analysis will differ according to the distribution rate of hydrogen buses, further analysis following this future distribution rate of hydrogen buses is needed, and future users should be made clearly aware of the safety and environmental nature of the technology.