• Title/Summary/Keyword: Hydrogen generation system

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Reaction of ferritin with hydrogen peroxide induces lipid peroxidation

  • Yoon, Hung-Hwan;Lee, Myeong-Seon;Kang, Jung-Hoon
    • BMB Reports
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    • v.43 no.3
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    • pp.219-224
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    • 2010
  • Lipid peroxidation is known to be an important factor in the pathologies of many diseases associated with oxidative stress. We assessed the lipid peroxidation induced by the reaction of ferritin with $H_2O_2$. When linoleic acid micelles or phosphatidyl choline liposomes were incubated with ferritin and $H_2O_2$, lipid peroxidation increased in the presence of ferritin and $H_2O_2$ in a concentration-dependent manner. The hydroxyl radical scavengers, azide and thiourea, prevented lipid peroxidation induced by the ferritin/$H_2O_2$ system. The iron specific chelator desferoxamine also prevented ferritin/$H_2O_2$ systemmediated lipid peroxidation. These results demonstrate the possible role of iron in ferritin/$H_2O_2$ system-mediated lipid peroxidation. Carnosine is involved in many cellular defense processes, including free radical detoxification. In this study, carnosine, homocarnosine, and anserine were shown to significantly prevent ferritin/$H_2O_2$ system-mediated lipid peroxidation and also inhibited the free radical-generation activity of ferritin. These results indicated that carnosine and related compounds may prevent ferritin/$H_2O_2$ system-mediated lipid peroxidation via free radical scavenging.

Analysis on Operational Characteristics of PV-SPE System by a Novel MPPT Control (PV-SPE 시스템을 위한 새로운 MPPT 제어의 운전특성 분석에 관한 연구)

  • Choi, Jong-Ho;Lee, Dong-Han;Kim, Jong-Hyun;Kim, Jae-Ho;Park, Min-Won;Yu, In-Keun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.121-124
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    • 2006
  • In the newly developed control method, the current flowing into SPE cell is the only one considerable factor. So, the structure of control circuit becomes simple and the manufacturing cost of the control device decreases. In conventional power comparison MPPT control method however, a voltage and current coming out from PV cell should be feedbacked to chase maximum power point at every moment. Then, the structure of control circuit becomes so complex and the risk of control failure is much higher than the novel MPPT control method. Therefore, PV generation system by a novel MPPT control method is especially operated much more safely in case of a huge system, because the voltage coming out from PV-cell is not needed to be feedbacked. In this paper, the PV-SPR system was actually manufactured based on the simulation model of PSCAD/EMTDC program and the results tested were shown. Authors are sure that it is the most useful method to maximize power from PV to SPE with only a feedback of SPE input current.

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Study of Linear Generator for Power/Generation System using Hydrogen (수소연소 동력/발전시스템용 리니어 발전기 설계에 대한 연구)

  • Choi, Dong-Min;Noh, Tae-Seok;Lim, Jae-Won;Kim, Ki-Young;Oh, Si-Deok
    • Proceedings of the KIEE Conference
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    • 2008.10c
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    • pp.182-184
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    • 2008
  • 수소리니어 동력/발전시스템은 기존의 인프라를 이용한 개발이 가능한 이점과 고압축비, 초회박연소 실현에 의한 고효율, 저배기 달성이 가능한 장점을 가지고 있다. 또한 엔진 혹은 발전기의 구조변경 없이 다양한 연료를 사용이 가능하기 때문에 차세대 수소이용 기관으로 연구가 이루어지고 있다. 본 연구에서는 기존에 설계한 5kW급 리니어발전기의 성능향상을 위해 공극구조의 개선과 디텐트력 감소 설계를 했다. SPM 타입의 자석을 적용한 내충격 구조의 이동자 설계과 디텐트력 감소를 위한 치 형상설계가 이루어졌다.

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An Analysis on Policy Trends of the Use and Development of Nuclear Power in Nuclear Advanced Countries (주요국의 원자력이용개발 정책동향 분석)

  • 차종희;조흥곤;양맹호
    • Journal of Korea Technology Innovation Society
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    • v.6 no.4
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    • pp.462-479
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    • 2003
  • The policy trends of use and the development of nuclear power in the United States, France, United Kingdom. Germany, Russia, China, Japan and Korea are briefly investigated. Nuclear power technology has been developed as the national policy in the nuclear-advanced countries. 50 years has passed since the declaration of "Atoms for Peace" by USA President Eisenhour in December 1953. Recently, it appears to revitalize the nuclear power program in world major countries in order to recover the shortage of electric power and to curb the excess emission of carbon dioxide as well as to secure competitiveness in electricity markets. Advanced countries are making new initiatives for the development of the fourth generation nuclear power system. Furthermore, wide-ranged use and development of nuclear power technologies are expected in district heating in commercial sectors, power in the space exploration, and propulsion power of large tankers and spaceships. High temperature gas cooled nuclear power reactor will be applied for mass production of hydrogen energy in the future.

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Reaction Characteristics of Five Kinds of Oxygen Carrier Particles for Chemical-Looping Combustor (매체순환식 가스연소기 적용을 위한 5가지 산소공여입자들의 반응특성)

  • Ryu, Ho-Jung;Kim, Gyoung-Tae;Lim, Nam-Yun;Bae, Seong-Youl
    • Journal of Hydrogen and New Energy
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    • v.14 no.1
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    • pp.24-34
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    • 2003
  • For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion may yield great advantages for the savings of energy to $CO_2$ separation and suppressing the effect on environment, In chemical-looping combustor, fuel is oxidized by metal oxide medium in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. In this study, five oxygen carrier particles such as NiO/bentonite, NiO/YSZ, $(NiO+Fe_2O_3)VYSZ$, $NiO/NiAl_2O_4$, and $Co_{\chi}O_y/CoAl_2O_4$ were examined &om the viewpoints of reaction kinetics, oxygen transfer capacity, and carbon deposition characteristics. Among five oxygen particles, NiO/YSZ particle is superior in reaction rate, oxygen carrier capacity, and carbon deposition to other particles. However, at high temperature ($>900^{\circ}C$), NiO/bentonite particle also shows enough reactivity and oxygen carrier capacity to be applied in a practical system.

A Study on Operation Characteristics of Planar-type SOFC System Integrated with Fuel Processor (연료개질기를 연계한 고체 산화물 연료전지 시스템의 운전 특성에 관한 연구)

  • Ji Hyun-Jin;Lim Sung-Kwang;Yoo Yung-Sung;Bae Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.8 s.251
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    • pp.731-740
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    • 2006
  • The solid oxide fuel cell (SOFC) is expected to be a candidate for distributed power sources in the next generation, due to its high efficiency and high-temperature waste heat utilization. In this study, the 5-cell SOFC stack was operated with pure hydrogen or reformed gas at anode side and air at cathode side. When stack was operated with diesel and methane ATR reformer, the influence of the $H_2O/C,\;O_2/C$ and GHSV on performance of stacks have been investigated. The result shows that the cell voltage was decreased with the increase of $H_2O/C$ and $O_2/C$ due to the partial pressure of fuel and water, and cell voltage was more sensitive to $O_2/C$ than $H_2O/C$. Next, the dynamic model of SOFC system included with ATR reformer was established and compared with experimental data. Based on dynamic model, the operation strategy to optimize SOFC-Reformer system was suggested and simulated.

Studies on the antioxidant Effects of Carthami Flos Extract (홍화(紅花) 추출물의 항산화 효과에 대한 연구)

  • Yoo, Jin-Sook;Lim, Hyung-Ho
    • The Journal of Korean Medicine
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    • v.28 no.1 s.69
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    • pp.137-147
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    • 2007
  • Objective : The objective of this study was to investigate the antioxidative effects of Carthami Flos extract. Methods : Total antioxidant status was examined by total antioxidant capacity(TAC) and total antioxidant response(TAR) against potent free radical reactions. The effect of Carthami Flos extract was examined far details of total phenolic content concentration at which 1,1-dipheny1-2-picrylhydrazyl(DPPH) radical scavenging activity was inhibited, the inhibitory effect on lipid peroxidation, and the effect on reactive oxygen species(ROS) generation. Results : TAC of Carthami Flos extract at the concentration of 5 mg/ml was 1.84 mM Trolox equivalent. 2. TAR of Carthami Flos extract, on the other hand, couldn't be determined due to interference from unidentified compounds. 3. Total phenolic content of Carthami Flos extract at the concentration of 5 mg/ml was 2.01 mM gallic acid equivalent. 4. Concentration of Carthami Flos extract at which DPPH radical scavenging activity was inhibited by 50% was 6.43 mg/ml as compared to 100% by Pyrogallol solution as a reference. 5. The inhibitory effect of the extract on lipid peroxidation was examined using rat liver mitochondria induced by FeS04/ascorbic acid. Carthami Flos extract at the concentration of 10 ms/ml slightly but significantly decreased TBARS concentration. The extract continued to prevent lipid peroxidation in a dose-dependent manner. 6. The effect of Carthami Flos extract on reactive oxygen species(ROS) generation was examined using a cell-free system induced by hydrogen peroxide/FeS04. Addition of 1 mg/ml of Carthami Flos extract significantly reduced dichlorofluorescein(DCF) fluorescence. Carthami Flos extract caused concentration-dependent attenuation of the increase in DCF fluorescence, indicating that the ektract significantly prevented ROS generation in vitro. Conclusion: : Antioxidant efffcts of Carffami ffor extract seem to be due, at least in part, to the prevention offree radical-induced oxidation, fellowed by inhibition of lipid peroxidation.

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Studies on the Antioxidant Effects of Mori Folium Extract (상엽(桑葉)추출물의 항산화효과에 대한 연구)

  • Lee, Ji-Eun;Lim, Hyung-Ho;Song, Yun-Kyung
    • The Journal of Korean Medicine
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    • v.28 no.1 s.69
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    • pp.148-158
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    • 2007
  • Objective : The objective of this study was to investigate the antioxidant effects of Mori Folium extract. Methods Total antioxidant status was examined by total antioxidant capacity(TAC) and total antioxidant response(TAR) against potent free radical reactions. The effect of Mori Folium extract was examined by measuring total phenolic content, concentration at which 1,1-dipheny1-2-picrylhydrazyl(DPPH) radical scavenging activity was inhibited, inhibitory effect on lipid peroxidation, and the effect on reactive oxygen species(ROS) generation. Results : 1. TAC and TAR of Mori Folium extract at the concentration of 5 mg/ml were 1.61 and 1.24 mM Trolox equivalents, respectively. 2. Total phenolic content of Mori Folium extract at the concentration of 5 mg/Ml was 1.70 mM gallic acid equivalent. 3. Concentration of Mori Folium extract at which DPPH radical scavenging activity was inhibited by 50% was 2.29 m9/m4 as compared to 100% by Pyrogallol solution as a reference. 4. The inhibitory effect of the extract on lipid peroxidation was examined using rat liver mitochondria induced by FeSO$_4$/ascorbic acid. Mori Folium extract at the concentration of 10 mg/ml significantly decreased thiobarbituric acid reactive substances(TBARS) concentration. The extract prevented lipid peroxidation in a dose-dependent 5. The effect of Mori Folium extract on reactive oxygen species(ROS) generation was examined using a celt-free system induced by hydrogen peroxide FeSO$_4$. Addition of 1 mg/ml of Mori Folium extract significantly reduced dichlorofluorescein(DCf) fluorescence. The extract caused concentration-dependent attenuation of the increase in DCF fluorescence, indicating that the extract significantly prevented ROS generation in vitro. Conclusion ; The antioxidant effects of Mori Folium extract seem to be due, at least in part, to the prevention offree radical-induced oxidation, fllowed by inhibition of lipid peroxidation.

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Effect of Varying Excessive Air Ratios on Nitrogen Oxides and Fuel Consumption Rate during Warm-up in a 2-L Hydrogen Direct Injection Spark Ignition Engine (2 L급 수소 직접분사 전기점화 엔진의 워밍업 시 공기과잉률에 따른 질소산화물 배출 및 연료 소모율에 대한 실험적 분석)

  • Jun Ha;Yongrae Kim;Cheolwoong Park;Young Choi;Jeongwoo Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.52-58
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    • 2023
  • With the increasing awareness of the importance of carbon neutrality in response to global climate change, the utilization of hydrogen as a carbon-free fuel source is also growing. Hydrogen is commonly used in fuel cells (FC), but it can also be utilized in internal combustion engines (ICE) that are based on combustion. Particularly, ICEs that already have established infrastructure for production and supply can greatly contribute to the expansion of hydrogen energy utilization when it becomes difficult to rely solely on fuel cells or expand their infrastructure. However, a disadvantage of utilizing hydrogen through combustion is the potential generation of nitrogen oxides (NOx), which are harmful emissions formed when nitrogen in the air reacts with oxygen at high temperatures. In particular, for the EURO-7 exhaust regulation, which includes cold start operation, efforts to reduce exhaust emissions during the warm-up process are required. Therefore, in this study, the characteristics of nitrogen oxides and fuel consumption were investigated during the warm-up process of cooling water from room temperature to 88℃ using a 2-liter direct injection spark ignition (SI) engine fueled with hydrogen. One advantage of hydrogen, compared to conventional fuels like gasoline, natural gas, and liquefied petroleum gas (LPG), is its wide flammable range, which allows for sparser control of the excessive air ratio. In this study, the excessive air ratio was varied as 1.6/1.8/2.0 during the warm-up process, and the results were analyzed. The experimental results show that as the excessive air ratio becomes sparser during warm-up, the emission of nitrogen oxides per unit time decreases, and the thermal efficiency relatively increases. However, as the time required to reach the final temperature becomes longer, the cumulative emissions and fuel consumption may worsen.

Mechanical and Electrochemical Characteristics of Welding Parts Surface for Friction Stir Welded 5456-H116 Al Alloy (마찰교반용접한 5456-H116 알루미늄 합금 용접부 표면의 기계적 및 전기화학적 특성)

  • Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of Surface Science and Engineering
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    • v.41 no.4
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    • pp.156-162
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    • 2008
  • Small FRP(fiber-reinforced polymer) fishing ships have numerous problems with the point of the environmental and recycling perspectives. In light of these aspects, aluminum can be used as a material for ship building. It is environmental friendly, easy to recycle, and provides a high added value to fishing boats. In this paper, we report on mechanical and electrochemical characteristics of welding parts for friction stir welded 5456-H116 Al alloy. In friction stir welded at various traveling speeds under the rotation speed of 500 RPM, the best characteristics presented in traveling speed of 15mm/min. The anodic polarizations of base metal and welding metal were observed tendency which current density from the open circuit potential suddenly increase. The cathodic polarization presented concentrated polarization caused by the dissolved oxygen reduction reaction and activation polarization caused by hydrogen generation. From result of Tafel analysis, the corrosion potential of 5456 alloy(Base metal) was lower than that of friction stir welded part, as were its corrosion current densities.