• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.723-726
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• 2009

As a preliminary study of cost estimates for nuclear hydrogen systems, the hydrogen production costs of the nuclear energy sources benchmarking GT-MHR are estimated in the necessary input data on a Korean specific basis. G4-ECONS developed by EMWG of GIF in 2008 was appropriately modified to calculate the cost for hydrogen production of SI process with VHTR as a thermal energy source rather than the LUEC. The estimated costs presented in this paper show that hydrogen production by the VHTR could be competitive with current techniques of hydrogen production from fossil fuels if $CO_2$ capture and sequestration is required. Nuclear production of hydrogen would allow large-scale production of hydrogen at economic prices while avoiding the release of $CO_2$. Nuclear production of hydrogen could thus become the enabling technology for the hydrogen economy. The major factors that would affect the cost of hydrogen were also discussed.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.228.2-228.2
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• 2010

In this work, the hydrogen production costs of the nuclear energy sources are estimated in the necessary input data on a Korean specific basis. G4-ECONS was appropriately modified to calculate the cost for hydrogen production of HTE process with Very High Temperature nuclear Reactor (VHTR) as a thermal energy source rather than the LUEC (Levelized Unit Electricity Cost). The general ground rules and assumptions follow G4-ECONS. Through a preliminary study of cost estimates, we wished to evaluate the economic potential for hydrogen produced from nuclear energy, and, in addition, to promptly estimate the hydrogen production costs for an updated input data for capital costs. The estimated costs presented in this paper show that hydrogen production by the VHTR could be competitive with current techniques of hydrogen production from fossil fuels if $CO_2$ capture and sequestration is required. Nuclear production of hydrogen would allow large-scale production of hydrogen at economic prices while avoiding the release of $CO_2$. Nuclear production of hydrogen could thus become the enabling technology for the hydrogen economy. The major factors that would affect the cost of hydrogen were also discussed.

• 한국자동차공학회논문집
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• 제3권3호
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• pp.129-139
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• 1995

This study investigates the combustion characteristics of methane-hydrogen-air premixture in a constant volume combustion chamber. Primary factors of the combustion characteristics of methane- hydrogen-air premixture are the equivalence ratio and hydrogen supplement rate. In the case of $\phi$= 1.1, maximum combustion pressure and heat release rate have peaks, and they increase as the initial pressure and hydrogen supplement rate increase. The total burning time is also the shortest at the $\phi$= 1.1, it shorten by lowering the initial pressure and by increasing the hydrogen supplement rate. The maximum flame temperature is shown at the $\phi$= 1.0, and increasing the initial pressure and hydrogen supplement rate, it increases. The concentration of NO reveals the highest value at the $\phi$= 0.9, and it increases by increasing the initial pressure and hydrogen supplement rate. It is also found that the limit of lean inflammability of methane-hydrogen-air premixture is greatly widened by increasing the hydrogen supplement rate.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
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• pp.37-40
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• 2013

Hydrogen-dimethy ether (DME) and hydrogen-diesel compression ignition engine combustion were investigated and compared each other in a single cylinder compression ignition engine. Hydrogen and DME were used as low carbon alternative fuels to reduce green house gases and pollutant. Hydrogen was injected at the intake manifold with an injection pressure of 0.5 MPa at fixed injection timing, $-210^{\circ}CA$ aTDC. DME and diesel were injected directly into the cylinder through the common-rail injection system at injection pressure of 30 MPa. DME and diesel inejction timing was varied to find the optimum CI combustion to reduce CO, HC and NOx emissions. When DME was injected early, CO and HC emissions were high while NOx emission was low. Fuel consumption, heat release rate, and exhaust emissions were measured to analyze each combustion characteristics of each ignition promoter. Fuel consumption was decreased when diesel was used as an ignition promoter. This is due to the lower volatility of diesel which created more stratified charge than DME.

• 한국환경농학회지
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• 제36권4호
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• pp.288-292
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• 2017

BACKGROUND: Silicon tetrachloride reacts with moisture in the atmosphere to generate hydrogen chloride, which affects the environment. Since silicon tetrachloride and its by-products are dispersed in the atmosphere in a short time after the silicon tetrachloride release into the atmosphere, it is difficult to directly assess the extent of environmental impact. In the present study, the exposure test of silicon tetrachloride or hydrogen chloride was examined in order to establish the criterion of the range affected by the silicon tetrachloride release, and the actual crops in the area exposed to silicon tetrachloride leakage were analyzed. METHODS AND RESULTS: For the experiment of exposure to silicon tetrachloride or hydrogen chloride, the leaves of red-pepper and corn were used in glass sealed containers. In the actual accident area, 59 samples from 10 different kinds of crops were collected. The pretreatment of the sample was performed by freezing and grinding, and then extracted using distilled water. The pH and concentration of chloride ($Cl^-$) ion of the extracted solution were measured using pH meter and ion chromatograph, respectively. CONCLUSION: Exposure to silicon tetrachloride caused visible damage, increasing the concentration of chloride ion, and decreasing the pH as well as hydrochloric acid. In the actual crops of the affected area, the tendency was the same as the result of the laboratory test, and the range of influence could be estimated through the concentration of $Cl^-$ ion over 2,000 mg/kg, and the correlation evaluation between the concentration of $Cl^-$ and pH. Therefore, the concentration of $Cl^-$ ion and the correlation between $Cl^-$ and pH would be considered as the factors to estimate the influence range of silicon tetrachloride release.

• 대한약리학회지
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• 제32권3호
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• pp.389-397
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• 1996

위점막은 위강내에서 생성되는 독성이 강한 활성산소종에 노출된다. Nitric oxide는 glutathione의 항상성을 유지시킴으로써 acetaminophen 유도 간독성에 대한 보호효과를 나타내었다. 본 연구는 hydrogen peroxide로 인한 위선세포 손상에 대한 nitric oxide의 작용을 규명하고자 하였다. Hydrogen peroxide는 ${\beta}-D-glucose$와 glucose oxidase의 반응에 의해 생성시켰으며, 위선세포에 L-arginine, $N^{G}-nitro-L-arginine$ methyl ester 및 $N^G-nitro-L-arginine$을 전처리 한 후, 세포외로 유리되는 지질과산화물 및 nitrite를 정량하고 세포내 glutathione 함량을 측정하였다. 결과로서, glucose/glucose oxidase를 처리한 경우 glucose oxidase 농도의존적으로 지질과산화물 생성은 증가되었으며, nitrite 유리 및 glutathione 함량은 감소되었다. NO synthase의 기질인 L-arginine 전처리시 glucose/glucose oxidase에 의한 지질과산화 및 nitrite 유리 증가와 세포내 glutathione 감소등이 방지되었다. $N^G-nitro-L-arginine$ methyl ester 및 $N^G-nitro-L-arginine$등 NO synthase 억제제들은 세포손상에 보호효과를 나타내지 않았다. 결론적으로 nitric oxide는 hydrogen peroxide로 인한 세포손상에 대한 보호효과가 없으며, 이는 지질과산화 반응 및 세포내 glutathione 고갈등을 억제시킴으로써 이루어진다고 사료된다.

• 한국재료학회지
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• 제22권3호
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• pp.159-167
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• 2012

Hydrogen is in the spotlight as an alternative next generation energy source for the replacement of fossil fuels because it has high specific energy density and emits almost no pollution, with zero $CO_2$ emission. In order to use hydrogen safely, reliable storage and transportation methods are required. Recently, solid hydrogen storage systems using metal hydrides have been under extensive development for application to fuel cell vehicles and fuel cells of MCFC and SOFC. For the practical use of hydrogen on a commercial basis, hydrogen storage materials should satisfy several requirements such as 1) hydrogen storage capacity of more than 6.5wt.% $H_2$, moderate hydrogen release temperature below $100^{\circ}C$, 3) cyclic reversibility of hydrogen absorption/desorption, 4) non toxicity and low price. Among the candidate materials, Li based metal hydrides are known to be promising materials with high practical potential in view of the above requirements. This paper reviews the characteristics and recent R&D trends of Li based complex hydrides, Li-alanates, Li-borohydrides, and Li-amides/imides.

• 한국수소및신에너지학회논문집
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• 제33권4호
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• pp.383-390
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• 2022

Appropriate explosion proof electrical equipment should be installed in hazardous areas. In areas where hydrogen is handled, explosion proof electrical equipment adjacent to the hydrogen handing facility must be reviewed for selection of gas group IIC (or IIB+H₂) equipment. When selecting explosion proof electrical equipment for the flammable substance handling facility in areas where hydrogen and flammable substance are handled, the method to avoid gas group IIC (or IIB+H₂) equipment has been suggested by using the operating pressure of the hydrogen handling facility. When the operating pressure of the outdoor hydrogen handling facility is 1.065 MPa or less, it has been confirmed that there is no need to install gas group IIC (or IIB+H₂) equipment for the flammable substance handling facility adjacent to the hydrogen handling facility. And the method of selecting explosion proof electrical equipment for the flammable substance handling facility has been suggested as a flowchart, so it will be able to be utilized when selecting appropriate explosion proof electrical equipment.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.225-230
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• 2017

Coal oil is widely used as a home heating fuel for portable and installed coal oil heaters. Today, Coal oil is widely used as fuel for jet engines and some rocket engines in several grades. This paper describes the performance characteristics according to the compression ratio of spark ignition engine fuelled with coal oil. As a result, the following knowledge is obtained: As the compression ratio is decreased, there is an increase in torque, indicated mean effective pressure (IMEP), heat release rate, and brake thermal efficiency. Higher compression ratio of the engine decreases the ignition delay period, combustion period, and cooling loss.

• 한국대기환경학회지
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• 제32권3호
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• pp.248-255
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• 2016

The leaves of three plant species, such as soybean, raspberry, and kudzu, exposed to hydrogen fluoride was collected in an area surrounding an emission source where the release accident occurred. The ultrasonic-assisted extraction and analysis of fluoride by ion chromatography was carried out. The mean concentration of fluoride in the leaves of three plant species exposed to hydrogen fluoride was $5,409{\pm}1,198mg\;F/kg\;dry\;wt$ and $788{\pm}339mg\;F/kg\;dry\;wt$, respectively. The mean fluoride concentration in ambient air were estimated to be $2.36{\pm}0.65mg/m^3$ ($2.89{\pm}0.79ppm$) and $0.35{\pm}0.15mg/m^3$ ($0.43{\pm}0.19ppm$) in exposed and unexposed sites, respectively. It seems likely that the passive monitoring using plant leaves could identify with respect to plant risk by fluoride in atmosphere.